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Layer by layer synthesis of zinc-iron layered hydroxy sulfate for electrocatalytic hydrogen evolution from ethanol in alkali media

https://doi.org/10.17586/2220-8054-2019-10-4-480-487

Abstract

This paper proposes a method for producing nanocomposite electrocatalytic coatings based on zinc-iron layered hydroxy sulfate Zn2Fe4(OH)12SO4· 8H2O and iron(III) hydroxide Fe(OH)3 using the successive ionic layer deposition (SILD) method. The obtained materials were investigated with the methods of SEM and EDX, XRD, FTIR spectroscopy, and also were analyzed their electrocatalytic performance. These compounds are formed on the surface of the substrate in nanosheets shape with an average size of 6–17 nm, which self-organized into coral-like agglomerates. It was shown that by varying the anionic component of the reaction solution – NO or Cl, effective control of the 2D nanocrystals phase composition is possible. It has been determined that electrocatalytic materials based on Zn2Fe4(OH)12SO4·8H2O and Fe(OH)3 are active in the process of hydrogen evolution from alkaline water-alcohol solutions. In result overpotential value of hydrogen evolution reaction at 10 mA cm−2 decreases about ∼ 10%, as well as energy consumption to carry out this process reduces about 8–12%. as shown from the decline of the Tafel slope. The developed materials have high cyclic stability and short non-stationary mode, which allows them to be considered as the base of electrocatalysts for the processes of hydrogen evolution from ethanol in an alkaline medium.

About the Authors

D. S. Dmitriev
Ioffe Institute
Russian Federation

194021 Saint Petersburg, 26 Polytechnicheskaya street



V. I. Popkov
Ioffe Institute
Russian Federation

194021 Saint Petersburg, 26 Polytechnicheskaya street



References

1. Glebova N.V., Nechitailov A.A., Krasnova A.O., et al. Cathode of hydrogen fuel cell, with modified structure and hydrophobicity. Russ. J. Appl. Chem., 2015, 88, P. 769–774.

2. Krasnova A.O., Agafonov D.V., Glebova N.V., et al. Technological Aspects of Hydrogen Fuel Cell Electrodes with Controlled Porosity and Transport Properties. Altern. Energy. Ecol., 2019, 4-6, P. 51–64.

3. Mitra M.A. Study on Advances in Hydrogen Fuel Cells. Electrical Engineering Open Access Open Journal, 2019, 1, P. 1–4.

4. Sharaf O.Z., Orhan M.F. An overview of fuel cell technology: Fundamentals and applications. Renew. Sustain. Energy. Rev., 2014, 32, P. 810–853.

5. Akhairi M.A.F., Kamarudin S.K. Catalysts in direct ethanol fuel cell (DEFC): An overview. Int. J. Hydrogen Energy, 2016, 41, P. 4214–4228.

6. Brandon N.P., Parkes M.A. Fuel Cells: Materials. Ref. Modul. Mater. Sci. Mater., 2016, P. 1–6.

7. Tuomi S., Santasalo-Aarnio A., Kanninen P., Kallio T. Hydrogen production by methanol-water solution electrolysis with an alkaline membrane cell. J Power Sources, 2013, 229, P. 32–35.

8. Gutierrez-Guerra N., Jim´ enez-V´ azquez M., Serrano-Ruiz J.C., et al. Electrochemical reforming vs. catalytic reforming of ethanol: A process´ energy analysis for hydrogen production. Chem Eng Process: Process Intensif, 2015, 95, P. 9–16.

9. Hasa B., Vakros J., Katsaounis A.D. Study of low temperature alcohol electro-reforming. Mater Today Proc, 2018, 5, P. 27337–27344.

10. Hasa B., Vakros J., Katsaounis A.D. Effect of TiO2 on Pt-Ru-based anodes for methanol electroreforming. Appl Catal. B Environ, 2018, 237, P. 811–816.

