Synthesis Ni-doped CuO nanorods via Successive Ionic Layer Deposition method and their capacitive performance
https://doi.org/10.17586/2220-8054-2020-11-5-608-614
Abstract
In this work first described the new relatively simple approach to the synthesis of nanolayers of Ni-doped CuO via of Successive Ionic Layer
Deposition (SILD) method. The study of Ni-doped CuO nanolayers, synthesized of SILD, has been carried out by HRTEM, XRD, FTIR and XPS spectroscopy methods; it was demonstrated that they had been formed of nanorods with dimensions of about 10–15 nm and tenorite crystal structure CuO were formed. The research electrochemical properties of nanolayers were carried out in 1 KOH solution by using techniques of cyclic voltammetry and galvanostatic curves method. The electrochemical study of nickel foam electrodes modified by Ni-doped CuO nanolayer prepared by 30 SILD cycles demonstrates that specific capacitance is 154 mAh/g (1240 F/g) at current density 1 A/g. Repeated cycling after 1000 charge-discharge cycles demonstrates 8% capacitance fade from the initial value, so such electrodes may be used as effective electroactive materials for alkaline battery and pseudocapacitors.
Keywords
copper oxide,
nanocrystal,
nanorods,
successive ionic layer deposition,
electrode materials,
alkaline battery
Supporting agencies: This research was financial supported by the Grant of President of Russian Federation MK-2860.2019.3. The authors are grateful to the Centers for X-ray diffraction studies and Nanotechnology of Saint-Petersburg State University.
About the Authors
A. A. Lobinsky
Saint Petersburg State University
Russian Federation
Russian Federation
Peterhof, 198504 Saint Petersburg
M. V. Kaneva
Saint Petersburg State University
Russian Federation
Russian Federation
Peterhof, 198504 Saint Petersburg
References
1. Zhong C., Deng Y., Hu W., Qiao J., Zhang L., Zhang J. A review of electrolyte materials and compositions for electrochemical supercapacitors. Chem. Soc. Rev., 2015, 44, P. 7484–7539.
2. Wang F., Wu X., Yuan X. et al. Latest advances in supercapacitors: from new electrode materials to novel device designs. Chem. Soc. Rev., 2017, 46, P. 6816–6854.
3. Meher S.K., Rao G.R. Ultralayered Co3O4 for high-performance supercapacitor applications. J. Phyl. Chem. C, 2011, 115, P. 15646–15654.
4. Zhiyi Zhang, Qiuyue Gao, Haibo Gao, Zhenyu Shi, Junwei Wu, Mingjia Zhi, Zhanglian Hong. Nickel oxide aerogel for high-performance supercapacitor electrode. RSC Adv., 2016, 6, P. 112620–112624.
5. Zhu G., He Z., Chen J. et al. Highly conductive threedimensional MnO2-carbon nanotube-graphene-Ni hybrid foam as a binder-free supercapacitor electrode. Nanoscale, 2014, 6, P. 1079–1085.
6. Yang P., Ding Y., Lin Z. et al. Low-cost high-performance solid-state asymmetric supercapacitors based on MnO2 nanowires and Fe2O3 nanotubes. Nano Lett., 2014, 14, P. 731–736.
7. Choi C, Ashby D.S., Butts D.M. et al. Achieving high energy density and high power density with pseudocapacitive materials. Nat. Rev. Mater., 2020, 5, P. 5–19.
8. Liu Y., Cao X., Jiang D., Jia D., Liu J. Hierarchical CuO nanorod arrays in situ generated on three-dimensional copper foam via cyclic voltammetry oxidation for high-performance supercapacitors. J. Mater. Chem. A, 2018, 6, P. 10474–10483.
9. Deepak P. Dubal, Girish S. Gund, Chandrakant D. Lokhande, Rudolf Holze. CuO cauliflowers for supercapacitor application: Novel potentiodynamic deposition. Materials Research Bulletin, 2013, 48, P. 923–928.
10. Mohammad Bagher Gholivand, HamidHeydari, Abbas Abdolmaleki, Hamid Hosseini. Nanostructured CuO/PANI composite as supercapacitor electrode material. Materials Science in Semiconductor Processing, 2015, 30, P. 157–161.
11. Seyyed E Moosavifard, Maher F El-Kady, Mohammad S Rahmanifar, Richard B Kaner, Mir F Mousavi. Designing 3D highly ordered nanoporous CuO electrodes for high-performance asymmetric supercapacitors. ACS Appl. Mater. Interfaces, 2015, 7(8), P. 4851–60.
12. Tolstoy V.P., Kodintsev I.A., Reshanova K.S., Lobinsky A.A. A brief review of metal oxide (hydroxide)-graphene nanocomposites synthesis by layer-by-layer deposition from solutions and synthesis. Reviews on advanced materials science, 2017, 49(1), P. 28–37.
13. Lobinsky A.A., Tolstoy V.P., Gulina L.B. A novel oxidation-reduction route for successive ionic layer deposition of NiO1+x·nH2O nanolayers and their capacitive performance. Materials Research Bulletin, 2016, 76, P. 229–234.
