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Spectral regularities of the critical energy density of the pentaerythriol tetranitrate-aluminum nanosystems initiated by the laser pulse

Abstract

   In this work, the absorption of aluminum nanoparticles and the critical energy densities of the pentaerythritol tetranitrate-aluminum nanosystems, initiated by laser pulses, were calculated for wavelengths from 400 to 1200 nm. Data showed that it is necessary to consider both thermal and optical characteristics in order to calculate the critical initiation energy density and the radius of the most dangerous inclusion. The nanoparticle’s radius, corresponding to the maximum on the curve of absorptivities, and the maximum’s amplitude and critical energy density of the explosive materials, were all shown to depend on the initiating wavelength. The maximum of the aluminum nanoparticles’ absorptivity and minimum of the critical energy density of the explosive decomposition were observed for the 400 nm wavelength, there is also a local maximum at 850 nm. The results from the experiment qualitatively and quantitatively agree with our calculations. These results are very important to optimize the cap composition for the optical detonators.

About the Authors

A. V. Kalenskii
Kemerovo state University
Russian Federation

650043; Kemerovo



M. V. Ananyeva
Kemerovo state University
Russian Federation

650043; Kemerovo



References

1. Chumakov Yu.A., Knyazeva A.G. Initiation of reaction in the vicinity of a single particle heated by microwave radiation. Fizika goreniya i vzryva, 48(2), P. 24–30 (2012).

2. Ananyeva M.V., Zvekov A.A., et al. Promising compounds for the cap of optical detonator. Perspektivnye materialy, 7, P. 5–12 (2014).

3. Aduev B.P., Nurmukhametov D.R., et al. Vzryvchatoye razlozheniye TENa s nanodobavkami alyuminiya pri vozdeystvii impulsnogo lazernogo izlucheniya razlichnoy dliny volny. Khimicheskaya fizika, 32(8), P. 39–42 (2013).

4. Kalenskii A.V., Zvekov A.A., et al. Influence of the laser irradiation wavelength on the energetic materials’ initiation critical energy. Fizika goreniya i vzryva, 50(3), P. 98–104 (2014).

5. Kalenskii A.V., Ananyeva M.V., Zvekov A.A., Zykov I.Yu. Spectrum dependence of the critical energy density of composites based on pentaerythritol tetranitrate with nikel nanoparticles. Fundamental’nye problemy sovremennogo materialovedenia, 11(3), P. 340–345 (2014).

6. Kriger V.G., Kalenskii A.V., et al. Opredelenie shiriny fronta volny reakcii vzryvnogo razlozhenija azida serebra. Fizika goreniya i vzryva, 48(4), P. 129–136 (2012).

7. Korepanov V.I., Lisicyn V.M., Oleshko V.I., Cipilev V.P. K voprosu o kinetike i mehanizme vzryvnogo razlozhenija azidov tjazhelyh metallov. Fizika goreniya i vzryva, 42(1), P. 106–119 (2006).

8. Aduev B.P., Nurmuhametov D.R., Cipilev V.P., Furega R.I. Vlijanie dobavok ul”tradispersnyh chastic Al-C na chuvstvitel”nost” tjena k lazernomu vozdejstviju. Fizika goreniya i vzryva, 49(2), P. 102–105 (2013).

9. Kriger V.G., Kalenskii A.V., Ananyeva M.V., Borovikova A.P. Critical initiation-energy density as a function of single-crystal size in explosive decomposition of silver azide. Fizika goreniya i vzryva, 44(2), P. 76–78 (2008).

10. Aduev B.P., Ananyeva M.V., et al. Mikroochagovaja model’ lazernogo iniciirovanija vzryvnogo razlozhenija jenergeticheskih materialov s uchetom plavlenija. Fizika goreniya i vzryva, 50(6), P. 92–99 (2014).

11. Kriger V.G., Kalenskii A.V., et al. Vliyaniye effektivnosti pogloshcheniya lazernogo izlucheniya na temperaturu razogreva vklyucheniya v prozrachnykh sredakh. Fizika goreniya i vzryva, 48(6), P. 54–58 (2012).

12. Nikitin A.P. Raschet kriticheskih parametrov iniciirovanija teplovogo vzryva tjena s nanochasticami medi na raznyh dlinah voln. Mezhdunarodnoe nauchnoe izdanie Sovremennye fundamental’nye i prikladnye issledovanija, 4(11), P. 68–75 (2013).

13. Zolotarev V.M., Morozov V.N., Smirnova E.V. Opticheskie postojannye prirodnyh i tehnicheskih sred. L.: Himija, 216 p. (1984).

14. Aduev B.P., Nurmukhametov D.R., et al. Integrating Sphere Study of the Optical Properties of Aluminum Nanoparticles in Tetranitropentaerytrite. Zhurnal Tekhnicheskoi Fiziki, 84(9), P. 126–131 (2014).

15. Kriger V.G., Kalenskii A.V., Zvekov A.A., Zykov I.Yu., Nikitin A.P. Protsessy teploperenosa pri lazernom razogreve vklyucheny v inertnoy matritse. Teplofizika i aeromekhanika, 20(3), P. 375–382 (2013).

16. Aleksandrov E. I., Cipilev V. P. Issledovanie vlijanija dlitel’nosti vozbuzhdajushhego impul’sa na chuvstvitel’nost’ azida svinca k dejstviju lazernogo izluchenija. Fizika goreniya i vzryva, 20(6), P. 104–108 (1984).

17. Burkina R.S., Morozova E.Ju., Cipilev V.P. Iniciirovanie reakcionno-sposobnogo veshhestva potokom izluchenija pri pogloshhenii ego neodnorodnostjami veshhestva. Fizika goreniya i vzryva, 47(5), P. 95–105 (2011).


Review

For citations:


Kalenskii A.V., Ananyeva M.V. Spectral regularities of the critical energy density of the pentaerythriol tetranitrate-aluminum nanosystems initiated by the laser pulse. Nanosystems: Physics, Chemistry, Mathematics. 2014;5(6):803-810.

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ISSN 2220-8054 (Print)
ISSN 2305-7971 (Online)