Preview

Nanosystems: Physics, Chemistry, Mathematics

Advanced search

Investigation of the initial stages of spark-plasma sintering of Si–Ge based thermoelectric materials

https://doi.org/10.17586/2220-8054-2018-9-5-622-630

Abstract

Thermoelectric materials based on a mixture of Ge–Si nanopowders were fabricated and investigated. The materials were obtained by spark plasma sintering technique using the modes corresponding to the initial stages of sintering of the powder particles. The possibility for controlling the electrical characteristics of materials (type and magnitude of conductivity, the Seebeck coefficient) by varying the sintering parameters was shown. It was found that the analysis of electrical characteristics allows one to draw conclusions about the degree of mixing for silicon and germanium in the sintered material. 

About the Authors

M. V. Dorokhin
Lobachevsky State University of Nizhniy Novgorod
Russian Federation

Gagarin ave. 23/3, 603950, Nizhniy Novgorod



I. V. Erofeeva
Lobachevsky State University of Nizhniy Novgorod
Russian Federation

Gagarin ave. 23/3, 603950, Nizhniy Novgorod



Yu. M. Kuznetsov
Lobachevsky State University of Nizhniy Novgorod
Russian Federation

Gagarin ave. 23/3, 603950, Nizhniy Novgorod



M. S. Boldin
Lobachevsky State University of Nizhniy Novgorod
Russian Federation

Gagarin ave. 23/3, 603950, Nizhniy Novgorod



A. V. Boryakov
Lobachevsky State University of Nizhniy Novgorod
Russian Federation

Gagarin ave. 23/3, 603950, Nizhniy Novgorod



A. A. Popov
Lobachevsky State University of Nizhniy Novgorod
Russian Federation

Gagarin ave. 23/3, 603950, Nizhniy Novgorod



E. A. Lantsev
Lobachevsky State University of Nizhniy Novgorod
Russian Federation

Gagarin ave. 23/3, 603950, Nizhniy Novgorod



N. V. Sakharov
Lobachevsky State University of Nizhniy Novgorod
Russian Federation

Gagarin ave. 23/3, 603950, Nizhniy Novgorod



P. B. Demina
Lobachevsky State University of Nizhniy Novgorod
Russian Federation

Gagarin ave. 23/3, 603950, Nizhniy Novgorod



A. V. Zdoroveyshchev
Lobachevsky State University of Nizhniy Novgorod
Russian Federation

Gagarin ave. 23/3, 603950, Nizhniy Novgorod



V. N. Trushin
Lobachevsky State University of Nizhniy Novgorod
Russian Federation

Gagarin ave. 23/3, 603950, Nizhniy Novgorod



References

1. Rowe Ed.D.M. Termoelectric hand book macro to nano. CRC Press, Boca Raton, 2006.

2. Hicks L., Dresselhaus M. Thermoelectric figure of merit of a one-dimensional conductor. Physical Revew B, 1993, 47, P. 16631–16634.

3. Minnich A.J., Dresselhaus M.S., Ren Z.F., Chen G. Bulk Nanostructured Thermoelectric Materials: Current Research and Future Prospects. Energy & Environmental Science, 2009, 2 (5), P. 466–479.

4. Cook B.A., Harringa J.L., Han S.H., Vining C.B. Si80Ge20 thermoelectric alloys prepared with GaP additions. J. Appl. Phys., 1995, 78, P. 5474–5480.

5. Cook B.A., Harringa J.L., Han S.H., Beaudry B.J. Parasitic effects of oxygen on the thermoelectric properties of Si80Ge20 doped with GaP and P. J. Appl. Phys., 1992, 72, P. 1423–1428.

6. Lahwal A., Bhattacharya S., et al. Impact of yttria stabilized zirconia nanoinclusions on the thermal conductivity of n-type Si80Ge20 alloys prepared by spark plasma sintering. J. Appl. Phys., 2015, 117, 145101.

7. Usenko A., Moskovskikh D., et al. Thermoelectric Properties of n-Type Si0.8Ge0.2–FeSi2 Multiphase Nanostructures. Scripta Materialia, 2017, 127, P. 63–69.

8. Bathula S., Jayasimhadri M., Dhar A. Mechanical properties and microstructure of spark plasma sintered nanostructured p-type SiGe thermoelectric alloys. Materials & Design, 2015, 87, P. 414–440.

9. Zamanipour Z., Shi X., et al. The effect of synthesis parameters on transport properties of nanostructured bulk thermoelectric ptype silicon germanium alloy. Physica status solidi (a), 2012, 209 (10), P. 2049–2058.

10. Dismukes, J.P., Ekstrom L., et al. Thermal and electrical properties of heavily doped Ge–Si alloys up to 1300 K. J. Appl. Phys., 1964, 35, P. 2899–2907.

11. Weber L., Gmelin E. Transport properties of silicon. Applied Physics A, 1991, 53, P. 136–140.

12. Boukai A.I., Bunimovich Y., et al. Silicon Nanowires as Efficient Thermoelectric Materials. Nature, 2008, 451, P. 168–171.

13. Sze S.M., Ng Kwok K. Physics of Semiconductor Devices. John Wiley & Sons. Hoboken, New Jersey, 2006, 832 p.


Review

For citations:


Dorokhin M.V., Erofeeva I.V., Kuznetsov Yu.M., Boldin M.S., Boryakov A.V., Popov A.A., Lantsev E.A., Sakharov N.V., Demina P.B., Zdoroveyshchev A.V., Trushin V.N. Investigation of the initial stages of spark-plasma sintering of Si–Ge based thermoelectric materials. Nanosystems: Physics, Chemistry, Mathematics. 2018;9(5):622-630. https://doi.org/10.17586/2220-8054-2018-9-5-622-630

Views: 5


Creative Commons License
This work is licensed under a Creative Commons Attribution 4.0 License.


ISSN 2220-8054 (Print)
ISSN 2305-7971 (Online)