najoNanosystems: Physics, Chemistry, MathematicsНаносистемы: физика, химия, математика2220-80542305-7971Университет ИТМО10.17586/2220-8054-2015-6-3-412-423najo-999Research ArticleCHEMISTRY AND MATERIALS SCIENCEХИМИЯ И НАУКА О МАТЕРИАЛАХMorphological memory of polymeric bodiesMelikhovI. V.

Moscow

melikhov@radio.chem.msu.ruAlekseevaO. V.

Ivanovo

ova@isc-ras.ruRudinV. N.

Moscow

KozlovskayaE. D.

Moscow

NoskovA. V.

Ivanovo

M.V. Lomonosov Moscow State UniversityRussian FederationG.A. Krestov Institute of Solution Chemistry RASRussian Federation20151508202563412423Copyright © Melikhov I.V., Alekseeva O.V., Rudin V.N., Kozlovskaya E.D., Noskov A.V., 20252025Melikhov I.V., Alekseeva O.V., Rudin V.N., Kozlovskaya E.D., Noskov A.V.Melikhov I.V., Alekseeva O.V., Rudin V.N., Kozlovskaya E.D., Noskov A.V.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://nanojournal.ifmo.ru/jour/article/view/999

The model of microrelief formation on the surface of polymers was formulated, describing the connection between the microrelief structural elements distribution function on the states with the kinetics of macro molecule formation, aggregation and aggregates integration into the polymer body. Methods for calculating the kinetics of these processes, using experimental data on the microrelief properties, were developed. The developed methods have proven e ective in the study of microrelief on lms obtained by the evaporation of o xylene and toluene solutions of polystyrene, as well as polystyrene granulesmicrorelief. The hierarchical structures were found on the surface of these bodies, from which it was possible to extract information about the polymerization and aggregation of the polystyrene macromolecules. The obtained data are sum marized in the form of a morphological memory representation of the polymer bodies, consisting in the long-term preservation of nonequilibrium structures available for study without destroying the body, as well as the possibility to use the results of the study to describe the kinetics of these structures formation.

