Синтез и термическое поведение KCe2(PO4)3 — нового соединения в семействе AIMIV2 (PO4)3
Т. О. Козлова,
Д. Н. Васильева,
Д. А. Козлов,
М. А. Теплоногова,
А. Е. Баранчиков,
Н. П. Симоненко,
В. К. Иванов https://doi.org/10.17586/2220-8054-2023-14-1-112-119
Аннотация
Гидротермальной обработкой наноразмерного аморфного церийфосфатного геля в водном растворе KOH была получена новая фаза KCe2(PO4)3. Уточнение структуры KCe2(PO4)3 показало, что она изоструктурна с ранее описанной фазой (NH4)Ce2(PO4)3. Параметры элементарной ячейки KCe2(PO4)3 (пр. гр. C2/c) составили a = 17.3781(3) Å, b = 6.7287(1) Å, c = 7.9711(2) Å, β = 102.351(1) °, V = 910.53(4) Å3, Z = 4. Термическое разложение KCe2(PO4)3 при 800°C привело к образованию смеси кристаллических CePO4 и KPO3.
Об авторах
Т. О. Козлова
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
Россия
Россия
Москва.
Д. Н. Васильева
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences; National Research University Higher School of Economics
Россия
Россия
Москва.
Д. А. Козлов
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences; Lomonosov Moscow State University
Россия
Россия
Москва.
М. А. Теплоногова
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences; Lomonosov Moscow State University
Россия
Россия
Москва.
А. Е. Баранчиков
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
Россия
Россия
Москва.
Н. П. Симоненко
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
Россия
Россия
Москва.
В. К. Иванов
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
Россия
Россия
Москва.
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Рецензия
Для цитирования:
Козлова Т.О., Васильева Д.Н., Козлов Д.А., Теплоногова М.А., Баранчиков А.Е., Симоненко Н.П., Иванов В.К. Синтез и термическое поведение KCe2(PO4)3 — нового соединения в семействе AIMIV2 (PO4)3. Наносистемы: физика, химия, математика. 2023;14(1):112-119. https://doi.org/10.17586/2220-8054-2023-14-1-112-119
For citation:
Kozlova T.O., Vasilyeva D.N., Kozlov D.A., Teplonogova M.A., Baranchikov A.E., Simonenko N.P., Ivanov V.K. Synthesis and thermal behavior of KCe2(PO4)3, a new full-member in the AIMIV2 (PO4)3 family. Nanosystems: Physics, Chemistry, Mathematics. 2023;14(1):112-119. https://doi.org/10.17586/2220-8054-2023-14-1-112-119
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