Hydrophobization of up-conversion luminescent films based on nanocellulose/MF2:Ho particles (M = Sr, Ca) by acrylic resin
https://doi.org/10.17586/2220-8054-2019-10-5-585-598
Abstract
Luminescent hydrophobic composite films based on nanocrystalline (CNC) and nanofibrillated (CNF) cellulose matrix with up-conversion MF2:Ho (M = Ca, Sr) particles and acrylic resin (ACR) as a coating have been synthesized. Flexible, translucent composite films were obtained by molding from the CNC/CNF suspensions with up-conversion particles. ACR coating was applied to the composite film by spraying. Studies have shown that ACR coating with a layer thickness of 7 – 10 γm provides hydrophobic properties for the films, increasing the water contact angle up to 100 ± 2° with a simultaneous improvement in the luminescent properties. Transparency of CNC/CNF/MF2:Ho-ACR films in the visible and near IR region improves by 20 – 25 % without compromising the flexibility and thermal stability. The manufactured water-resistant composite films can be utilized as potential photonics materials, in particular for visualization of near-IR laser radiation and luminescent labels.
Keywords
cellulose nanocrystals,
cellulose nanofibrils,
nanocomposites,
hydrophobicity,
acrylic resins,
SrF2:Ho,
CaF2:Ho,
up-conversion luminescence films
Supporting agencies: The study was funded by the Russian Foundation for Basic Research (RFBR 16-29-11784-ofi-m).
About the Authors
A. A. Luginina
Prokhorov General Physics Institute of the Russian Academy of Sciences
Russian Federation
Russian Federation
A.A. Luginina
Vavilov str. 38, Moscow, 119991
S. V. Kuznetsov
Prokhorov General Physics Institute of the Russian Academy of Sciences
Russian Federation
Russian Federation
S.V. Kuznetsov
Vavilov str. 38, Moscow, 119991
V. V. Voronov
Prokhorov General Physics Institute of the Russian Academy of Sciences
Russian Federation
Russian Federation
V.V. Voronov
Vavilov str. 38, Moscow, 119991
A. D. Yapryntsev
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
Russian Federation
Russian Federation
A. D. Yapryntsev
Leninskii prosp. 31, Moscow, 119991
V. K. Ivanov
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
Russian Federation
Russian Federation
V. K. Ivanov
Leninskii prosp. 31, Moscow, 119991
D. I. Petukhov
Lomonosov Moscow State University, Chemical department
Russian Federation
Russian Federation
D. I. Petukhov
Leninskie Gory str. 1, Moscow, 119991
A. A. Lyapin
Ogarev Mordovia State University
Russian Federation
Russian Federation
A. A. Lyapin
Bolshevistskaya str. 68, Saransk, 430005
A. S. Ermakov
Ogarev Mordovia State University
Russian Federation
Russian Federation
A. S. Ermakov
Bolshevistskaya str. 68, Saransk, 430005
D. V. Pominova
Prokhorov General Physics Institute of the Russian Academy of Sciences
Russian Federation
Russian Federation
D.V. Pominova
Vavilov str. 38, Moscow, 119991
E. V. Chernova
Prokhorov General Physics Institute of the Russian Academy of Sciences
Russian Federation
Russian Federation
E.V. Chernova
Vavilov str. 38, Moscow, 119991
A. A. Pynenkov
Ogarev Mordovia State University
Russian Federation
Russian Federation
A. A. Pynenkov
Bolshevistskaya str. 68, Saransk, 430005
K. N. Nishchev
Ogarev Mordovia State University
Russian Federation
Russian Federation
K. N. Nishchev
Bolshevistskaya str. 68, Saransk, 430005
P. P. Fedorov
Prokhorov General Physics Institute of the Russian Academy of Sciences
Russian Federation
Russian Federation
P. P. Fedorov
Vavilov str. 38, Moscow, 119991
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For citations:
Luginina A.A., Kuznetsov S.V., Voronov V.V., Yapryntsev A.D., Ivanov V.K., Petukhov D.I., Lyapin A.A., Ermakov A.S., Pominova D.V., Chernova E.V., Pynenkov A.A., Nishchev K.N., Fedorov P.P. Hydrophobization of up-conversion luminescent films based on nanocellulose/MF2:Ho particles (M = Sr, Ca) by acrylic resin. Nanosystems: Physics, Chemistry, Mathematics. 2019;10(5):585-599. https://doi.org/10.17586/2220-8054-2019-10-5-585-598
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