11. Bambagioni V., Bevilacqua M., Bianchini C., et al. Self-sustainable production of hydrogen, chemicals, and energy from renewable alcohols by electrocatalysis. Chem. Sus. Chem., 2010, 3, P. 851–855.

12. De Lucas-Consuegra A., Calcerrada A.B., De La Osa A.R., Valverde J.L. Electrochemical reforming of ethylene glycol. Influence of the operation parameters, simulation and its optimization. Fuel Process Technol, 2014, 127, P. 13–19.

13. Caravaca A., Sapountzi F.M., De Lucas-Consuegra A., et al. Electrochemical reforming of ethanol-water solutions for pure H2 production in a PEM electrolysis cell. Int J Hydrogen Energy, 2012, 37, P. 9504–9513.

14. Safizadeh F., Ghali E., Houlachi G. Electrocatalysis developments for hydrogen evolution reaction in alkaline solutions - A Review. Int. J. Hydrogen Energy, 2015, 40, P. 256–274.

15. Nikolic V.M., Maslovara S.L., Tasic G.S., et al. Kinetics of hydrogen evolution reaction in alkaline electrolysis on a Ni cathode in the presence of Ni-Co-Mo based ionic activators. Appl Catal B Environ, 2015, 179, P. 88–94.

16. Ruetschi P., Delahay P. Hydrogen overvoltage and electrode material. A theoretical analysis.¨ J. Chem. Phys., 1955, 23, P. 195–199.

17. Kubisztal J., Budniok A., Lasia A. Study of the hydrogen evolution reaction on nickel-based composite coatings containing molybdenum powder. Int. J. Hydrogen Energy, 2007, 32, P. 1211–1218.

18. Perez-Alonso F.J., Adˆ an C., Rojas S., et al. Ni-Co electrodes prepared by electroless-plating deposition. A study of their electrocatalytic´ activity for the hydrogen and oxygen evolution reactions. Int. J. Hydrogen Energy, 2015, 40, P. 51–61.

19. Siddeswara D.M.K., Mahesh K.R.V., Sharma S.C., et al. ZnO decorated graphene nanosheets: an advanced material for the electrochemical performance and photocatalytic degradation of organic dyes. Nanosyst.: Physics, Chem., Math., 2016, 7, P. 678–682.

20. Alekseeva O.A., Naberezhnov A.A., Stukova E.V., Popkov V.I. The effect of barium titanate admixture on the stability of potassium nitrate ferroelectric phase in (1−x)KNO3+(x)BaTiO3 composites. St. Petersbg. Polytech. Univ. J. Phys. Math., 2015, 1, P. 229–234.

21. Mylarappa M., Lakshmi V.V., Mahesh K.R.V., et al. Electro chemical and photo catalytic studies of MnO2 nanoparticle from waste dry cell batteries. Nanosyst.: Physics, Chem., Math., 2016, 7, P. 657–661.

22. Gimaztdinova M.M., Tugova E.A., Tomkovich M.V. Synthesis of GdFeO3 nanocrystals via glycine-nitrate combustion. Condens Phases Interfaces, 2016, 18, P. 422–431.

23. Kodintsev I., Tolstoy V., Lobinsky A. Room temperature synthesis of composite nanolayer consisting of AgMnO2 delafossite nanosheets and Ag nanoparticles by successive ionic layer deposition and their electrochemical properties. Mater. Lett., 2017, 196, P. 54–56.

24. Eftekhari A. Electrocatalysts for hydrogen evolution reaction. Int. J. Hydrogen Energy, 2017, 42, P. 11053–11077.

25. Wang H., Gao L. Recent developments in electrochemical hydrogen evolution reaction. Curr. Opin Electrochem, 2018, 7, P. 7–14.

26. Zou X., Zhang Y. Noble metal-free hydrogen evolution catalysts for water splitting. Chem. Soc. Rev., 2015, 44, P. 5148–80.

