Preview

Nanosystems: Physics, Chemistry, Mathematics

Advanced search

Effect of oxide composition (V2O5+Al2O3) via gas phase on the thermal oxidation of InP

Abstract

 The effect of the oxide-chemostimulator V2O5 and the inert component Al2O3 binary compositions on the thermal oxidation of InP have been studied. The area of negative deviation of nanoscale oxide film thickness on InP from the additive joint effect has been established with a minimum for a composition of 20% Al2O3 + 80% V2O5. A decrease in the transit efficiency effect of V2O5 chemostimulator in composition with Al2O3 has been associated with an intensification of the transformation of V2O5 into V2O3, which is not an oxygen transitor.

About the Authors

B. V. Sladkopevtcev
Voronezh State University
Russian Federation

Voronezh



N. N. Tretyakov
Voronezh State University
Russian Federation

Voronezh



A. I. Dontsov
Voronezh State University
Russian Federation

Voronezh



E. V. Tomina
Voronezh State University
Russian Federation

Voronezh



I. Ya. Mittova
Voronezh State University
Russian Federation

Voronezh



References

1. P.K. Penskoi, V.F. Kostryukov, V.R. Pshestanchik, I.Ya. Mittova. Joint effect of chemostimulator (Sb2O3, Bi2O3, MnO2) compositions with an inert component (Al2O3) on gallium arsenide thermal oxidation. Doklady Chemistry, 414 (2), P. 152–154 (2007).

2. I.Ya. Mittova, E.V. Tomina, et al. Thermal oxidation of InP surfaces modified with NiO + PbO mixtures. Inorganic Materials, 41 (4), P. 323–330 (2005).

3. P.K. Penskoi, V.F. Kostryukov, et al. Effect of inert components (Y2O3, Al2O3, and Ga2O3) on the chemistim ulating effect of the Sb2O3 activator of GaAs thermal oxidation. Russian Journal of Inorganic Chemistry, 54 (10), P. 1564–1570 (2009).

4. T.V. Kozhevnikova, P.K. Penskoi, et al. Role of an inert component in compositions with manganese(II) and manganese(IV) oxides in studying nonlinear effects in GaAs thermal oxidation. Russian Journal of Inorganic Chemistry, 55 (12), P. 1857–1862 (2010).

5. I.Ya. Mittova, V.R. Pshestanchik. The chemistry of processes which create dielectric layers with functional group substituents on semiconductors by impurity thermo-oxidation. Russian chemical reviews, 60 (9), P. 967 979 (1991).

6. M. Yamaguchi. Thermal oxidation of InP and properties of oxide films. Journal of Applied Physics, 51 (9), P. 5007–5012 (1980).

7. V.M. Ievlev, A.A. Samsonov, et al. Catalytic effect of a nanolayer of the (V2O5 + PbO) composite in the thermal oxidation of InP crystals. Doklady Chemistry, 417 (2), P. 277–281 (2007).

8. I.Ya. Mittova, E.V. Tomina, A.A. Lapenko, B.V. Sladkopevtsev. Synthesis and catalytic performance of V2O5 nanoislands produced on the surface of InP crystals by electroexplosion. Inorganic Materials, 46 (4), P. 383 388 (2010).

9. I.Ya. Mittova, E.V. Tomina, A.A. Lapenko, A.O. Khorokhordina. Solid-state reactions during thermal oxidation of vanadium-modified GaAs surfaces. Inorganic Materials, 40 (5), P. 441–444 (2004).

10. Phase diagrams of refractory oxides: Handbook. Nauka, Leningrad, P. 1–2, (1986).

11. I.Ya. Mittova, V.R. Pshestanchik, V.F. Kostryukov. Alternating nonlinearity of the joint activating effect of binary mixtures of p-element oxides on the chemically activated thermal GaAs oxidation. Doklady Chemistry, 378 (4–6), P. 165–167 (2001).

12. E.K. Kazenas, Y.V. Tsvetkov. Thermodynamics of evaporation of oxides. LKI, Moscow, 474 pp. (2007).

13. I.Ya. Mittova, B.V. Sladkopevtsev, E.V. Tomina, A.I. Dontsov. Effect of V2O5 nanoislands on the surface composition and structure of InP during thermal oxidation. Inorganic Materials, 47 (8), P. 811–815 (2011).

14. I.Ya. Mittova, G.V. Borzakova, V.A. Terekhov. Growth of native oxide layers on indium phosphide. Izv. Akad. Nauk SSSR, Inorganic Materials, 27 (10), P. 2047–2051 (1991).

15. A.A. Fotiev. Vanadates. Composition, synthesis, structure, properties. Nauka, Moscow, 272 pp. (2008).

16. O.V. Krilov, B.R. Shub. Nonequilibrium processes in catalysis. Chimiya, Moscow, 284 pp. (1990).

17. I.Ya. Mittova, E.V. Tomina, A.A. Lapenko, B.V. Sladkopevtsev. The catalytic action of vanadium and its ox ides (V) in the oxidation process of AIIIBV semiconductors. Nanosystems: physics, chemistry, mathematics, 3 (2), P. 116–138 (2012).


Review

For citations:


Sladkopevtcev B.V., Tretyakov N.N., Dontsov A.I., Tomina E.V., Mittova I.Ya. Effect of oxide composition (V2O5+Al2O3) via gas phase on the thermal oxidation of InP. Nanosystems: Physics, Chemistry, Mathematics. 2013;4(2):260-268.

Views: 4


Creative Commons License
This work is licensed under a Creative Commons Attribution 4.0 License.


ISSN 2220-8054 (Print)
ISSN 2305-7971 (Online)