Цеолит клиноптилолит, механохимически модифицированный полиэтиленгликолем для получения нефтесорбентов
https://doi.org/10.17586/2220-8054-2025-16-5-640-649
Аннотация
Исследовано влияние «мягкой» механохимической активации в воздушной атмосфере смеси клиноптилолит-цеолитовых пород с 10; 20 мас. % полиэтиленгликоля ПЭГ-4000 на структуру, физические и нефтеадсорбционные свойства. Дозы приложенной механической энергии составили 2,16 и 5,04 кДж/г. Показано, что клиноптилолитовая порода, модифицированная 10 мас. % полиэтиленгликоля при дозе механической энергии 5,04 кДж/г, и клиноптилолитовая порода, модифицированная 20 мас. % этого полимера при дозе энергии 2,16 кДж/г, имеют нефтеемкость на твердой поверхности 1,4 г/г. Установлено, что в ИКспектрах этих образцов отношение интенсивностей полос поглощения, обусловленных валентными колебаниями силоксановых и гидроксильных групп, составляет не менее 3,2, а пористость слоя - не менее 72 %. Выявлена корреляция между нефтеемкостью и содержанием полимера, пористостью, структурными изменениями.
Ключевые слова
Об авторе
О. Н. Дабижа
Transbaikal State University; Branch of the Petersburg Nuclear Physics Institute named by B.P. Konstantinov of National Research Centre “Kurchatov Institute” – Institute of Silicate Chemistry
Россия
Россия
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Для цитирования:
Дабижа О.Н. Цеолит клиноптилолит, механохимически модифицированный полиэтиленгликолем для получения нефтесорбентов. Наносистемы: физика, химия, математика. 2025;16(5):640-649. https://doi.org/10.17586/2220-8054-2025-16-5-640-649
For citation:
Dabizha O.N. Clinoptilolite zeolite mechanochemically modified with polyethylene glycol for the preparation of oil sorbents. Nanosystems: Physics, Chemistry, Mathematics. 2025;16(5):640-649. https://doi.org/10.17586/2220-8054-2025-16-5-640-649
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