Synthesis and thermal behavior of KCe2(PO4)3, a new full-member in the AIMIV2 (PO4)3 family
T. O. Kozlova,
D. N. Vasilyeva,
D. A. Kozlov,
M. A. Teplonogova,
A. E. Baranchikov,
N. P. Simonenko,
V. K. Ivanov https://doi.org/10.17586/2220-8054-2023-14-1-112-119
Abstract
Hydrothermal treatment of nanoscale amorphous ceric phosphate gel in KOH aqueous solutions was found to result in a new KCe2(PO4)3 phase. The refinement of the KCe2(PO4)3 structure showed that it was isostructural to recently reported (NH4)Ce2(PO4)3. For the KCe2(PO4)3 phase, the unit cell parameters (sp. gr. C2/c) were a = 17.3781(3) A,˚ b = 6.7287(1) A,˚ c = 7.9711(2) A,˚ β = 102.351(1) ◦, V = 910.53(4) A˚ 3, Z = 4. The thermal decomposition of KCe2(PO4)3 at 800 ◦C resulted in the mixture of crystalline CePO4 and KPO3.
Supporting agencies: This work was supported by Russian Science Foundation (Grant no. 21-73-00294, https://rscf.ru/en/project/21-73-00294/) using the equipment of the JRC PMR IGIC RAS. The authors thank Dr. A. V. Gavrikov for FT-IR spectroscopy studies.
About the Authors
T. O. Kozlova
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
Russian Federation
Russian Federation
Taisiya O. Kozlova,
Leninsky prospect, 31, Moscow, 119991.
D. N. Vasilyeva
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences; National Research University Higher School of Economics
Russian Federation
Russian Federation
Darya N. Vasilyeva,
Leninsky prospect, 31, Moscow, 119991;
Myasnitskaya str., 20, Moscow, 101000.
D. A. Kozlov
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences; Lomonosov Moscow State University
Russian Federation
Russian Federation
Daniil A. Kozlov,
Leninsky prospect, 31, Moscow, 119991;
Leninskie Gory 1, Moscow, 119991.
M. A. Teplonogova
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences; Lomonosov Moscow State University
Russian Federation
Russian Federation
Mariia A. Teplonogova,
Leninsky prospect, 31, Moscow, 119991;
Leninskie Gory 1, Moscow, 119991.
A. E. Baranchikov
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
Russian Federation
Russian Federation
Alexander E. Baranchikov,
Leninsky prospect, 31, Moscow, 119991.
N. P. Simonenko
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
Russian Federation
Russian Federation
Nikolay P. Simonenko,
Leninsky prospect, 31, Moscow, 119991.
V. K. Ivanov
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
Russian Federation
Russian Federation
Vladimir K. Ivanov,
Leninsky prospect, 31, Moscow, 119991.
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Review
For citations:
Kozlova T.O., Vasilyeva D.N., Kozlov D.A., Teplonogova M.A., Baranchikov A.E., Simonenko N.P., Ivanov V.K. Synthesis and thermal behavior of KCe2(PO4)3, a new full-member in the AIMIV2 (PO4)3 family. Nanosystems: Physics, Chemistry, Mathematics. 2023;14(1):112-119. https://doi.org/10.17586/2220-8054-2023-14-1-112-119
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