Synthesis and down-conversion luminescence of Ba4Y3F17:Yb:Pr solid solutions for photonics
https://doi.org/10.17586/2220-8054-2019-10-2-190-198
Abstract
Single-phase powders of Ba4Y3F17:Yb:Pr solid solutions with an average agglomerate size of 400 nm were synthesized by co-precipitation from aqueous solutions. It was shown that the down-conversion mechanism in the investigated samples was quantum cutting, with one photon absorbed by Pr3+ ions resulting in two photons emitted by Yb3+ ions. At first, overall the external quantum yield of down-conversion luminescence measured appeared to be relatively high, with a maximum value of 2.9 % for the Ba4Y3F17:Pr(0.1 %):Yb(10 %) sample. It makes this compound promising for Si-based solar cells efficiency enhancement.
Supporting agencies: The study was funded by the Russian Science Foundation (project # 17-73-20352). Authors thank E. V. Chernova for her assistance with the preparation of this manuscript.
About the Authors
S. V. Kuznetsov
Prokhorov General Physics Institute of the Russian Academy of Sciences
Russian Federation
Russian Federation
38 Vavilov str., Moscow, 119991
A. S. Nizamutdinov
Kazan Federal University
Russian Federation
Russian Federation
18 Kremljovskaya, Kazan, 420008
M. N. Mayakova
Prokhorov General Physics Institute of the Russian Academy of Sciences
Russian Federation
Russian Federation
38 Vavilov str., Moscow, 119991
V. V. Voronov
Prokhorov General Physics Institute of the Russian Academy of Sciences
Russian Federation
Russian Federation
38 Vavilov str., Moscow, 119991
E. I. Madirov
Kazan Federal University
Russian Federation
Russian Federation
18 Kremljovskaya, Kazan, 420008
A. R. Khadiev
Kazan Federal University
Russian Federation
Russian Federation
18 Kremljovskaya, Kazan, 420008
D. A. Spassky
Skobeltsyn Institute of Nuclear Physics, Lomonosov Moscow State University
Russian Federation
Russian Federation
Leninskie Gory, Moscow 119991
I. A. Kamenskikh
Physics Faculty of Lomonosov Moscow State University
Russian Federation
Russian Federation
Leninskie Gory, Moscow 119991
A. D. Yapryntsev
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
Russian Federation
Russian Federation
31 Leninsky pr., Moscow,119991
V. K. Ivanov
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
Russian Federation
Russian Federation
31 Leninsky pr., Moscow,119991
M. A. Marisov
Kazan Federal University
Russian Federation
Russian Federation
18 Kremljovskaya, Kazan, 420008
V. V. Semashko
Kazan Federal University
Russian Federation
Russian Federation
18 Kremljovskaya, Kazan, 420008
P. P. Fedorov
Prokhorov General Physics Institute of the Russian Academy of Sciences
Russian Federation
Russian Federation
38 Vavilov str., Moscow, 119991
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Review
For citations:
Kuznetsov S.V., Nizamutdinov A.S., Mayakova M.N., Voronov V.V., Madirov E.I., Khadiev A.R., Spassky D.A., Kamenskikh I.A., Yapryntsev A.D., Ivanov V.K., Marisov M.A., Semashko V.V., Fedorov P.P. Synthesis and down-conversion luminescence of Ba4Y3F17:Yb:Pr solid solutions for photonics. Nanosystems: Physics, Chemistry, Mathematics. 2019;10(2):190-198. https://doi.org/10.17586/2220-8054-2019-10-2-190-198
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