Two facile routes for functionalization of WS2 nanotubes with silver nanoparticles
https://doi.org/10.17586/22208054201785628634
Abstract
Silvercoated WS2 nanotubes (NTWS 2) were successfully synthesized via two wet chemistry techniques. The first employs spontaneous silver nanoparticle growth resulting from an interaction of disulfide nanotubes with AgNO3 in aqueous suspensions at 100 C without any additional reducing agents or stabilizers. The second utilizes [Ag(NH3)2]OH complex to produce silver nanoparticles upon thermal decomposition. Both techniques are capable of producing AgNTWS 2 nanocomposites containing 5–60 nm silver nanoparticles tightly attached to the nanotubes’ surfaces. The hexagonal arrangement of sulfur atoms of the outer WS2 layer was postulated to facilitate crystallization of silver nanocrystals with hexagonal crystallographic system (4H–Ag). The physicalchemical model for spontaneous AgNP formation is proposed.
Keywords
WS<2>текст nanotubes,
silver nanoparticles,
plasmonic nanoparticles,
nanocomposite,
spontaneous growth,
4H silver
Supporting agencies: This work is supported by the Russian Science Foundation (grant 141300871), AYP acknowledges partial personal support by the Russian Foundation for Basic Research (project # 163301058 mol a) and Lomonosov Moscow State University Program of Development (the use of Carl Zeiss Libra 200 MC microscope). Authors thank Maria Poliakova (Tsukuba University, Japan) for the proofreading.
About the Authors
A. Yu. Polyakov
Department of Materials Science, Lomonosov Moscow State University
Russian Federation
Russian Federation
173 Leninskiye gory, Moscow, 119991
V. A. Lebedev
Department of Materials Science, Lomonosov Moscow State University
Russian Federation
Russian Federation
173 Leninskiye gory, Moscow, 119991
L. Yadgarov
Tel Aviv University
Israel
Israel
P. O. Box 39040, Tel Aviv 6997801
E. A. Goodilin
Department of Materials Science, Lomonosov Moscow State University
Russian Federation
Russian Federation
173 Leninskiye gory, Moscow, 119991
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For citations:
Polyakov A.Yu., Lebedev V.A., Yadgarov L., Goodilin E.A. Two facile routes for functionalization of WS2 nanotubes with silver nanoparticles. Nanosystems: Physics, Chemistry, Mathematics. 2017;8(5):628–634. https://doi.org/10.17586/22208054201785628634
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