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Volume properties of water solution and refraction at 25 oC water-soluble tris-malonate of light fullerene- C60[=C(COOH)2]3

Abstract

The volume Properties of water soluble tris-malonate of light fullerene — C60[=C(COOH)2]3 were investigated with the help of quartz pycnometers at 25 ◦C, including the concentration dependence of density, average molar volume of the solutions and partial molar volumes of C60[=C(COOH)2]3 and H2O. Concentration dependence of the refraction index in water solutions of C60[=C(COOH)2]3 was also determined with the help of refractometer, specific and molar refraction of the components were calculated with the help of the rules of the additive refraction of solution components.

About the Authors

K. N. Semenov
St. Petersburg State University
Russian Federation

Saint-Petersburg



N. A. Charykov
St. Petersburg State University; St. Petersburg State Technological Institute (Technical University)
Russian Federation

Saint-Petersburg



A. S. Kritchenkov
St. Petersburg State University
Russian Federation

Saint-Petersburg



I. A. Cherepkova
St. Petersburg State Technological Institute (Technical University)
Russian Federation

Saint-Petersburg



O. S. Manyakina
St. Petersburg State Technological Institute (Technical University)
Russian Federation

Saint-Petersburg



D. P. Tyurin
St. Petersburg State Technological Institute (Technical University)
Russian Federation

Saint-Petersburg



A. A. Shestopalova
St. Petersburg State Technological Institute (Technical University)
Russian Federation

Saint-Petersburg



V. A. Keskinov
St. Petersburg State Technological Institute (Technical University)
Russian Federation

Saint-Petersburg



K. V. Ivanova
St. Petersburg State Technological Institute (Technical University)
Russian Federation

Saint-Petersburg



N. M. Ivanova
St. Petersburg State University
Russian Federation

Saint-Petersburg



D. G. Letenko
St. Petersburg State University Architecture Academy
Russian Federation

Saint-Petersburg



V. A. Nikitin
St. Petersburg State Technical University
Russian Federation

Saint-Petersburg



E. L. Fokina
St. Petersburg State University
Russian Federation

Saint-Petersburg



O. V. Rakhimova
St. Petersburg State Electro-Technical University (LETI)
Russian Federation

Saint-Petersburg



References

1. K.N.Semenov, N.A.Charykov, A.S.Kritchenkov, et al. Synthesis and identification water-soluble tris-malonate of light fullerene – C60[=C(COOH)2]3. Nanosystems: Physics, Chemistry, Mathematics, 5 (2), P. 315–319 (2014).

2. I.Lamparth, A.Hirsch. Water-soluble malonic acid derivatives of C60 with a defined three-dimensional structure. J. Chem. Soc Chem. Commun., P. 1727–1728 (1994).

3. A.V.Storonkin. Thermodynamics of Heterogeneous Systems. Rus. Leningrad: LGU, Book 1, Part 1, 2. 467 pp. (1967).

4. A.Muenster. Chemical thermodynamics. Rus. Transl. from Engl. Moscow: Mir (1971).

5. Atomic refractions according to Fogel. Directory of Chemist/ red. B.P. Nikol’skiy. Rus. Leningrad: Chemistry, 1, 395 pp. (1982).


Review

For citations:


Semenov K.N., Charykov N.A., Kritchenkov A.S., Cherepkova I.A., Manyakina O.S., Tyurin D.P., Shestopalova A.A., Keskinov V.A., Ivanova K.V., Ivanova N.M., Letenko D.G., Nikitin V.A., Fokina E.L., Rakhimova O.V. Volume properties of water solution and refraction at 25 oC water-soluble tris-malonate of light fullerene- C60[=C(COOH)2]3. Nanosystems: Physics, Chemistry, Mathematics. 2014;5(3):427-434.

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ISSN 2220-8054 (Print)
ISSN 2305-7971 (Online)