Volume properties of water solution and refraction at 25 oC water-soluble tris-malonate of light fullerene- C60[=C(COOH)2]3
Abstract
The volume Properties of water soluble tris-malonate of light fullerene — C60[=C(COOH)2]3 were investigated with the help of quartz pycnometers at 25 ◦C, including the concentration dependence of density, average molar volume of the solutions and partial molar volumes of C60[=C(COOH)2]3 and H2O. Concentration dependence of the refraction index in water solutions of C60[=C(COOH)2]3 was also determined with the help of refractometer, specific and molar refraction of the components were calculated with the help of the rules of the additive refraction of solution components.
About the Authors
K. N. SemenovRussian Federation
Saint-Petersburg
N. A. Charykov
Russian Federation
Saint-Petersburg
A. S. Kritchenkov
Russian Federation
Saint-Petersburg
I. A. Cherepkova
Russian Federation
Saint-Petersburg
O. S. Manyakina
Russian Federation
Saint-Petersburg
D. P. Tyurin
Russian Federation
Saint-Petersburg
A. A. Shestopalova
Russian Federation
Saint-Petersburg
V. A. Keskinov
Russian Federation
Saint-Petersburg
K. V. Ivanova
Russian Federation
Saint-Petersburg
N. M. Ivanova
Russian Federation
Saint-Petersburg
D. G. Letenko
Russian Federation
Saint-Petersburg
V. A. Nikitin
Russian Federation
Saint-Petersburg
E. L. Fokina
Russian Federation
Saint-Petersburg
O. V. Rakhimova
Russian Federation
Saint-Petersburg
References
1. K.N.Semenov, N.A.Charykov, A.S.Kritchenkov, et al. Synthesis and identification water-soluble tris-malonate of light fullerene – C60[=C(COOH)2]3. Nanosystems: Physics, Chemistry, Mathematics, 5 (2), P. 315–319 (2014).
2. I.Lamparth, A.Hirsch. Water-soluble malonic acid derivatives of C60 with a defined three-dimensional structure. J. Chem. Soc Chem. Commun., P. 1727–1728 (1994).
3. A.V.Storonkin. Thermodynamics of Heterogeneous Systems. Rus. Leningrad: LGU, Book 1, Part 1, 2. 467 pp. (1967).
4. A.Muenster. Chemical thermodynamics. Rus. Transl. from Engl. Moscow: Mir (1971).
5. Atomic refractions according to Fogel. Directory of Chemist/ red. B.P. Nikol’skiy. Rus. Leningrad: Chemistry, 1, 395 pp. (1982).
Review
For citations:
Semenov K.N., Charykov N.A., Kritchenkov A.S., Cherepkova I.A., Manyakina O.S., Tyurin D.P., Shestopalova A.A., Keskinov V.A., Ivanova K.V., Ivanova N.M., Letenko D.G., Nikitin V.A., Fokina E.L., Rakhimova O.V. Volume properties of water solution and refraction at 25 oC water-soluble tris-malonate of light fullerene- C60[=C(COOH)2]3. Nanosystems: Physics, Chemistry, Mathematics. 2014;5(3):427-434.