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Electro chemical and photo catalytic studies of MnO2 nanoparticle from waste dry cell batteries

https://doi.org/10.17586/2220-8054-2016-7-4-657-661

Abstract

The objective of the existing research was essentially focused on recovery of MnO2 nanoparticles from consumed dry cells by employing adapted hydrometallurgical process. Experimental tests for the recovery of MnO2 present in the dry cell batteries have been carried out by an acidic reductive leachant, namely oxalic acid.  The elemental compositions of the recovered metals from dry cells were confirmed by Energy Dispersive X-ray analysis (EDAX). Surface morphology of the recovered metals was examined using Scanning Electron Microscopy (SEM). Phase composition of the recovered metals from dry cell batteries were confirmed from X-ray Diffract meter (XRD). Cyclic Voltammetry (CV) studies were carried out to clarify the reversibility of the reactions. The obtained MnO2 catalyst was applied for the degradation of different non-volatile dye compounds such as Indigo carmine (IC) and Rhodamine B (RB). The performance of MnO2 shows fast degradation of dyes of high concentration.

About the Authors

M. Mylarappa
AMC Engineering College; Tumkur University
India

Research Centre, Department of Chemistry, AMC Engineering College; Department of Studies and Research in Chemistry, Tumkur University

Bengaluru-560083, Karnataka;
Tumkur-572103, Karnataka



V. Venkata Lakshmi
AMC Engineering College
India

Research Centre, Department of Chemistry

Bengaluru-560083, Karnataka

 



K. R. Vishnu Mahesh
Dayananda Sagar College of Engineering
India

Bengaluru-560083, KarnatakaDepartment of Chemistry



H. P. Nagaswarupa
East West Institute of Technology
India

Research Centre, Department of Science

Bengaluru-560091, Karnataka



S. C. Prashantha
East West Institute of Technology
India

Research Centre, Department of Science

Bengaluru-560091, Karnataka



D. M. K. Siddeswara
East West Institute of Technology
India

Research Centre, Department of Science

Bengaluru-560091, Karnataka



N. Raghavendra
RV College of Engineering
Russian Federation

CMRTU

Bengaluru-560059, Karnataka



References

1. Gallegos M.V., Falco L.R., et al. Recovery of manganese oxides from spent alkaline and zinc-carbon batteries. An application as catalysts for VOCs elimination. Waste Management, 2013, 33, P. 1483–1490.

2. Sobianowska-Turek A., Szczepaniak W., Zablocka-Malicka M. Electrochemical evolution of reducers – Recovery of Mn from Zinc-Mn and Zinc-C battery waste. Journal of Power Sources, 2014, 270, P. 668–674.

3. Baba A.A., Adekola A.F., Bale R.B. Development of a combined pyro-and hydro-metallurgical route to treat spent Zinc-carbon batteries. Journal of power sources, 2009, 171, P. 838–844.

4. Macolino P., Manciulea A.L., et al. Manganese recovering from alkaline spent batteries by ammonium peroxodisulfate. Acta Metallurgica Slovaca, 2013, 19 (3), P. 212–222.

5. Andrade Tacca C.A., Duart M.M.E. Acid leaching and electrochemical recovery of manganese from spent alkaline batteries. 2nd Mercosur Congress on Chemical Engineering and 4th Mercosur Congress on Process Systems Engineering.

6. SiXu Deng, Dan Sun, et al. Synthesis and electrochemical properties of MnO2 nanorods/graphene composites for supercapacitor applica- tions. Electrochimica Acta, 2013, 111, P. 707–712.

7. Devreese J.T., Evrard R.P., Van Doren V.E. Highly Conducting One-DimensionalSolids. Plenum, New York, 1979.

8. Pandey B.K., Shahi A.K., Gopal R. Synthesis, optical properties and growth mechanism of MnO nano structures. Applied Surface Science, 2013, 283, P. 430–437.

9. Kursunoglu S., Kavya M. Dissolution and precipitation of Zinc and Manganese obtained from spent Zinc-carbon and alkaline battery powder. Physicochem. Probl. Miner Process, 2014, 50, P. 39–53.

10. Buzatu M., Aceanu S.S., et al. Recovery of zinc and manganese from spent batteries by reductive leaching in acidic media. Journal of power sources, 2014, 247, P. 612–617.

11. Chanhlin Yu, Gao Li, et al. Fabrication,characterization of β-MnO2 micro rod catalysts and their performance in rapid degradation of dyes of high concentration. Catalysis Today, 2014, 224, P. 154–162


Review

For citations:


Mylarappa M., Venkata Lakshmi V., Vishnu Mahesh K.R., Nagaswarupa H.P., Prashantha S.C., Siddeswara D.M., Raghavendra N. Electro chemical and photo catalytic studies of MnO2 nanoparticle from waste dry cell batteries. Nanosystems: Physics, Chemistry, Mathematics. 2016;7(4):657-661. https://doi.org/10.17586/2220-8054-2016-7-4-657-661

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ISSN 2220-8054 (Print)
ISSN 2305-7971 (Online)