Cryometry and excess thermodynamic functions in water soluble of the fullerenol C60(OH)24
https://doi.org/10.17586/2220-8054-2020-11-2-205-213
Abstract
The temperature of water-ice crystallization initiation decreases (∆T) were determined in the binary water solutions of water soluble fullerenol:
C60(OH)24 − H2O at 272.85–273.15 K. Solution concentrations (in molar fractions) vary over a wide range xnano−cluster = 5.0 · 10−6 ÷
1.6 · 10−4 a.un. Liquidus temperatures were determined with the help of Beckman thermometer with a linear resolution of the device scale ∆T ≈ 0.01 K/mm (h – height of Hg capillary raising). For the thermodynamic description of the discussed systems, we have elaborated an ∆h original semi-empirical model, the virial decomposition asymmetric model (VD-AS), with assistance from partial molar functions of nano-clusters (activities and activity coefficients) were calculated. The Gibbs energies for the solutions and miscibility gap concentration regions were calculated. VD-AS model excellently describes pre-delamination or micro-heterogeneous-structure formation in the considered solutions. These calculations are confirmed by the dynamic light scattering data.
Supporting agencies: This work was supported by Russian Foundation for Basic Research (RFBR) (Projects Nos. 18-08-00143 A, 19-015-00469 A, and 19-016-00003 A).
About the Authors
N. A. Charykov
St. Petersburg State Technological Institute (Technical University); St. Petersburg Electrotechnical University “LETI”
Russian Federation
Russian Federation
Moskovsky prospect, 26 Saint-Petersburg, 190013
ul. Professora Popova 5, 197376 St. Petersburg
K. N. Semenov
St. Petersburg State Technological Institute (Technical University); St. Petersburg State University; Pavlov First Saint Petersburg State Medical University
Russian Federation
Russian Federation
Moskovsky prospect, 26 Saint-Petersburg, 190013
7/9 Universitetskaya emb., Saint-Petersburg, 199034
L’va Tolstogo str. 6-8 Saint Petersburg, 197022
V. A. Keskinov
St. Petersburg State Technological Institute (Technical University)
Russian Federation
Russian Federation
Moskovsky prospect, 26 Saint-Petersburg, 190013
V. A. Kulenova
D. Serikbayev East Kazakhstan state technical university
Kazakhstan
Kazakhstan
A.K. Protozanov Street, 69, Ust-Kamenogorsk city, 070004
Z. K. Shaimardanov
D. Serikbayev East Kazakhstan state technical university
Kazakhstan
Kazakhstan
A.K. Protozanov Street, 69, Ust-Kamenogorsk city, 070004
B. K. Shaimardanova
D. Serikbayev East Kazakhstan state technical university
Kazakhstan
Kazakhstan
A.K. Protozanov Street, 69, Ust-Kamenogorsk city, 070004
L. V. Gerasimova
St. Petersburg State Technological Institute (Technical University)
Russian Federation
Russian Federation
Moskovsky prospect, 26 Saint-Petersburg, 190013
Ayat Kanbar
St. Petersburg State Technological Institute (Technical University)
Russian Federation
Russian Federation
Moskovsky prospect, 26 Saint-Petersburg, 190013
D. G. Letenko
St. Petersburg State University of Architecture and Civil Engineering (SPSUACE)
Russian Federation
Russian Federation
2-nd Krasnoarmeiskaya St. 4, 190005 St. Petersburg
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Review
For citations:
Charykov N.A., Semenov K.N., Keskinov V.A., Kulenova V.A., Shaimardanov Z.K., Shaimardanova B.K., Gerasimova L.V., Kanbar A., Letenko D.G. Cryometry and excess thermodynamic functions in water soluble of the fullerenol C60(OH)24. Nanosystems: Physics, Chemistry, Mathematics. 2020;11(2):205–213. https://doi.org/10.17586/2220-8054-2020-11-2-205-213
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