Sorption and liquid chromatographic separation of light fullerenes C60 and C70 with multiwall carbon nanotubes
Abstract
Isotherms for the sorption of light fullerenes (C60 and C70) from toluene solutions with the use of multiwall carbon nanotubes (MWCNTs) were investigated. Both isotherms are of the Langmuir-type. The successful liquid chromatographic separation of light fullerenes from toluene solutions was accomplished using the above-mentioned sorbent.
Keywords
Supporting agencies: Authors are grateful to the Russian Found of Fundamental Researches for the support (Project N 09-03-00350-a).
About the Authors
V. N. Postnov
Saint Petersburg State Technological Institute (Technical University)
Russian Federation
Russian Federation
Saint Petersburg
A. Ya. Scaletckaya
Saint Petersburg State Technological Institute (Technical University),
Russian Federation
Russian Federation
Saint Petersburg
O. A. Krokhina
Saint Petersburg State University
Russian Federation
Russian Federation
Saint Petersburg
V. A. Keskinov
Saint Petersburg State Technological Institute (Technical University)
Russian Federation
Russian Federation
Saint Petersburg
N. A. Charykov
Saint Petersburg State Technological Institute (Technical University)
Russian Federation
Russian Federation
Saint Petersburg
K. N. Semenov
Saint Petersburg State University
Russian Federation
Russian Federation
Saint Petersburg
References
1. K. Semenov, N. Charykov. Solubility of Light Fullerenes and Derivatives. LAP LAMBERT Academic Publishing GmbH & Co. KG, Saarbr¨ucken, Germany, 238 pp. (2011).
2. Semenov K. N., Charykov N.A. Phase Equilibria in the Fullerene-Containing Systems. Handbook on Fullerene: Synthesis, Properties and Applications. P. 1-91 (2012).
3. Semenov K.N., Charykov N.A.Solubility of Light Fullerenes and Fullerenol in Biocompatible with Human Beings Solvents. Chapter in Handbook: Grapes: Cultivation, Varieties and Nutritional Uses, Nova Sciences Publishers, Inc., P. 1–48 (2011).
4. K.N. Semenov, N.A. Charykov, V.A. Keskinov, et al. Solubility of Light Fullerenes in Organic Solvents. J. Chem. Eng. Data, 55, P. 13–36 (2010).
5. L.N. Sidorov, M.A. Yurovskaya, et al. Fullerenes. Ekzamen, Moscow, 688 pp. (2005).
6. A.A. Blokhin, V.A. Keskinov, Yu.V. Murashkin, et al. Method for chromatographic separation of fullerenes. Patent RF 2302372, C01B 31/02 (2007).
7. N.N. Ermilov, N.A. Charykov, et al. Nanotechnology — from theory to practical application. Journal of Innovations (rus.), 12, P.79–83 (2007).
8. N.A. Charykov, V.V. Zuev, E.A. Kuznetsova. High-efficiency complex for fullerenes production. Petersburg Electronics Journal, 4, P. 16–31 (2007).
9. V.A. Keskinov, N.A. Charykov, M.V. Keskinova, et al. Pre-chromatography crude separation of light fullerenes by poly-thermal re(crystallization) method. Nanosystems: Physics, Chemistry, Mathematics, 4(3), P. 344–351 (2013).
Review
For citations:
Postnov V.N., Scaletckaya A.Ya., Krokhina O.A., Keskinov V.A., Charykov N.A., Semenov K.N. Sorption and liquid chromatographic separation of light fullerenes C60 and C70 with multiwall carbon nanotubes. Nanosystems: Physics, Chemistry, Mathematics. 2013;4(5):706–715.
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