<?xml version="1.0" encoding="UTF-8"?>
<!DOCTYPE article PUBLIC "-//NLM//DTD JATS (Z39.96) Journal Publishing DTD v1.3 20210610//EN" "JATS-journalpublishing1-3.dtd">
<article article-type="research-article" dtd-version="1.3" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xml:lang="en"><front><journal-meta><journal-id journal-id-type="publisher-id">najo</journal-id><journal-title-group><journal-title xml:lang="en">Nanosystems: Physics, Chemistry, Mathematics</journal-title><trans-title-group xml:lang="ru"><trans-title>Наносистемы: физика, химия, математика</trans-title></trans-title-group></journal-title-group><issn pub-type="ppub">2220-8054</issn><issn pub-type="epub">2305-7971</issn><publisher><publisher-name>Университет ИТМО</publisher-name></publisher></journal-meta><article-meta><article-id pub-id-type="doi">10.17586/2220-8054-2015-6-3-361-365</article-id><article-id custom-type="elpub" pub-id-type="custom">najo-944</article-id><article-categories><subj-group subj-group-type="heading"><subject>Research Article</subject></subj-group><subj-group subj-group-type="section-heading" xml:lang="en"><subject>PHYSICS</subject></subj-group><subj-group subj-group-type="section-heading" xml:lang="ru"><subject>ФИЗИКА</subject></subj-group></article-categories><title-group><article-title>Synthesis of copper nanoparticles for use in an optical initiation system</article-title><trans-title-group xml:lang="ru"><trans-title></trans-title></trans-title-group></title-group><contrib-group><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="western" xml:lang="en"><surname>Pugachev</surname><given-names>V. M.</given-names></name></name-alternatives><bio xml:lang="en"><p>Kemerovo, 650043</p></bio><email xlink:type="simple">kriger@kemsu.ru</email><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="western" xml:lang="en"><surname>Datiy</surname><given-names>K. A.</given-names></name></name-alternatives><bio xml:lang="en"><p>Kemerovo, 650000</p></bio><xref ref-type="aff" rid="aff-2"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="western" xml:lang="en"><surname>Valnyukova</surname><given-names>A. S.</given-names></name></name-alternatives><bio xml:lang="en"><p>Kemerovo, 650043</p></bio><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="western" xml:lang="en"><surname>Ananyeva</surname><given-names>M. V.</given-names></name></name-alternatives><bio xml:lang="en"><p>Kemerovo, 650043</p></bio><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="western" xml:lang="en"><surname>Kalenskii</surname><given-names>A. V.</given-names></name></name-alternatives><bio xml:lang="en"><p>Kemerovo, 650043</p></bio><xref ref-type="aff" rid="aff-1"/></contrib></contrib-group><aff xml:lang="en" id="aff-1"><institution>Kemerovo state University</institution><country>Russian Federation</country></aff><aff xml:lang="en" id="aff-2"><institution>Institute of Coal Chemistry and Material Science SB RAS</institution><country>Russian Federation</country></aff><pub-date pub-type="collection"><year>2015</year></pub-date><pub-date pub-type="epub"><day>15</day><month>08</month><year>2025</year></pub-date><volume>6</volume><issue>3</issue><fpage>361</fpage><lpage>365</lpage><permissions><copyright-statement>Copyright &amp;#x00A9; Pugachev V.M., Datiy K.A., Valnyukova A.S., Ananyeva M.V., Kalenskii A.V., 2025</copyright-statement><copyright-year>2025</copyright-year><copyright-holder xml:lang="ru">Pugachev V.M., Datiy K.A., Valnyukova A.S., Ananyeva M.V., Kalenskii A.V.