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Concentration dependence of electric conductivity and pH for aqueous solutions of water-soluble light fullerene - C60[=C(COOH)2]3 tris-malonate

Аннотация

 

Studies of the concentration dependence of electric conductivity and pH for aqueous solutions of the light fullerene – C60[=C(COOH)2]3 tris-malonate were performed at 25 ◦C. From both data (from the equivalent electric conductivity and pH), the apparent degree of dissociation and concentration dissociation constants of C60[=C(COOH)2]3 in aqueous solutions were calculated. Thermodynamic dissociation constants of C60[=C(COOH)2]3 in aqueous solutions, calculated for infinitely dilute solutions by the both methods, were reasonably similar.

Об авторах

K. Semenov
St. Petersburg State University
Россия


N. Charykov
St. Petersburg State Technological Institute (Technical University); St. Petersburg State Electro-Technical University (LETI)
Россия


A. Kritchenkov
St. Petersburg State University
Россия


I. Cherepkova
St. Petersburg State Technological Institute (Technical University)
Россия


O. Manyakina
St. Petersburg State Technological Institute (Technical University)
Россия


D. Tyurin
St. Petersburg State Technological Institute (Technical University)
Россия


A. Shestopalova
St. Petersburg State Technological Institute (Technical University)
Россия


V. Keskinov
St. Petersburg State Technological Institute (Technical University)
Россия


E. Kulenova
D. Serikbayev East-Kazakhstan state technical university
Казахстан


K. Ivanova
St. Petersburg State Technological Institute (Technical University)
Россия


N. Ivanova
St. Petersburg State University
Россия


D. Letenko
St. Petersburg State University Architecture Academy
Россия


V. Nikitin
St. Petersburg State Technical University
Россия


E. Fokina
St. Petersburg State University
Россия


Список литературы

1. K.N.Semenov, N.A.Charykov, A.S.Kritchenkov et al. Synthesis and identification water-soluble tris-malonate of light fullerene – C60[=C(COOH)2]3. Nanosystems: Physics, Chemistry, Mathematics, 5 (2), P. 315–319 (2014).

2. K.N.Semenov, N.A.Charykov, A.S.Kritchenkov et al. Volume properties of water solutions and refraction at 25 ◦C water soluble tris-malonate of light fullerene – C60[=C(COOH)2]3. Nanosystems: Physics, Chemistry, Mathematics, 5 (3), P. 427–434 (2014).

3. K.N.Semenov, N.A.Charykov, A.S.Kritchenkov et al. Poly-thermal solubility and complex thermal analysis of water soluble tris-malonate of light fullerene – C60[=C(COOH)2]3. Nanosystems: Physics, Chemistry, Mathematics. 5 (3), P. 435–440 (2014).

4. I. Lamparth, A. Hirsch. Water-soluble malonic acid derivatives of C60 with a defined three-dimensional structure. J. Chem. Soc Chem. Commun., 14, P. 1727–1728 (1994).

5. A.L. Horvath. Handbook of aqueous electrolyte solutions: physical properties, estimation and correlation methods. Ellis Horwood series in physical chemistry. Chichester: Halsted Press, 631 pp. (1985).

6. A.G. Stromberg, D.P. Semchenko. Physical Chemistry. Handbook for Chemical Specialists of Institutes. Moscow: High School, 527 pp. (1999).


Рецензия

Для цитирования:


 ,  ,  ,  ,  ,  ,  ,  ,  ,  ,  ,  ,  ,   . Наносистемы: физика, химия, математика. 2014;5(5):709-717.

For citation:


Semenov K.N., Charykov N.A., Kritchenkov A.S., Cherepkova I.A., Manyakina O.S., Tyurin D.P., Shestopalova A.A., Keskinov V.A., Kulenova E.A., Ivanova K.V., Ivanova N.M., Letenko D.G., Nikitin V.A., Fokina E.L. Concentration dependence of electric conductivity and pH for aqueous solutions of water-soluble light fullerene - C60[=C(COOH)2]3 tris-malonate. Nanosystems: Physics, Chemistry, Mathematics. 2014;5(5):709-717.

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ISSN 2220-8054 (Print)
ISSN 2305-7971 (Online)