14. Lobinsky A.A., Tolstoy V.P. Synthesis of γ-MnOOH nanorods by successive ionic layer deposition method and their capacitive performance. Journal of Energy Chemistry, 2017, 26, P. 336–339.
15. Lobinsky A.A., Tolstoy V.P. Red-ox reactions in aqueous solutions of Co(OAc)2 and K2S2O8 and synthesis of CoOOH nanolayers by the SILD method. Nanosystems: Physics, Chemistry, Mathematics, 2015, 6(6), P. 843–849.
16. Kodintsev I.A., Tolstoy V.P. Lobinsky A.A. Room temperature synthesis of composite nanolayer consisting of AgMnO2 delafossite nanosheets and Ag nanoparticles by successive ionic layer deposition and their electrochemical properties. Materials Letters, 2017, 196, P. 54–56.
17. Kodintsev I.A., Martinson K.D., Lobinsky A.A., Popkov V.I. Successive ionic layer deposition of Co-doped Cu(OH)2 nanorods as electrode material for electrocatalytic reforming of ethanol. Nanosystems: Physics, Chemistry, Mathematics, 2019, 10(5), P. 573–578.
18. Kodintsev I.A., Martinson K.D., Lobinsky A.A., Popkov V.I. SILD synthesis of the efficient and stable electrocatalyst based on CoO-NiO solid solution toward hydrogen production. Nanosystems: Physics, Chemistry, Mathematics, 2019, 10(6), P. 681–685.
19. Dmitriev D.S., Popkov V.I., Layer by layer synthesis of zinc-iron layered hydroxy sulfate for electrocatalytic hydrogen evolution from ethanol in alkali media. Nanosystems: Physics, Chemistry, Mathematics, 2019, 10(4), P. 480–487.
20. Popkov V.I., Tolstoy V.P., Semenov V.G., Synthesis of phase-pure superparamagnetic nanoparticles of ZnFe2O4 via thermal decomposition of zinc-iron layered double hydroxysulphate. Journal of Alloys and Compounds, 2020, 813, P. 152179.
21. Tolstoy V.P., Lobinsky A.A., Levin O.V., Kuklo L.I. Direct synthesis of Ni2Al(OH)7−x(NO3)x·nH2O layered double hydroxide nanolayers by SILD and their capacitive performance. Materials Letters, 2015, 139, P. 4–6.
22. Tolstoy V.P., Lobinsky A.A. Synthesis of 2D Zn-Co LDH nanosheets by a successive ionic layer deposition method as a material for electrodes of high-performance alkaline battery-supercapacitor hybrid devices. RSC Advances, 2018, 8, P. 29607–29612.
23. Liu Y., Cao X., Jiang D., Jia D., Liu J. Hierarchical CuO nanorod arrays in situ generated on three-dimensional copper foam via cyclic voltammetry oxidation for high-performance supercapacitors. J. Mater. Chem. A, 2018, 6, P. 10474–10483.
24. Zhao H., Zhou X.X., Pan L.Y., Wang M., Chen H.R., Shi J.L. Facile synthesis of spinel Cu1.5Mn1.5O4 microspheres with high activity for the catalytic combustion of diesel soot. RSC Adv., 2017, 7, P. 20451–20459.
25. Xie J., Cao H., Jiang H., Chen Y., Shi W., Zheng H., Huang Y. Co3O4-reduced graphene oxide nanocomposite as an effective peroxidase mimetic and its application in visual biosensing of glucose. Anal. Chim. Acta, 2013, 796, P. 92.
26. Zhangpeng Li, Jinqing Wang, Lengyuan Niu, Jinfeng Sun, Peiwei Gong, Wei Hong, Limin Ma, Shen-grong Yang Rapid. Synthesis of graphene/cobalt hydroxide composite with enhanced electrochemical performance for supercapacitors. Journal of Power Sources, 2014, 245, P. 224–231.
27. Ethiraj A.S., Kang D.J., Synthesis and characterization of CuO nanowires by a simple wet chemical method. Nanoscale Research Letters, 2012, 7(1), P. 70.
28. Xu L., Zhang H., Li J. at all. Designing core-shell Ni(OH)2@CuO nanowire arrays on 3D copper foams for high-performance asymmetric supercapacitors. Chem. Electro Chem., 2019, 6, P. 5462–5468.
29. Gui Chen, Lingjing Chen, Siu-Mui Ng, Tai-Chu Lau. Efficient chemical and visible-light-driven water oxidation using nickel complexes and salts as precatalysts. Chem. Sus. Chem., 2014, 7, P. 127–134.
Review
For citations:
Lobinsky A.A., Kaneva M.V. Synthesis Ni-doped CuO nanorods via Successive Ionic Layer Deposition method and their capacitive performance. Nanosystems: Physics, Chemistry, Mathematics. 2020;11(5):608–614. https://doi.org/10.17586/2220-8054-2020-11-5-608-614
Views:
1
Email this article 