Hierarchically porous graphene in natural graphitic globules from silicate magmatic rocks
Abstract
Naturally-occurring nanostructured graphites from silicate magmatic rocks, which are rare, were characterized using electron microscope and X-ray spectroscopy. This graphite consists of porous carbon, nanographite layers, micro- and nanotubes. The porous carbon is classified as macroporous matter with a small amount of mezopores. Evidence for the unusual properties of porous carbon are given: nanographite layers are created at the exposed surface of sample and the nanotubes occurs in the bulk of porous carbon.
About the Authors
V. A. PonomarchukRussian Federation
Novosibirsk
A. T. Titov
Russian Federation
Novosibirsk
T. N. Moroz
Russian Federation
Novosibirsk
A. N. Pyryaev
Russian Federation
Novosibirsk
A. V. Ponomarchuk
Russian Federation
Novosibirsk
References
1. H.W. Kroto, J.R. Heath, S.C. O’Brien, R.F. Curl, R.E. Smalley. C60: Buckminsterfullerene. Nature, 318, P. 162 (1985).
2. S. Lijima. Helical microtubules of graphitic carbon. Nature, 354, P. 56–58 (1991).
3. L.V. Radushkevich, V.M. Lukyanovich. The structure of carbon formed by thermal decomposition of carbon oxide on an iron contact. Journal of Physical Chemistry, 26, P. 88–95 (1952).
4. S.M. Manocha. Porous carbons. Sadhana, 28, P. 335–348 (2003).
5. M. Paradise, T. Goswami. Carbon nanotubes – Production and industrial applications. Materials and Design, 28, P. 1477–1489 (2007).
6. Yu.E. Lozovik, A.M. Popov. Formation and growth of carbon nanostructures: fullerenes, nanoparticles, nanotubes and cones. Phys. Usp, 40, P. 717–737 (1997).
7. A.V. Eletskii. Carbon nanotubes. Phys. Usp, 40, P. 899–924 (1997).
8. G.D. Nessim. Properties, synthesis, and growth mechanisms of carbon nanotubes with special focus on thermal chemical vapor deposition. Nanoscale, 2, P. 1306–1323 (2010).
9. S.K. Simakov, A.A. Grafchikov, A.K. Sirotkin, I.A. Drozdova, E.A. Grebenshchikova, A.E. Lapshin. Synthesis of carbon nanotubes and fullerite structures at PT parameters corresponding to natural mineral formation. Doklady Earth Sciences, 376, P. 87–89 (2001).
10. J.A. Jasczak, S. Dimovski, S.A. Hackney. Micro- and nano-scale graphite cones and tubes from Hackman Valley, Kola Peninsula, Russia. Canad. Mineralogist, 45, P. 379–389 (2007).
11. V.V. Ryabov, A.J. Shevko, M.P. Gore. Magmatic formations of Norilsk region. Petrology of the trapps. Atlas of igneous rocks. Nonpareil, Novosibirsk, 408 p. (2000).
12. V.V. Ryabov, V.A. Ponomarchuk, A.T. Titov, D.V. Semenova. Micro- and Nanostructures of Carbon in Pt–Low-Sulfide Ores of the Talnakh Deposit (Siberian Platform). Doklady Earth Sciences, 446(2), P. 1193–1196 (2012).
13. V.A. Ponomarchuk, Y.P. Kolmogorov, V.V. Ryabov, A.T. Titov, T.N. Moroz, D.V. Semenova, A.N. Pyryaev, A.V. Ponomarchuk. SR XRF Study of Natural Micro- and Nanostructured Carbon from Igneous Rocks. Bulletin of the Russian Academy of Sciences. Physics, 77(2), P. 203–206 (2013).
14. M.J. Allen, V.C. Tung, R.B. Kaner. Honeycomb Carbon: A Review of Graphene. Chem. Rev., 110(1), P. 132–145 (2010).
15. M.M. Dubinin. The potential theory of adsorption of gases and vapors for adsorbents with energetically nonuniform surfaces. Chem Rev., 60, P. 235–241 (1960).
16. IUPAC Manual of Symbols and Terminology, Appendix 2, Pt. 1, Colloid and Surface Chemistry. Pure Appl. Chem., 31, P. 578 (1972).
17. H. Gleiter. Nanostructured materials: basic concepts and microstructure. Acta Materialia, 48(1), P. 1-29 (2000).
18. R.T.K. Baker. Catalytic growth of carbon filaments. Carbon, 27, P. 315–323 (1989).
19. V.Z. Mordkovich. Carbon Nanofibers: A New Ultrahigh-Strength Material for Chemical Technology. Theoretical Foundations of Chemical Engineering, 37(5), P. 429–438 (2003).
20. M.A. Pimenta, G. Dresselhaus, M.S. Dresselhaus, L.G. Cancado, A. Jorioa, R. Saitoe. Studying disorder in graphite-based systems by Raman spectroscopy. Phys.Chem.Chem.Phys., 9, P. 1276–1291 (2007).
21. O. Beyssac, B. Goffe, C. Chopin, J.N. Rouzaud. Raman spectra of carbonaceous material in metasediments: a new geothermometer. J. metamorphic Geol., 20, P. 859–871 (2002).
22. S.S. Bukalov, L.A. Mikhalicin, Ya.V. Zubavichus, L.A. Leytis, U.N. Novikov. Structure investigation of graphites and some another sp2 carbonic materials using micro-, Raman spectroscopy and X-ray diffraction methods. Ros. Chem. J., L(1), P. 83–91 (2006).
Review
For citations:
Ponomarchuk V.A., Titov A.T., Moroz T.N., Pyryaev A.N., Ponomarchuk A.V. Hierarchically porous graphene in natural graphitic globules from silicate magmatic rocks. Nanosystems: Physics, Chemistry, Mathematics. 2014;5(1):123-129.