Photoelectrochemical cell performance Cu doped ZnO photoanode sensitized by xanthene dyes
https://doi.org/10.17586/2220-8054-2019-10-4-466-474
Abstract
In this study transition metal Cu is doped into ZnO framework at 1, 3 and 5 mol% concentrations by sol-gel method and Photoelectrochemical performance under sensitization is recorded. Structural analysis XRD and Raman gives information of wurtzite structure formation without any mislaid peaks. It also informs decrement in crystalline size and lattice parameters as doping level increases. SEM and EDAX provide nono structure formation with appropriate compositions. Optical analysis by FTIR and PL gives peaks at expected positions while DRS UV-visible peaks show humps with red shift due to effect of Cu doping. After structural and morphological study NPs are deposited on conducting glass surface of FTO substrate by doctor blade method and sensitized with mixed xanthene dyes (Eosine Y., Rhodamine B., and Rose Bengal) for 12 h and photoelectrochemical cell performance are recorded under solar simulator under standard AM 1.5 one sun illumination in that 1 % Cu/ZnO photoanode shows good performance as compared to other.
Supporting agencies: This research was made possible by support given by DST-FIST Analytical Instrumentation Laboratory of Lal Bahadur Shastri College, Satara and Jaysingpur College, Jaysingpur, Maharashtra, India.
About the Authors
Deepak Kumbhar
Department of Chemistry, Raje Ramrao Mahavidyalaya; Department of Chemistry, Lal Bahadur Shastri College
India
India
Jath, 416 404, affiliated to Shivaji University Kolhapur 416004, MS
Satara, 415 002, affiliated to Shivaji University Kolhapur 416004, MS
Sarita Kumbhar
Department of Physics, Rajashri Chhatrapati Shahu College
India
India
Kolhapur, 416 005, affiliated to Shivaji University Kolhapur 416004
Sagar Delekar
Department of Chemistry, Shivaji University
India
India
Kolhapur, 416 004, MS
Rekha Nalawade
Department of Chemistry, Shivaji University
India
India
Kolhapur, 416 004, MS
Avinash Nalawade
Department of Chemistry, Lal Bahadur Shastri College
India
India
Satara, 415 002, affiliated to Shivaji University Kolhapur 416004, MS
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Review
For citations:
Kumbhar D., Kumbhar S., Delekar S., Nalawade R., Nalawade A. Photoelectrochemical cell performance Cu doped ZnO photoanode sensitized by xanthene dyes. Nanosystems: Physics, Chemistry, Mathematics. 2019;10(4):466–474. https://doi.org/10.17586/2220-8054-2019-10-4-466-474
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