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Наносистемы: физика, химия, математика

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Синтез и термическое поведение KCe2(PO4)3 — нового соединения в семействе AIMIV2 (PO4)3

https://doi.org/10.17586/2220-8054-2023-14-1-112-119

Аннотация

Гидротермальной обработкой наноразмерного аморфного церийфосфатного геля в водном растворе KOH была получена новая фаза KCe2(PO4)3. Уточнение структуры KCe2(PO4)3 показало, что она изоструктурна с ранее описанной фазой (NH4)Ce2(PO4)3. Параметры элементарной ячейки KCe2(PO4)3 (пр. гр. C2/c) составили a = 17.3781(3) Å, b = 6.7287(1) Å, c = 7.9711(2) Å, β = 102.351(1) °, V = 910.53(4) Å3, Z = 4. Термическое разложение KCe2(PO4)3 при 800°C привело к образованию смеси кристаллических CePO4 и KPO3.

Об авторах

Т. О. Козлова
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
Россия

Москва.



Д. Н. Васильева
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences; National Research University Higher School of Economics
Россия

Москва.



Д. А. Козлов
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences; Lomonosov Moscow State University
Россия

Москва.



М. А. Теплоногова
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences; Lomonosov Moscow State University
Россия

Москва.



А. Е. Баранчиков
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
Россия

Москва.



Н. П. Симоненко
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
Россия

Москва.



В. К. Иванов
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
Россия

Москва.



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Рецензия

Для цитирования:


Козлова Т.О., Васильева Д.Н., Козлов Д.А., Теплоногова М.А., Баранчиков А.Е., Симоненко Н.П., Иванов В.К. Синтез и термическое поведение KCe2(PO4)3 — нового соединения в семействе AIMIV2 (PO4)3. Наносистемы: физика, химия, математика. 2023;14(1):112-119. https://doi.org/10.17586/2220-8054-2023-14-1-112-119

For citation:


Kozlova T.O., Vasilyeva D.N., Kozlov D.A., Teplonogova M.A., Baranchikov A.E., Simonenko N.P., Ivanov V.K. Synthesis and thermal behavior of KCe2(PO4)3, a new full-member in the AIMIV2 (PO4)3 family. Nanosystems: Physics, Chemistry, Mathematics. 2023;14(1):112-119. https://doi.org/10.17586/2220-8054-2023-14-1-112-119

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