</copyright-holder><copyright-holder xml:lang="en">Pugachev V.M., Datiy K.A., Valnyukova A.S., Ananyeva M.V., Kalenskii A.V.</copyright-holder><license xml:lang="ru" license-type="creative-commons-attribution" xlink:href="https://creativecommons.org/licenses/by/4.0/" xlink:type="simple"><license-p>Данная работа распространяется под лицензией Creative Commons Attribution 4.0.</license-p></license><license xml:lang="en" license-type="creative-commons-attribution" xlink:href="https://creativecommons.org/licenses/by/4.0/" xlink:type="simple"><license-p>This work is licensed under a Creative Commons Attribution 4.0 License.</license-p></license></permissions><self-uri xlink:href="https://nanojournal.ifmo.ru/jour/article/view/944">https://nanojournal.ifmo.ru/jour/article/view/944</self-uri><abstract><p>In this work, the modes of synthesizing copper nanoparticles for use in an optical initiation system were proposed. The optimal sizes of the copper particles in the pentaerythritol tetranitrate were estimated, for use as a cup of the optical detonator on the rst and the second harmonics of the Nd:Yag laser. For the rst harmonic of the Nd:Yag, laser the absorptivity maximum was 0.097 and the particles radius was 98 nm, for the second harmonic, the absorptivity maximum rose more than in 34 times, and it was equal to 3.29 and the copper particles radius was 30 nm. Comparison of the calculated critical energy densities shows that pentaerythritol tetranitrate, which contains the copper nanoparticles, must be signi cantly more sensitive ( 29 times) to the second harmonic than to the rst. The modes of synthesis for copper nanoparticles of the required size were determined and tested.</p></abstract><kwd-group xml:lang="en"><kwd>Hot spot model</kwd><kwd>laser initiation</kwd><kwd>metal nanoparticles absorption</kwd><kwd>copper nanoparticles</kwd><kwd>synthesis of nanoparticles</kwd></kwd-group></article-meta></front><back><ref-list><title>References</title><ref id="cit1"><label>1</label><citation-alternatives><mixed-citation xml:lang="ru">Yang G., Zhang Z., et al. Synthesis and characterization of highly stable dispersions of copper nanopar ticles by a novel one-pot method. Materials Research Bulletin, 2013, 48, P. 1716.</mixed-citation><mixed-citation xml:lang="en">Yang G., Zhang Z., et al. Synthesis and characterization of highly stable dispersions of copper nanopar ticles by a novel one-pot method. Materials Research Bulletin, 2013, 48, P. 1716.</mixed-citation></citation-alternatives></ref><ref id="cit2"><label>2</label><citation-alternatives><mixed-citation xml:lang="ru">Patolsky F., Zheng G., et al. Nanowire-based biosensors. Analytical Chemistry, 2006, 78(13), P. 4260 4269.</mixed-citation><mixed-citation xml:lang="en">Patolsky F., Zheng G., et al. Nanowire-based biosensors. Analytical Chemistry, 2006, 78(13), P. 4260 4269.</mixed-citation></citation-alternatives></ref><ref id="cit3"><label>3</label><citation-alternatives><mixed-citation xml:lang="ru">Wang J. Carbon-nanotube based electrochemical biosensors: A review. Electroanalysis, 2005, 17, P. 7 14.</mixed-citation><mixed-citation xml:lang="en">Wang J. Carbon-nanotube based electrochemical biosensors: A review. Electroanalysis, 2005, 17, P. 7 14.</mixed-citation></citation-alternatives></ref><ref id="cit4"><label>4</label><citation-alternatives><mixed-citation xml:lang="ru">Paxton W. F., Sen A., Mallouk T. E. Motility of catalytic nanoparticles through self-generated forces. Chemistry- A European Journal, 2005, 11, P. 64626470.