Self-cleaning nanocomposite membranes based on sulfonated tetrafluoroethylene and g-C3N4 for water purification
https://doi.org/10.17586/2220-8054-2025-16-4-510-520
Abstract
Water contamination from industrial effluents is a significant environmental challenge due to the presence of organic dyes. This study presents the development of self-cleaning nanocomposite membranes based on sulfonated tetrafluoroethylene and 2D graphitic carbon nitride (g-C3N4) nanosheets for efficient water purification. The membranes were synthesized using solution casting with 1 and 5 wt. % g-C3N4 as a photocatalytic filler. A comprehensive physicochemical characterization was conducted using XRD, FTIR, SEM, DRS, and adsorption tests. The photocatalytic performance was assessed through the degradation of methylene blue under visible light. Results show that membranes with 5 wt. % g-C3N4 exhibit enhanced adsorption efficiency (k = 0.0800 min-1) and notable photocatalytic activity (k = 0.0083 min-1), leading to effective dye removal and self-cleaning functionality. These findings highlight the potential of hybrid polymer-nanomaterial membranes for sustainable wastewater treatment. The proposed membranes offer a promising solution for removing hazardous organic pollutants while maintaining long-term operational stability.
Keywords
About the Authors
M. I. ChebanenkoRussian Federation
Maria I. Chebanenko
Politechnicheskaya, 26, St. Petersburg, 194021, Russia
L. A. Lebedev
Russian Federation
Lev A. Lebedev
Politechnicheskaya, 26, St. Petersburg, 194021, Russia
M. I. Tenevich
Russian Federation
Maksim I. Tenevich
Politechnicheskaya, 26, St. Petersburg, 194021, Russia
K. D. Martinson
Russian Federation
Kirill D. Martinson
Politechnicheskaya, 26, St. Petersburg, 194021, Russia
O. N. Primachenko
Russian Federation
Oleg N. Primachenko
Bolshoy Prospekt of Vasilyevsky Island, 31, St. Petersburg 199004, Russia
S. V. Kononova
Russian Federation
Svetlana V. Kononova
Bolshoy Prospekt of Vasilyevsky Island, 31, St. Petersburg 199004, Russia
V. I. Popkov
Russian Federation
Vadim I. Popkov
Politechnicheskaya, 26, St. Petersburg, 194021, Russia
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For citations:
Chebanenko M.I., Lebedev L.A., Tenevich M.I., Martinson K.D., Primachenko O.N., Kononova S.V., Popkov V.I. Self-cleaning nanocomposite membranes based on sulfonated tetrafluoroethylene and g-C3N4 for water purification. Nanosystems: Physics, Chemistry, Mathematics. 2025;16(4):510-520. https://doi.org/10.17586/2220-8054-2025-16-4-510-520