polystyrenemicroreliefnanoparticlessubnanoparticlesThe work was supported by Russia Foundation for Basic Research (grant N 15-43 03034-a).ReferencesAlekseeva O.V., Bagrovskaya N.A., Kuzmin S.M., Noskov A.V., Melikhov I.V., Rudin V.N. Inuence of fullerene additives on the structure of the polystyrene lms. Russ. J. Phys. Chem., 2009, 83(7), P. 13201326.Alekseeva O.V., Bagrovskaya N.A., Kuzmin S.M., Noskov A.V., Melikhov I.V., Rudin V.N. Inuence of fullerene additives on the structure of the polystyrene lms. Russ. J. Phys. Chem., 2009, 83(7), P. 13201326.Alekseeva O.V, Bagrovskaya N.A., Kuzmin S.M., Noskov A.V., Melikhov I.V., Rudin V.N. E ect of C60 Doping on the Structure and Properties of Polystyrene. In Handbook on Fullerene: Syntesis, Properties and Applcations ISBN 978-1-62100-429-5. Editor:R.F.Verner, C.Benvegnu, P. 439456. 2012 Nova Science Publishers, Inc. New York, 558 p.Alekseeva O.V, Bagrovskaya N.A., Kuzmin S.M., Noskov A.V., Melikhov I.V., Rudin V.N. E ect of C60 Doping on the Structure and Properties of Polystyrene. In Handbook on Fullerene: Syntesis, Properties and Applcations ISBN 978-1-62100-429-5. Editor:R.F.Verner, C.Benvegnu, P. 439456. 2012 Nova Science Publishers, Inc. New York, 558 p.Brinker C.J., Scherer G.W. Sol-Gel Science. The Physics and Chemistry of Sol-Gel Processing. San Diego, CA: Academic Press, 1990, 908 p.Brinker C.J., Scherer G.W. Sol-Gel Science. The Physics and Chemistry of Sol-Gel Processing. San Diego, CA: Academic Press, 1990, 908 p.Salamone C. (Ed). Polymeric Material Encyclopedia. Boca Raton TL: CRC Press, 1996.Salamone C. (Ed). Polymeric Material Encyclopedia. Boca Raton TL: CRC Press, 1996.Korolev G.V., Mogilevich M.M. Three-dimensional radical polymerization. Mesh and hyperbranched polymers. Khimia. St. Petersburg, 2006.Korolev G.V., Mogilevich M.M. Three-dimensional radical polymerization. Mesh and hyperbranched polymers. Khimia. St. Petersburg, 2006.Kabanov V.A. Selected Works. Nauka, Moscow, 2010, 603 p.Kabanov V.A. Selected Works. Nauka, Moscow, 2010, 603 p.Ferreiro, V., Douglas, J. F., Warren, J., and Karim, A. Non-Equilibrium Pattern Formation in the Crystallization of Polymer Blend Films. Physical Review E, 2002, 65(4), P. 042802:1-4.Ferreiro, V., Douglas, J. F., Warren, J., and Karim, A. Non-Equilibrium Pattern Formation in the Crystallization of Polymer Blend Films. Physical Review E, 2002, 65(4), P. 042802:1-4.Irzhak V.I., Mezhikovsky S.M. Kinetics of oligomer curing. Russ. Chem. Rev., 2008, 77(1), P. 78104.Irzhak V.I., Mezhikovsky S.M. Kinetics of oligomer curing. Russ. Chem. Rev., 2008, 77(1), P. 78104.Emanuel N.M., Buchachenko A.L. Chemical physics of molecular degradation and stabilization of poly mers. Moscow, Nauka, 1988, 368 p.Emanuel N.M., Buchachenko A.L. Chemical physics of molecular degradation and stabilization of poly mers. Moscow, Nauka, 1988, 368 p.Grosberg A.Yu., Khokhlov A.R. Polymers and biopolymers from the point of view of physics. Dolgo prudny: Publishing House Intellect , 2010, 304 p.Grosberg A.Yu., Khokhlov A.R. Polymers and biopolymers from the point of view of physics. Dolgo prudny: Publishing House Intellect , 2010, 304 p.Palmer R.E., Pratonter S., Boyen H.-G. Nanostructured Surfaces from size-selected clusters. Nature Materials, 2003, 2(7), P. 443448.Palmer R.E., Pratonter S., Boyen H.-G. Nanostructured Surfaces from size-selected clusters. Nature Materials, 2003, 2(7), P. 443448.Askadskii A.A., Khokhlov A.R. Introduction to physical chemistry of polymers. Moscow, Nauchny Mir, 2009, 384 p.Askadskii A.A., Khokhlov A.R. Introduction to physical chemistry of polymers. Moscow, Nauchny Mir, 2009, 384 p.Melihov I.V. An evolutionary approach to the creation of nanostructures. Nanosystems: physics, chem istry, mathematics, 2010, 1(1), P. 148155.Melihov I.V. An evolutionary approach to the creation of nanostructures. Nanosystems: physics, chem istry, mathematics, 2010, 1(1), P. 148155.Melikhov I.V., Physico-chemical evolution of solid. Moscow, Binom, 2006, 309 p.Melikhov I.V., Physico-chemical evolution of solid. Moscow, Binom, 2006, 309 p.Yampolsky Yu.P. Methods of studying the free volume in polymers. Russ. Chem. Rev., 2007, 76(1), P. 6687.Yampolsky Yu.P. Methods of studying the free volume in polymers. Russ. Chem. Rev., 2007, 76(1), P. 6687.Nalwes H.S. (Ed). Handbook of Nanostructured Materials and Nanotechnology, v 5. Organics, Polymer and Biological Compounds. Boston: Acad. Press, 2000.Nalwes H.S. (Ed). Handbook of Nanostructured Materials and Nanotechnology, v 5. Organics, Polymer and Biological Compounds. Boston: Acad. Press, 2000.Tant M.R., Connell J.W., McManus H.L.N.(Eds). High Temperature Properties and Applications of Polymeric Materials. ACS Symposium Series. V 603. American Chemical Society, Washington Dc, 1995.Tant M.R., Connell J.W., McManus H.L.N.(Eds). High Temperature Properties and Applications of Polymeric Materials. ACS Symposium Series. V 603. American Chemical Society, Washington Dc, 1995.Mozhikovsky S.M., Arinshtein A.E., Deberdeev R.Ya. Oligomeric state of matter. Moscow, Nauka, 2005, 252 p.Mozhikovsky S.M., Arinshtein A.E., Deberdeev R.Ya. Oligomeric state of matter. Moscow, Nauka, 2005, 252 p.Volfson S.A., Enikolopyan I.S. The calculation of high-performance polymerization processes. Moscow, Khimia, 1980, 312 p.Volfson S.A., Enikolopyan I.S. The calculation of high-performance polymerization processes. Moscow, Khimia, 1980, 312 p.Fredrickson G.H. The Equilibrium Theory of Inhomogeneous Polymers. Oxford: University Press, 2006.Fredrickson G.H. The Equilibrium Theory of Inhomogeneous Polymers. Oxford: University Press, 2006.Simon P., Huhle R., Lehmann M., Lichte H., Monter D., Bieber T., Reschetilowski V., at all. Electron Holography on Beam Sensitive Materials: Organic Polymers and Mesoporous Silica. Chem.Mater., 2002, 14, P. 15051514.Simon P., Huhle R., Lehmann M., Lichte H., Monter D., Bieber T., Reschetilowski V., at all. Electron Holography on Beam Sensitive Materials: Organic Polymers and Mesoporous Silica. Chem.Mater., 2002, 14, P. 15051514.Vang D., Zhu J., Yao Q., Wilkie C.A. A Comparison of Various Methods for the Preparation of Polystyrene an Poly(methyl methacrylate) clay Nanocomposites. Chem.Mater., 2002, 14(9), P. 3837 3843.Vang D., Zhu J., Yao Q., Wilkie C.A. A Comparison of Various Methods for the Preparation of Polystyrene an Poly(methyl methacrylate) clay Nanocomposites. Chem.Mater., 2002, 14(9), P. 3837 3843.Dutschke A., Diegelmann C., Lobmann P. Nucleation and Growth of TiO2 Thin Films on Modi ed Polystyrene Surfaces. Chem.Mater., 2003, 15(18), P. 35013506.Dutschke A., Diegelmann C., Lobmann P. Nucleation and Growth of TiO2 Thin Films on Modi ed Polystyrene Surfaces. Chem.Mater., 2003, 15(18), P. 35013506.Seeman N.C. DNA in a material world. Nature, 2003, 421(6921), P. 427431.Seeman N.C. DNA in a material world. Nature, 2003, 421(6921), P. 427431.Egen M., Voss R., Griesebock B., Zentel R. Heterostructures of Polymer Photonic Crystal Films. Chem.Mater., 2003, 15(20), P. 37863790.Egen M., Voss R., Griesebock B., Zentel R. Heterostructures of Polymer Photonic Crystal Films. Chem.Mater., 2003, 15(20), P. 37863790.Donald A.M. The use of environmental scanning electron microscopy for imaging wet and insulating materials. Nature Materials, 2003, 2(8), P. 511516Donald A.M. The use of environmental scanning electron microscopy for imaging wet and insulating materials. Nature Materials, 2003, 2(8), P. 511516

The authors declare that there are no conflicts of interest present.