</mixed-citation><mixed-citation xml:lang="en">Paxton W. F., Sen A., Mallouk T. E. Motility of catalytic nanoparticles through self-generated forces. Chemistry- A European Journal, 2005, 11, P. 64626470.</mixed-citation></citation-alternatives></ref><ref id="cit5"><label>5</label><citation-alternatives><mixed-citation xml:lang="ru">Ananyeva M.V., Zvekov A.A., et al. Promising compounds for the cap of optical detonator. Perspek tivnye materialy, 2014, 7, P. 512.</mixed-citation><mixed-citation xml:lang="en">Ananyeva M.V., Zvekov A.A., et al. Promising compounds for the cap of optical detonator. Perspek tivnye materialy, 2014, 7, P. 512.</mixed-citation></citation-alternatives></ref><ref id="cit6"><label>6</label><citation-alternatives><mixed-citation xml:lang="ru">Lukatova S.G. Calculation of the PETN-gold composites absorptivity for the second harmonic of the ND:YAG laser. Mezhdunarodnoe nauchnoe izdanie Sovremennye fundamentalnye i prikladnye issle dovanija, 2014, 1(12), P. 9598.</mixed-citation><mixed-citation xml:lang="en">Lukatova S.G. Calculation of the PETN-gold composites absorptivity for the second harmonic of the ND:YAG laser. Mezhdunarodnoe nauchnoe izdanie Sovremennye fundamentalnye i prikladnye issle dovanija, 2014, 1(12), P. 9598.</mixed-citation></citation-alternatives></ref><ref id="cit7"><label>7</label><citation-alternatives><mixed-citation xml:lang="ru">Ananyeva M.V., Kalenskii A.V., et al. Kinetic regularities of explosive decomposition of PETN contan ing aluminium, cobalt and nickel nanoparticles. Bulletin of Kemerovo state university, 2014, 1-1(57), P. 194200.</mixed-citation><mixed-citation xml:lang="en">Ananyeva M.V., Kalenskii A.V., et al. Kinetic regularities of explosive decomposition of PETN contan ing aluminium, cobalt and nickel nanoparticles. Bulletin of Kemerovo state university, 2014, 1-1(57), P. 194200.</mixed-citation></citation-alternatives></ref><ref id="cit8"><label>8</label><citation-alternatives><mixed-citation xml:lang="ru">Kalenskii A.V., Ananyeva M.V., et al. Spectrum dependence of the critical energy density of compos ites based on pentaerythritol tetranitrate with nikel nanoparticles. Fundamentalnye problemy sovre mennogo materialovedenia, 2014, 11(3), P. 340345.</mixed-citation><mixed-citation xml:lang="en">Kalenskii A.V., Ananyeva M.V., et al. Spectrum dependence of the critical energy density of compos ites based on pentaerythritol tetranitrate with nikel nanoparticles. Fundamentalnye problemy sovre mennogo materialovedenia, 2014, 11(3), P. 340345.</mixed-citation></citation-alternatives></ref><ref id="cit9"><label>9</label><citation-alternatives><mixed-citation xml:lang="ru">Kalenskii A.V., Zvekov A.A., et al. Inuence of the laser irradiation wavelength on the energetic materials initiation critical energy. Fizika goreniya i vzryva, 2014, 50(3), P. 98104.</mixed-citation><mixed-citation xml:lang="en">Kalenskii A.V., Zvekov A.A., et al. Inuence of the laser irradiation wavelength on the energetic materials initiation critical energy. Fizika goreniya i vzryva, 2014, 50(3), P. 98104.</mixed-citation></citation-alternatives></ref><ref id="cit10"><label>10</label><citation-alternatives><mixed-citation xml:lang="ru">Kalenskii A.V., Kriger V.G., et al. The Microcenter Heat Explosion Model Modernization. Izvestia Vuzov Fizika, 2012, 55(11-3), P. 6266.</mixed-citation><mixed-citation xml:lang="en">Kalenskii A.V., Kriger V.G., et al. The Microcenter Heat Explosion Model Modernization. Izvestia Vuzov Fizika, 2012, 55(11-3), P. 6266.