najoNanosystems: Physics, Chemistry, MathematicsНаносистемы: физика, химия, математика2220-80542305-7971Университет ИТМО10.17586/2220-8054-2025-16-1-116-122najo-97Research ArticleCHEMISTRY AND MATERIALS SCIENCEХИМИЯ И НАУКА О МАТЕРИАЛАХSynthesis, structure and noncovalent interactions of mesityl(phenyl)phosphine oxide glycolate based hydrogen-bonded nanosized organic frameworkСинтез, структура и нековалентные взаимодействия наноразмерного водородно-связанного каркасного полимера на основе гликолята мезитил(фенил)фосфиноксидаhttps://orcid.org/0000-0002-5603-1311КагилевА. А.KagilevA. A.

Alexey A. Kagilev

420088, Kazan

al-kagilev@mail.ruhttps://orcid.org/0000-0002-7440-1486СахаповИ. Ф.SakhapovI. F.

Ilyas F. Sakhapov

420088, Kazan

ilyas.sakhapov@iopc.ruhttps://orcid.org/0000-0001-6615-8968ГафуровЗ. Н.GafurovZ. N.

Zufar N. Gafurov

420088, Kazan

gafurov.zufar@iopc.ruhttps://orcid.org/0000-0002-2285-300XКантюковА. О.KantyukovA. O.

Artyom O. Kantyukov

420088, Kazan

kant.art@mail.ruhttps://orcid.org/0000-0001-9373-2996МихайловИ. К.MikhailovI. K.

Ilya K. Mikhailov

420088, Kazan

tiimhailovilya@gmail.comhttps://orcid.org/0000-0002-5988-1012ИсламовД. Р.IslamovD. R.

Daut R. Islamov

420111, Kazan

daut1989@mail.ruhttps://orcid.org/0000-0003-4213-9724ГерасимовА. В.GerasimovA. V.

Alexander V. Gerasimov

420008, Kazan

Alexander.Gerasimov@kpfu.ruhttps://orcid.org/0000-0002-7963-2806ФилипповО. А.FilippovO. A.

Oleg A. Filippov

119991, Moscow

h-bond@ineos.ac.ruhttps://orcid.org/0000-0002-8114-7025ГубайдуллинА. Т.GubaidullinA. T.

Aidar T. Gubaidullin

420088, Kazan

aidar@iopc.ruhttps://orcid.org/0000-0003-3107-5251СофичеваО. С.SofichevaO. S.

Olga S. Soficheva

420088, Kazan

myaolechka@yandex.ruhttps://orcid.org/0000-0002-2241-9764СиняшинО. Г.SinyashinO. G.

Oleg G. Sinyashin

420088, Kazan

oleg@iopc.ruhttps://orcid.org/0000-0002-3906-8841ЯхваровД. Г.YakhvarovD. G.

Dmitry G. Yakhvarov

420088, Kazan

yakhvar@iopc.ruArbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center, Russian Academy of SciencesRussian FederationArbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center, Russian Academy of Sciences; A.M. Butlerov Institute of Chemistry, Kazan Federal UniversityRussian FederationLaboratory for Structural Studies of Biomacromolecules, FRC Kazan Scientific Center, Russian Academy of SciencesRussian FederationA.M. Butlerov Institute of Chemistry, Kazan Federal UniversityRussian FederationA.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of SciencesRussian Federation202501062025161116122Copyright © Kagilev A.A., Sakhapov I.F., Gafurov Z.N., Kantyukov A.O., Mikhailov I.K., Islamov D.R., Gerasimov A.V., Filippov O.A., Gubaidullin A.T., Soficheva O.S., Sinyashin O.G., Yakhvarov D.G., 20252025Кагилев А.А., Сахапов И.Ф., Гафуров З.Н., Кантюков А.О., Михайлов И.К., Исламов Д.Р., Герасимов А.В., Филиппов О.А., Губайдуллин А.Т., Софичева О.С., Синяшин О.Г., Яхваров Д.Г.Kagilev A.A., Sakhapov I.F., Gafurov Z.N., Kantyukov A.O., Mikhailov I.K., Islamov D.R., Gerasimov A.V., Filippov O.A., Gubaidullin A.T., Soficheva O.S., Sinyashin O.G., Yakhvarov D.G.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://nanojournal.ifmo.ru/jour/article/view/97

The reaction of glyoxylic acid monohydrate with mesityl(phenyl)phosphine in air led to the formation of mesityl(phenyl)phosphine oxide glycolate. The synthesized mesityl(phenyl)phosphine oxide glycolate has been characterized by various analytical methods including X-ray crystal structure analysis. The analysis of intermolecular interactions in the crystal revealed interesting modes of the noncovalent bonding between pairs of molecules. These intermolecular interactions cause the formation of one-dimensional cylindrical channels with diameter of 1 nm (10 A° ) and provide the crystal with the properties of precise nano-sized crystalline porous material which can be served as the component for precise nanofiltration membranes improving the properties of amorphous polymers which suffer from disordered pore structures and reduced selectivity towards separating molecules.

Реакция моногидрата глиоксиловой кислоты с мезитил(фенил)фосфином на воздухе привела к образованию гликолата оксида мезитил(фенил)фосфина. Синтезированный гликолят оксида мезитил(фенил)фосфина был охарактеризован различными аналитическими методами, кристаллическая структура определена методом рентгеновской дифракции. Анализ межмолекулярных взаимодействий в кристалле выявил интересные типы нековалентных связей между парами молекул. Эти межмолекулярные взаимодействия вызывают образование одномерных цилиндрических каналов диаметром 1 нм (10 Å) и придают кристаллу свойства наноразмерного кристаллического пористого материала с точным размером пор, который может служить компонентом для точных нанофильтрационных мембран, улучшающих свойства аморфных полимеров, имеющих неупорядоченную структуру и пониженную селективность по отношению к разделяемым молекулам

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The authors declare that there are no conflicts of interest present.