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A surface and catalytic investigation of ceria by laser desorption ionization mass spectrometry

https://doi.org/10.17586/2220-8054-2017-8-2-290-295

Abstract

Gd0.1Ti0.1Zr0.1Ce0.7O2 solid solution with crystallite size of 10 nm, specific surface area of 85 m2 /g and pore size of 2–6 nm has been prepared by a simple co-precipitation method with sonication and characterized by several methods. Among the characterization methods was laser desorption ionization-time of flight mass spectrometry (LDI-TOF) which was used to characterize the surface of the catalyst (fresh and used in CO oxidation) and thereby determine the catalytic sites (active sites of oxidation).

About the Authors

I. V. Zagaynov
A. A. Baikov Institute of Metallurgy and Materials Science
Russian Federation

Leninskii pr. 49, Moscow



A. K. Buryak
A. N. Frumkin Institute of Physical Chemistry and Electrochemistry
Russian Federation

Leninskii pr. 31, Moscow



References

1. Trovarelli A. Catalysis by Ceria and Related Materials. World Scientific Publishing Company, Singapore, 2002, 528 p.

2. Trovarelli A., Fornasiero P. Catalysis by Ceria and Related Materials (2nd ed.). World Scientific Publishing Company, Singapore, 2013, 908 p.

3. Chaudhary S., Sharma P., Kumar R., Mehta S.K. Nanoscale surface designing of cerium oxide nanoparticles for controlling growth, stability, optical and thermal properties. Ceram. Int., 2015, 41, P. 10995–11003.

4. Venkataswamy P., Jampaiah D., Aniz C.U., Reddy B.M. Investigation of physicochemical properties and catalytic activity of nanostructured Ce0.7M0.3O2−δ (M = Mn, Fe, Co) solid solutions for CO oxidation. J. Chem. Sci., 2015, 127, P. 1347–1360.

5. Vinodkumar T., Durgasri D.N., Maloth S., Reddy B.M. Tuning the structural and catalytic properties of ceria by doping with Zr4+, La3+ and Eu3+ cations. J. Chem. Sci., 2015, 127, P. 1145–1153.

6. Ingram A.J., Boeser C.L., Zare R.N. Going beyond electrospray: mass spectrometric studies of chemical reactions in and on liquids. Chem. Sci., 2016, 7, P. 39–55.

7. Henderson W., McIndoe J.S. Mass Spectrometry of Inorganic, Coordination and Organometallic Compounds. John Willey & Sons, London, 2005, 292 p.

8. Aneggi E., Divins N.J., et al. The formation of nanodomains of Ce6O11 in ceria catalyzed soot combustion. J. Catal., 2014, 312, P. 191–194.

9. Buryak A.K., Serduk T.M. Chromatography–mass spectrometry in aerospace industry. Russ. Chem. Rev., 2013, 82 (4), P. 369–392.

10. Zagaynov I.V., Buryak A.K. Mesoporous nanoscale ceria: synthesis from cerium (III) acetylacetonate and mechanism. J. Sol-Gel Sci. Technol., 2015, 74, P. 103–108.

11. Zagaynov I.V. Sonochemical synthesis of mesoporous GdxZryTizCe1−x−y−zO2 solid solution. Ceram. Int., 2015, 41, P. 8730–8734.

12. Zagaynov I.V., Liberman, E.Yu., Naumkin A.V. GdxZryTizCe1−x−y−zO2 mesoporous catalysts for oxidation reactions. Surf. Sci., 2015, 642, P. L11–L15.

13. Trovarelli A. Catalytic properties of ceria and CeO2-containing materials. Catal. Rev., 1996, 38, P. 439–520.

14. Alammar T., Chow Y.-K., Mudring A.-V. Energy efficient microwave synthesis of mesoporous Ce0.5M0.5O2 (Ti, Zr, Hf) nanoparticles for low temperature CO oxidation in an ionic liquid – a comparative study. New J. Chem., 2015, 39, P. 1339–1347.


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For citations:


Zagaynov I.V., Buryak A.K. A surface and catalytic investigation of ceria by laser desorption ionization mass spectrometry. Nanosystems: Physics, Chemistry, Mathematics. 2017;8(2):290-295. https://doi.org/10.17586/2220-8054-2017-8-2-290-295

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ISSN 2220-8054 (Print)
ISSN 2305-7971 (Online)