</mixed-citation></citation-alternatives></ref><ref id="cit11"><label>11</label><citation-alternatives><mixed-citation xml:lang="ru">Aduev B.P., Nurmukhametov D.R., et al. Vzryvchatoye razlozheniye TENa s nanodobavkami alyu miniya pri vozdeystvii impulsnogo lazernogo izlucheniya razlichnoy dliny volny. Khimicheskaya zika, 2013, 32(8), P. 3942.</mixed-citation><mixed-citation xml:lang="en">Aduev B.P., Nurmukhametov D.R., et al. Vzryvchatoye razlozheniye TENa s nanodobavkami alyu miniya pri vozdeystvii impulsnogo lazernogo izlucheniya razlichnoy dliny volny. Khimicheskaya zika, 2013, 32(8), P. 3942.</mixed-citation></citation-alternatives></ref><ref id="cit12"><label>12</label><citation-alternatives><mixed-citation xml:lang="ru">Aduev B.P., Nurmukhametov D.R., et al. Integrating Sphere study of the optical properties of alu minum nanoparticles in tetranitropentaerytrite. Zhurnal Tekhnicheskoi Fiziki, 2014, 84(9), P. 126131.</mixed-citation><mixed-citation xml:lang="en">Aduev B.P., Nurmukhametov D.R., et al. Integrating Sphere study of the optical properties of alu minum nanoparticles in tetranitropentaerytrite. Zhurnal Tekhnicheskoi Fiziki, 2014, 84(9), P. 126131.</mixed-citation></citation-alternatives></ref><ref id="cit13"><label>13</label><citation-alternatives><mixed-citation xml:lang="ru">Zvekov A.A., Ananyeva M.V., et al. Regularities of light di usion in the compo site material pentaery thritol tetranitrate nickel. Nanosystems: physics, chemistry, mathematics., 2014, 5(5), P. 685691.</mixed-citation><mixed-citation xml:lang="en">Zvekov A.A., Ananyeva M.V., et al. Regularities of light di usion in the compo site material pentaery thritol tetranitrate nickel. Nanosystems: physics, chemistry, mathematics., 2014, 5(5), P. 685691.</mixed-citation></citation-alternatives></ref><ref id="cit14"><label>14</label><citation-alternatives><mixed-citation xml:lang="ru">Kriger V.G., Kalenskii A.V., et al. Vliyaniye e ektivnosti pogloshcheniya lazernogo izlucheniya na temperaturu razogreva vklyucheniya v prozrachnykh sredakh. Fizika goreniya i vzryva, 2012, 48(6), P. 5458.</mixed-citation><mixed-citation xml:lang="en">Kriger V.G., Kalenskii A.V., et al. Vliyaniye e ektivnosti pogloshcheniya lazernogo izlucheniya na temperaturu razogreva vklyucheniya v prozrachnykh sredakh. Fizika goreniya i vzryva, 2012, 48(6), P. 5458.</mixed-citation></citation-alternatives></ref><ref id="cit15"><label>15</label><citation-alternatives><mixed-citation xml:lang="ru">Gazenaur N.V., Zykov I.Yu., et al. The wavelength dependence of copper absorption. Aspirant, 2014, 5, P. 9498.</mixed-citation><mixed-citation xml:lang="en">Gazenaur N.V., Zykov I.Yu., et al. The wavelength dependence of copper absorption. Aspirant, 2014, 5, P. 9498.</mixed-citation></citation-alternatives></ref><ref id="cit16"><label>16</label><citation-alternatives><mixed-citation xml:lang="ru">Aduev B.P., Ananyeva M.V., et al. Miro-hotspot model for the laser initiation of explosive decompo sition of energetic materials with melting taken into account. Fizika goreniya i vzryva, 2014, 50(6), P. 9299.</mixed-citation><mixed-citation xml:lang="en">Aduev B.P., Ananyeva M.V., et al. Miro-hotspot model for the laser initiation of explosive decompo sition of energetic materials with melting taken into account. Fizika goreniya i vzryva, 2014, 50(6), P. 9299.</mixed-citation></citation-alternatives></ref><ref id="cit17"><label>17</label><citation-alternatives><mixed-citation xml:lang="ru">Kriger V.G., Kalenskii A.V., et al. Protsessy teploperenosa pri lazernom razogreve vklyucheny v in ertnoy matritse. Teplo zika i aeromekhanika, 2013, 20(3), P. 375382.