The features of formation and modification of nanostructured films of carbon nitride
Abstract
The aim of this work was to obtain and experimental study of carbon nitride films. Upon the methods of thermogravimetric analysis (TGA), optical spectroscopy and scanning electron microscopy it was found that diamond-like films CNX consist of two phases: a nanostructured and amorphous. It was discovered that short-term heat treatment of the diamond-like films in air at 610 K results in etching of the amorphous phase and the formation of a divided columnar nanostructures.
About the Authors
A. M. PrudnikovRussian Federation
Prudnikov Anatoliy, senior research, PhD
Personal address: Kommunal’naya str., 21, Donetsk 83087, Ukraine
Home phone number: (+380 62) 381 1197
Work phone number: (+380 62) 311 6801
Mobile phone number: (+380 50) 837 75 32
A. I. Linnik
Russian Federation
Linnik Alexey, senior research, PhD
Personal address: Tankernaya str., 41, Donetsk 83053, Ukraine
Home phone number: (+380 62) 207 3445
Work phone number: (+380 62) 311 5263
Mobile phone number: (+380 62) 207 3445
R. V. Shalaev
Russian Federation
V. V. Rumyantsev
Russian Federation
Rumyantsev Vladimir, head of physics technology department, PhD, Dr Sci, professor
Personal address: Armavirskaya str., 26-31, Donetsk 83044, Ukraine
Home phone number: (+380 62) 222 34 02
Work phone number: (+380 62) 311 52 77
Mobile phone number: (+380 95) 793 11 35
A. O. Kucherik
Russian Federation
A. P. Alodjants
Russian Federation
Alodjants Alexander, Professor, Doctor of science, associate professor
Personal address: 4а Nikitina Str., Apt. 8, Vladimir
Home phone number: (4922)447197
Work phone number: (4922)479947
Mobile phone number: 89038335390
S. M. Arakelian
Russian Federation
Arakelian Sergei, Professor, Doctor of science
Personal address: 2 Mira Str., Apt. 29, Vladimir.
Home phone number: (4922)367022
Work phone number: (4922)233358
References
1. Нечаев Ю.С. О природе, кинетике и предельных значениях сорбции водорода углеродными наноструктурами. УФН, 2006, 176, № 6, 581-610.
2. Аракелян С.М., Герке М.Н., Кутровская С.В., Кучерик А.О., Прокошев В.Г. Формирование углеродных субмикронных и наноструктур на поверхности холодной подложки при воздействии лазерного излучения на поверхность углеродосодержащих материалов в атмосферном воздухе. Квантовая электроника, 2008, Т. 38.(1), 73-76.
3. Антипов А.А., Аракелян С.М., Кутровская С.В., Кучерик А.О., Осипов А.В., Прокошев В.Г., Щекин А.А. Лазерный синтез углеродных нановолокон и нанокластеров. Российские нанотехнологии, 2011, 6, 3-4.
4. Gago R., Abrasonis G., Mücklich A., Möller W., Czigány Zs., and Radnóczi G. Fullerenelike arrangements in carbon nitride thin films grown by direct ion beam sputtering. Appl. Phys. Let.,2005, 87, 071901.
5. Shalaev R., Ulyanov A., Prudnikov A., Shin G., Yoo S., Varyukhin V. Noncatalytic synthesis of car-bon-nitride nanocolumns by dc magnetron sputtering . Phys. Status Solidi A., 2010, Vol. 207, No. 10, 2300–2302.
6. Alibart F., Durand Drouhin O., Lejeune M., Benlahsen M., Rodil S.E., Camps E. Evolution of the opto-electronic properties of amorphous carbon films as a function of nitrogen incorporation. Diamond & Related Materials, 2008, 17, 925-930.
7. Musso S., Giorcelli M., Pavese M., Bianco S., Rovere M., Tagliaferro A. Improving macroscopic physical and mechanical properties of thick layers of aligned multiwall carbon nanotubes by annealing treatment. Diamond and Related Materials, 2008, 17, 542-547.
8. Mori Shinsuke, Suzuki Masaaki. Effect of oxygen and hydrogen addition on the low-temperature synthesis of carbon nanofibers using a low-temperature CO/Ar DC plasma. Diamond and Related Materials, 2008, 17, 999-1002.
9. Shalaev R.V., Varyukhin V.N., Prudnikov A.M., Linnik A.I., Zhikharev I.V., Belousov N.N., Raspornya D.V., Ulyanov A.N. Influence of intensive etching processes on structure and properties of carbon nitride films. Functional Materials, 2008, V.15, 580–584.
10. Se Yun Kim, Hyun Seok Kim, Saji Augustine, and Jeung Ku Kang. Nanopores in carbon nitride nanotubes: Reversible hydrogen storage sites. Appl. Phys. Let., 2006, V.89, 253119–253121.
11. Sang Kyu Choi, Kyoung-Yong Chun, Seung-Beck Lee. Selective decoration of silver nanoparticles on the defect sites of single-walled carbon nanotubes. Diamond & Related Materials, 2009, V.18, 637–641.
12. Ferrari A.C., Meyer J.C., Scardaci V., Casiraghi C., Lazzeri M., Mauri F., Piscanec S., Jiang O., Novoselov K.S., Roth S., Geim A.K. Raman spectrum of grapheme layers. Phys Rev B., 2006, 97, 187401.
13. Tuinstra F., Koenig J. Raman spectrum of graphite. J. Chem. Phys., 1970, 53, 1126
14. Ferrari A.C., Robertson J. Interpretation of Raman spectra of disordered and amorphous carbon. Phys. Rev. B, 2000, 61, 14095.
Review
For citations:
Prudnikov A.M., Linnik A.I., Shalaev R.V., Rumyantsev V.V., Kucherik A.O., Alodjants A.P., Arakelian S.M. The features of formation and modification of nanostructured films of carbon nitride. Nanosystems: Physics, Chemistry, Mathematics. 2012;3(6):134-145. (In Russ.)