The effect of co-precipitation temperature on the crystallite size and aggregation/agglomeration of GdFeO3 nanoparticles
https://doi.org/10.17586/2220-8054-2021-12-2-224-231
Abstract
In this work, a series of GdFeO3 nanopowders was successfully synthesized via a reverse co-precipitation technique at different solution temperatures (0, 25 and 50 ◦ C) followed by thermal treatment. Co-precipitated hydroxides and heat treatment products were analyzed using EDXS, DTA-TGA, PXRD, ASA and LD methods. It was shown that the formation temperature of GdFeO3 nanoparticles varies in the range of 737.5758.8 ◦C and total weight loss varies in the range of 23.6-26.4% depending on the temperature of initial solutions. The specific surface areas of nanopowders were found to be strongly dependent on the factor mentioned above and belong to 2.5-16.3 m[1]/g values interval. The hierarchical structure of the obtained nanopowders was established and the effect of co-precipitation temperature on the average crystallite (21.4-34.3 nm), aggregate (46.2-301.2 nm) and agglomerate (33.5-40.9 pm) sizes was discussed in detail.
Supporting agencies: The research was supported by the Russian Science Foundation (project No. 19-73-00286). The study was partially performed on equipment of the Engineering Center of Saint Petersburg State Institute of Technology. The authors acknowledge D.P. Danilovich (EDXS, DTA-TGA, LD) and M.I. Chebanenko (ASA) for their help with the physicochemical characterization of the samples.
About the Authors
V. I. Popkov
Ioffe Institute
Russian Federation
Russian Federation
Saint Petersburg, 194021
Y. Albadi
Saint Petersburg State Institute of Technology;
Al-Baath University
Russian Federation
Russian Federation
Saint Petersburg, 190013,
Homs, 77, Syrian Arab Republic
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Review
For citations:
Popkov V.I., Albadi Y. The effect of co-precipitation temperature on the crystallite size and aggregation/agglomeration of GdFeO3 nanoparticles. Nanosystems: Physics, Chemistry, Mathematics. 2021;12(2):224-231. https://doi.org/10.17586/2220-8054-2021-12-2-224-231
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