</mixed-citation><mixed-citation xml:lang="en">Kriger V.G., Kalenskii A.V., et al. Protsessy teploperenosa pri lazernom razogreve vklyucheny v in ertnoy matritse. Teplo zika i aeromekhanika, 2013, 20(3), P. 375382.</mixed-citation></citation-alternatives></ref><ref id="cit18"><label>18</label><citation-alternatives><mixed-citation xml:lang="ru">Avchinnikova E.A., Vorobeva S.A. Sintez i svoistva nanochastits medi, stabilizirovannykh polietileng likolem. Vestnik BGU, 2013, 2(3), P. 1216.</mixed-citation><mixed-citation xml:lang="en">Avchinnikova E.A., Vorobeva S.A. Sintez i svoistva nanochastits medi, stabilizirovannykh polietileng likolem. Vestnik BGU, 2013, 2(3), P. 1216.</mixed-citation></citation-alternatives></ref><ref id="cit19"><label>19</label><citation-alternatives><mixed-citation xml:lang="ru">Zaharov Yu.A., Pugachev V.M., et al. Nanosize powders of transition metals binary systems. J. Phys.: Conf. Ser., 2012, 345(1), P. 12024.</mixed-citation><mixed-citation xml:lang="en">Zaharov Yu.A., Pugachev V.M., et al. Nanosize powders of transition metals binary systems. J. Phys.: Conf. Ser., 2012, 345(1), P. 12024.</mixed-citation></citation-alternatives></ref><ref id="cit20"><label>20</label><citation-alternatives><mixed-citation xml:lang="ru">Pugachev V.M., Datiy K.A., et al. Study of products of nanoscale systems Fe CoNi synthesis. Bulletin of Kemerovo state university, 2013, 55(3), P. 7780.</mixed-citation><mixed-citation xml:lang="en">Pugachev V.M., Datiy K.A., et al. Study of products of nanoscale systems Fe CoNi synthesis. Bulletin of Kemerovo state university, 2013, 55(3), P. 7780.</mixed-citation></citation-alternatives></ref><ref id="cit21"><label>21</label><citation-alternatives><mixed-citation xml:lang="ru">Zaharov Yu.A., Pugachev V.M., et al. Chemical synthesis, structure and magnetic properties of nanocrystalline FeCo alloys. Materials Letters, 2012, 74, P. 173175.</mixed-citation><mixed-citation xml:lang="en">Zaharov Yu.A., Pugachev V.M., et al. Chemical synthesis, structure and magnetic properties of nanocrystalline FeCo alloys. Materials Letters, 2012, 74, P. 173175.</mixed-citation></citation-alternatives></ref><ref id="cit22"><label>22</label><citation-alternatives><mixed-citation xml:lang="ru">Pugachev V.M., Dodonov V.G., et al. Fazovyi sostav i nekotorye svoistva nanorazmernykh poroshkov Ni Co i Ni Cu. Persptktivnye materialy, 2011, 11, P. 156163.</mixed-citation><mixed-citation xml:lang="en">Pugachev V.M., Dodonov V.G., et al. Fazovyi sostav i nekotorye svoistva nanorazmernykh poroshkov Ni Co i Ni Cu. Persptktivnye materialy, 2011, 11, P. 156163.</mixed-citation></citation-alternatives></ref><ref id="cit23"><label>23</label><citation-alternatives><mixed-citation xml:lang="ru">Datiy K.A., Zakharov Yu.A., Khitsova L.M. Termostimyliryemye protsessy na poverkhnosti nanostryk tyrirovannykh poroshkov FeCoNi. Bulletin of Kemerovo state university, 2014, 3-3(59), P. 184 188</mixed-citation><mixed-citation xml:lang="en">Datiy K.A., Zakharov Yu.A., Khitsova L.M. Termostimyliryemye protsessy na poverkhnosti nanostryk tyrirovannykh poroshkov FeCoNi. Bulletin of Kemerovo state university, 2014, 3-3(59), P. 184 188</mixed-citation></citation-alternatives></ref></ref-list><fn-group><fn fn-type="conflict"><p>The authors declare that there are no conflicts of interest present.</p></fn></fn-group></back></article>
