Formation of rhabdophane-structured lanthanum orthophosphate nanoparticles in an impinging-jets microreactor and rheological properties of sols based on them
https://doi.org/10.17586/2220-8054-2019-10-2-206-214
Abstract
A free impinging-jets microreactor was used for synthesizing rhabdophane-structured LaPO4 sols. The rheological behavior was investigated for the sols obtained both by reagents mixing in a microreactor, and by pouring the initial solutions together and mixing them on a magnetic stirrer. Lanthanum phosphate sols obtained by two ways are structured systems characterized by deformation behavior accompanied by shear liquefaction. Some discovered anomalies were found to be associated with flow nonequilibrium at low shear rates, which indirectly indicates stronger binding of particles in the structure of samples obtained by the microreactor synthesis.
Supporting agencies: Rheological and X-ray diffraction studies, scanning electron microscopy and elemental analysis of samples were performed employing the equipment of the Engineering Center of the Saint Petersburg State Institute of Technology (Technical University). We thank our colleague D. P. Danilovich for his contribution to the project. Structural characterization was made on the equipment of the Federal Joint Research Centre “Material science and characterization in advanced technology” (Ioffe Institute, Saint Petersburg, Russia). The authors would like to thank V. N. Nevedomsky for his assistance. This work was supported by the Russian Foundation for Basic Research (project No 18-29-12119).
About the Authors
O. V. Proskurina
Saint Petersburg State Institute of Technology ; Ioffe Institute
Russian Federation
Russian Federation
Moskovsky Pr., 26, Saint Petersburg, 190013
Politekhnicheskaya Saint 26, Saint Petersburg, 194021
E. V. Sivtsov
Saint Petersburg State Institute of Technology
Russian Federation
Russian Federation
Moskovsky Pr., 26, Saint Petersburg, 190013
M. O. Enikeeva
Saint Petersburg State Institute of Technology ; Ioffe Institute
Russian Federation
Russian Federation
Moskovsky Pr., 26, Saint Petersburg, 190013
Politekhnicheskaya Saint 26, Saint Petersburg, 194021
A. A. Sirotkin
Saint Petersburg State Institute of Technology
Russian Federation
Russian Federation
Moskovsky Pr., 26, Saint Petersburg, 190013
R. Sh. Abiev
Saint Petersburg State Institute of Technology
Russian Federation
Russian Federation
Moskovsky Pr., 26, Saint Petersburg, 190013
V. V. Gusarov
Ioffe Institute
Russian Federation
Russian Federation
Politekhnicheskaya Saint 26, Saint Petersburg, 194021
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Review
For citations:
Proskurina O.V., Sivtsov E.V., Enikeeva M.O., Sirotkin A.A., Abiev R.Sh., Gusarov V.V. Formation of rhabdophane-structured lanthanum orthophosphate nanoparticles in an impinging-jets microreactor and rheological properties of sols based on them. Nanosystems: Physics, Chemistry, Mathematics. 2019;10(2):206-214. https://doi.org/10.17586/2220-8054-2019-10-2-206-214
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