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Synthesis of porous graphene nanocomposite and its excellent adsorption behavior for Erythromycin antibiotic

https://doi.org/10.17586/2220-8054-2020-11-2-214-222

Abstract

The purpose of this study was to evaluate the efficiency of porous magnetic graphene (PMG) for removal of Erythromycin (ER) from aqueous solutions. PMG was prepared from banana peel residue, which was considered as a discarded material. As-synthesized nanocomposite was characterized by SEM, AFM, FTIR, RAMAN and BET analysis. The optimum conditions were obtained at pH of 3, contact time of 30 min, initial antibiotic concentration of 200 mg/L, and adsorbent dose of 0.35 g/L. In equilibrium, the Langmuir isotherm model was the best fit to the experimental data for the kinetics study, the adsorption process developed the pseudo-second-order model. According to the results, nanosheet had high adsorption capacity (286 mg/g) and can be considered as an acceptable adsorbent for the removal of ER from aqueous solutions.

About the Authors

Fateme Bahmei
Department of Environmental Science, Faculty of Natural Resources, Tarbiat Modares University
Islamic Republic of Iran

Tehran



Nader Bahramifar
Department of Environmental Science, Faculty of Natural Resources, Tarbiat Modares University
Islamic Republic of Iran

Tehran



Habibollah Younesi
Department of Environmental Science, Faculty of Natural Resources, Tarbiat Modares University
Islamic Republic of Iran

Tehran



Valeri Tolstoy
Department of Chemistry, Saint Petersburg State University
Russian Federation

Peterhof, 198504, Saint Petersburg



References

1. Li MF, Liu YG, Zeng GM, Liu N, Liu SB. Graphene and graphene-based nanocomposites used for antibiotics removal in water treatment: a review. Chemosphere, 2019.

2. Koyuncu I., Arikan O.A., Wiesner M.R., Rice C. Removal of hormones and antibiotics by nanofiltration membranes. Journal of membrane science, 2008, 309(1-2), P. 94–101.

3. Moussavi G., Allahabad A., Yaghmaeian K., Eskandari M. Preparation, characterization and adsorption potential of the NH4Cl-induced activated carbon for the removal of amoxicillin antibiotic from water. Chemical engineering journal, 2013, 217, P. 119–128.

4. Yi J.W., Park J., Kim K.S., Kim B.H. pH-Responsive self-duplex of Py A-substituted oligodeoxyadenylate in graphene oxide solution as a molecular switch. Organic and biomolecular chemistry, 2011, 9(21), P. 7434–7438.

5. Dhinakaran V., Lavanya M., Vigneswari K., Ravichandran M., Vijayakumar M.D. Review on exploration of graphene in diverse applications and its future horizon. Materials Today: Proceedings, 2020.

6. Yousefi N., Lu X., Elimelech M., Tufenkji N. Environmental performance of graphene-based 3D macrostructures. Nature nanotechnology, 2019, 14(2), P. 107–119.

7. Zhu J., Wei S., Gu H., Rapole S.B., Wang Q., Luo Z., Haldolaarachchige N., Young D.P., Guo Z. One-pot synthesis of magnetic graphene nanocomposites decorated with core@ double-shell nanoparticles for fast chromium removal. Environmental science and technology, 2012, 46(2), P. 977–985.

8. Dideikin A.T., Vul A.Y. Graphene oxide and derivatives: the place in graphene family. Frontiers in Physics, 2019, 6, P. 149.

9. Shanmugam S., Nanjan S. In-situ conversion of rgo from graphene oxide based on solar mediated enhanced characterization properties. Nanosystems: Physics, Chemistry, Mathematics, 2019, 10(5), P. 579–584.

10. Lebedev S.P., Davydov V.Y., Usachov D.Y., Smirnov A.N., Levitskii V.S., Eliseyev I.A., Guschina E.V., Dunaevsckiy M.S., Vilkov O.Y., Rybkin A.G., Lebedev A.A. Graphene on silicon carbide as a basis for gasand biosensor applications. Nanosystems: Physics, Chemistry, Mathematics, 2018, 9(1), P. 95–97.

11. Ekhlasi L., Younesi H., Rashidi A., Bahramifar N. Populus wood biomass-derived graphene for high CO2 capture at atmospheric pressure and estimated cost of production. Process Safety and Environmental Protection, 2018, 113, P. 97–108.