27. Mahmood N., Yao Y., Zhang J.W., et al. Electrocatalysts for Hydrogen Evolution in Alkaline Electrolytes: Mechanisms, Challenges, and Prospective Solutions. Adv. Sci., 2018, 5, P. 1700464.

28. Voiry D., Yang J., Chhowalla M. Recent Strategies for Improving the Catalytic Activity of 2D TMD Nanosheets Toward the Hydrogen Evolution Reaction. Adv. Mater., 2016, 28, P. 6197–6206.

29. Shi Y., Zhang B. Recent advances in transition metal phosphide nanomaterials: Synthesis and applications in hydrogen evolution reaction. Chem. Soc. Rev., 2016, 45, P. 1529–1541.

30. Ojha K., Saha S., Dagar P., Ganguli A.K. Nanocatalysts for hydrogen evolution reactions. Phys. Chem. Chem. Phys., 2018, 20, P. 6777–6799.

31. Tolstoy V.P. Successive ionic layer deposition. The use in nanotechnology. Russ. Chem. Rev., 2006, 75, P. 161–175.

32. Lobinsky A.A., Tolstoy V.P., Kodinzev I.A. Electrocatalytic properties of γ-NiOOH nanolayers, synthesized by successive ionic layer deposition, during the oxygen evolution reaction upon water splitting in the alkaline medium. Nanosyst.: Physics., Chem., Math., 2018, 9, P. 669–675.

33. Lobinsky A.A., Tolstoy V.P. Synthesis of 2D Zn-Co LDH nanosheets by a successive ionic layer deposition method as a material for electrodes of high-performance alkaline battery-supercapacitor hybrid devices. RSC Adv, 2018, 8, P. 29607–29612.

34. Tolstoy V.P., Kuklo L.I., Gulina L.B. Ni(II) doped FeOOH 2D nanocrystals, synthesized by Successive Ionic Layer Deposition, and their electrocatalytic properties during oxygen evolution reaction upon water splitting in the alkaline medium. J. Alloys. Compd., 2019, 786,P. 198– 204.

35. Pathan H.M., Lokhande C.D. Deposition of metal chalcogenide thin films by successive ionic layer adsorption and reaction (SILAR) method. Bull. Mater. Sci., 2004, 27, P. 85–111.

36. Ho S.M. Chemical Science Review and Letters Synthesis of binary metal chalcogenides using SILAR method: Review. Chem. Sci. Rev. Lett., 2015, 4, P. 1305–1310.

37. Popkov V.I., Tolstoy V.P., Omarov S.O., Nevedomskiy V.N. Enhancement of acidic-basic properties of silica by modification with CeO2Fe2O3 nanoparticles via successive ionic layer deposition. Appl. Surf. Sci., 2019, 473, P. 313–317.

38. Popkov V.I., Tolstoy V.P., Nevedomskiy V.N. Peroxide route to the synthesis of ultrafine CeO2-Fe2O3 nanocomposite via successive ionic layer deposition. Heliyon, 2019, 5, P. e01443.

39. Kuklo L.I., Tolstoy V.P. Successive ionic layer deposition of Fe3O4@HxMoO4·nH2O composite nanolayers and their superparamagnetic properties. Nanosyst.: Physics., Chem., Math., 2017, 7, P. 1050–1054.

40. Nakamoto K. Infrared and Raman Spectra of Inorganic and Coordination Compounds. In: Griffiths PR (ed) Handbook of Vibrational Spectroscopy. John Wiley & Sons, Ltd, Chichester, UK, 2006.


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For citations:


Dmitriev D.S., Popkov V.I. Layer by layer synthesis of zinc-iron layered hydroxy sulfate for electrocatalytic hydrogen evolution from ethanol in alkali media. Nanosystems: Physics, Chemistry, Mathematics. 2019;10(4):480–487. https://doi.org/10.17586/2220-8054-2019-10-4-480-487

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ISSN 2220-8054 (Print)
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