Layer-by-layer synthesis of Zn-doped MnO2 nanocrystals as cathode materials for aqueous zinc-ion battery
https://doi.org/10.17586/2220-8054-2021-12-2-182-187
Abstract
This work first described the new oxidation-reduction route for the synthesis of Zn-doped MnO2 nanocrystals via layer-by-layer method as cathode material for an aqueous zinc-ion battery. The obtained nanolayers were characterized by SEM, XRD, XPS and FTIR spectroscopy. The results show the synthesized nanolayers were formed from two-dimensional nanocrystals Zn0.3MnO2 the thickness of about 3-8 nm and the morphology of “nanosheets” with the birnessite-like crystal structure. Benefiting from the aqueous 2M ZnSO4 electrolyte and Zn0.3MnO2 nanocrystals-based cathode, the zinc-ion battery delivers a high specific capacity (216 mAh/g at 1 A/g) and excellent cycling stability (95% capacity retention after 1000 charge-discharge cycles). The obtained results demonstrate the manganese oxide-based aqueous zinc-ion battery is a promising technology for powering next-generation electronics.
Supporting agencies: This research was financial supported by an RSF grant, project number 19-73-00304. The authors are grateful to the Centers for X-ray diffraction studies and Nanotechnology of Saint Petersburg State University
About the Authors
A. A. Lobinsky
Saint Petersburg State University
Russian Federation
Russian Federation
Peterhof, 198504 Saint Petersburg
M. V. Kaneva
Saint Petersburg State University
Russian Federation
Russian Federation
Peterhof, 198504 Saint Petersburg
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Review
For citations:
Lobinsky A.A., Kaneva M.V. Layer-by-layer synthesis of Zn-doped MnO2 nanocrystals as cathode materials for aqueous zinc-ion battery. Nanosystems: Physics, Chemistry, Mathematics. 2021;12(2):182-187. https://doi.org/10.17586/2220-8054-2021-12-2-182-187
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