12. Ai L., Zhang C., Chen Z. Removal of methylene blue from aqueous solution by a solvothermal-synthesized graphene/magnetite composite. Journal of hazardous materials, 2011, 15, 192(3), P. 1515–1524.

13. Lin L.Y., Kim D.E., Kim W.K., Jun S.C. Friction and wear characteristics of multi-layer graphene films investigated by atomic force microscopy. Surface and Coatings Technology, 2011, 205(20), P. 4864–4869.

14. Villar-Rodil S., Paredes J.I., Mart´ınez-Alonso A., Tascon J.M. Preparation of graphene dispersions and graphene-polymer composites in´ organic media. Journal of Materials Chemistry, 2009, 19(22), P. 3591–3593.

15. Calizo I., Balandin A.A., Bao W., Miao F., Lau C.N. Temperature dependence of the Raman spectra of graphene and graphene multilayers. Nano letters, 2007, 7(9), P. 2645–2649.

16. Ferrari A.C. Raman spectroscopy of graphene and graphite: disorder, electron–phonon coupling, doping and nonadiabatic effects. Solid state communications, 2007, 143(1-2), P. 47–57.

17. Xue B., Zhu J., Liu N., Li Y. Facile functionalization of graphene oxide with ethylenediamine as a solid base catalyst for Knoevenagel condensation reaction. Catalysis Communications, 2015, 64, P. 105–109.

18. Lu M., Li J., Yang X., Zhang C., Yang J., Hu H., Wang X. Applications of graphene-based materials in environmental protection and detection.¨ Chinese Science Bulletin, 2013, 58(22), P. 2698-710.

19. Guo X., Du B., Wei Q., Yang J., Hu L., Yan L., Xu W. Synthesis of amino functionalized magnetic graphenes composite material and its application to remove Cr (VI), Pb (II), Hg (II), Cd (II) and Ni (II) from contaminated water. Journal of hazardous materials, 2014, 278, P. 211-20.

20. Ou H., Chen Q., Pan J., Zhang Y., Huang Y., Qi X. Selective removal of erythromycin by magnetic imprinted polymers synthesized from chitosan-stabilized Pickering emulsion. Journal of hazardous materials, 2015, 289, P. 28–37.

21. Moussavi G., Alahabadi A., Yaghmaeian K., Eskandari M. Preparation, characterization and adsorption potential of the NH4Cl-induced activated carbon for the removal of amoxicillin antibiotic from water. Chemical engineering journal, 2013, 217, P. 119-28.

22. Budyanto S., Soedjono S., Irawaty W., Indraswati N. Studies of Adsorption Equilibria and Kinetics of amoxicillin from simulated wastewater using activated carbon and natural bentonite. Journal of environmental protection science, 2008, 2, P. 72–80.

23. Shafiee M., Akbari A., Ghiassimehr B. Removal of Pb (II) From Wastewater Using Henna; Optimization of Operational Conditions. Iranian Journal of Chemical Engineering, 2018, 15(4), P. 17–26.

24. Peer F.E., Bahramifar N., Younesi H. Removal of Cd (II), Pb (II) and Cu (II) ions from aqueous solution by polyamidoamine dendrimer grafted magnetic graphene oxide nanosheets. Journal of the Taiwan Institute of Chemical Engineers, 2018, 87, P. 225-40.

25. Beltrame K.K., Cazetta A.L., de Souza P.S., Spessato L., Silva T.L., Almeida V.C. Adsorption of caffeine on mesoporous activated carbon fibers prepared from pineapple plant leaves. Ecotoxicology and environmental safety. 2018. 147, P. 64–71.

26. Rostamian R., Behnejad H. A comparative adsorption study of sulfamethoxazole onto graphene and graphene oxide nanosheets through equilibrium, kinetic and thermodynamic modeling. Process Safety and Environmental Protection, 2016, 102, P. 20-9.

27. Budyanto S., Soedjono S., Irawaty W., Indraswati N. Studies of Adsorption Equilibria and Kinetics of amoxicillin from simulated wastewater using activated carbon and natural bentonite. Journal of environmental protection science, 2008, 2, P. 72–80.


Review

For citations:


Bahmei F., Bahramifar N., Younesi H., Tolstoy V. Synthesis of porous graphene nanocomposite and its excellent adsorption behavior for Erythromycin antibiotic. Nanosystems: Physics, Chemistry, Mathematics. 2020;11(2):214–222. https://doi.org/10.17586/2220-8054-2020-11-2-214-222

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ISSN 2220-8054 (Print)
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