Electrocatalytic properties of γ-NiOOH nanolayers, synthesized by successive ionic layer deposition, during the oxygen evolution reaction upon water splitting in the alkaline medium
https://doi.org/10.17586/2220-8054-2018-9-5-669-675
Abstract
Nickel oxyhydroxide nanolayers were synthesized on the surface of nickel foam and single crystalline silicon through Successive Ionic Layer Deposition (SILD) method by using aqueous solutions NiSO4 and K2S2O8. The obtained nanolayers were characterized by SEM, XRD, FTIR and XPS spectroscopy. The electrochemical properties of the electrodes were defined from polarization curves. SEM images revealed that nanolayers are formed by nanosheets with a thickness of 6 – 10 nm. The nanolayers were shown to exhibit electrocatalytic properties during the oxygen evolution reaction upon water splitting in the alkaline medium. By setting the number of SILD cycles, these properties can be changed precisely. For a number of samples, synthesized after 30 – 120 SILD cycles, it was found that in the oxygen evolution reaction the lowest overpotential value of 260 mV and the lowest Tafel slope of 54 mV/dec are achieved for the sample, synthesized after 90 SILD cycles.
Supporting agencies: This work was supported by the Russian Science Foundation (project No. 18-19-00370). We grateful to the Centres for X-ray Diffraction Studies, Nanotechnology and Physical Methods of Surface Investigation of Saint-Petersburg State University for their technical assistance with the investigation of the synthesized product.
About the Authors
A. A. Lobinsky
Institute of Chemistry, Saint Petersburg State University
Russian Federation
Russian Federation
26 University Pr., St. Peterhof, Saint Petersburg, 198504
V. P. Tolstoy
Institute of Chemistry, Saint Petersburg State University
Russian Federation
Russian Federation
26 University Pr., St. Peterhof, Saint Petersburg, 198504
V. P. Tolstoy
Institute of Chemistry, Saint Petersburg State University
Russian Federation
Russian Federation
26 University Pr., St. Peterhof, Saint Petersburg, 198504
I. A. Kodinzev
Institute of Chemistry, Saint Petersburg State University
Russian Federation
Russian Federation
26 University Pr., St. Peterhof, Saint Petersburg, 198504
References
1. Bandal H., Koteshwara Reddy K., Chaugule A., Kim H. Iron-based heterogeneous catalysts for oxygen evolution reaction; change in perspective from activity promoter to active catalyst. J. Power Sources, 2018, 395, P. 106–127.
2. Hunter B.M., Winkler J.R., Gray H.B. Iron is the active site in nickel/iron water oxidation electrocatalysts. Molecules, 2018, 4, P. 903–910.
3. Ya Yan, Bao Yu Xia, Bin Zhao, Xin Wang. A review on noble-metal-free bifunctional heterogeneous catalysts for overall electrochemical water splitting. J. Mater. Chem. A, 2016, 4, P. 17587–17603.
4. Yuanyuan Ma, Xiaoli Dong, Renhe Wang, Duan Bin, Yonggang Wang, Yongyao Xia. Combining water reduction and liquid fuel oxidization by nickel hydroxide for flexible hydrogen production. Energy Storage Materials, 2018, 11, P. 260–266.
5. Sarycheva A.S., Semenova A.A., Goodilin E.A. Vapor phase SERS sensor based on mesoporous silica decorated with silver nanoparticles. Nanosystems: Physics, Chemistry, Mathematics, 2017, 8(5), P. 579–585.
6. Krasilin A.A., Gusarov V.V. Redistribution of Mg and Ni cations in crystal lattice of conical nanotube with chrysotile structure. Nanosystems: Physics, Chemistry, Mathematics, 2017, 8(5), P. 620–627.
7. Nguyen A.T., Phan Ph.H.Nh., Mittova I.Ya., Knurova M.V., Mittova V.O. The characterization of nanosized ZnFe2O4 material prepared by coprecipitation. Nanosystems: Physics, Chemistry, Mathematics, 2016, 7(3), P. 459–463.
8. Mingshu Xiao, Yanping Tian, Yuhua Yan, Kai Feng, Yuqing Miao. Electrodeposition of Ni(OH)2/NiOOH in the presence of urea for the improved oxygen evolution. Electrochimica Acta, 2015, 164, P. 196–202.
9. Hidalgo-Acosta J.C., Scanlon M.D., Mendez M.A., Amstutz V., Vrube H., Opallo M., Giraulta H.H.. Boosting water oxidation layer-by- ´ layer. Phys. Chem. Chem. Phys., 2016, 13, P. 9295–9304. [10] Bryan H.R. Suryanto, Xunyu Lua, Chuan Zhao. Layer-by-layer assembly of transparent amorphous Co3O4 nanoparticles/graphene composite electrodes for sustained oxygen evolution reaction. J. Mater. Chem. A, 2013, 1, P. 12726–12731.
10. Lobinsky A.A., Tolstoy V.P. Red-ox reactions in aqueous solutions of Co(OAc)2 and K2S2O8 and synthesis of CoOOH nanolayers by the SILD method. Nanosystems: Physics, Chemistry, Mathematics, 2015, 6(6), P. 1–7.
11. Kuklo L.I., Tolstoy V.P. Successive ionic layer deposition of Fe3O4@HxMoO4·nH2O composite nanolayers and their superparamagnetic properties. Nanosystems: Physics, Chemistry, Mathematics, 2016, 7(6), P. 1050–1054.
12. Tolstoy V.P., Kodintsev I.A., Reshanova K.S., Lobinsky A.A. A brief review of metal oxide (hydroxide)-graphene nanocomposites synthesis by layer-by-layer deposition from solutions and synthesis of CuO nanorods-graphene nanocomposite. Rev. Adv. Mater. Sci., 2017, 49, P. 28–37.
13. Lobinsky A.A., Tolstoy V.P., Gulina L.B. A novel oxidation-reduction route for successive ionic layer deposition of NiO1+x·nH2O nanolayers and their capacitive performance. Materials Research Bulletin, 2016, 76, P. 229–234.
14. Mingjun Pang, Guohui Long, Shang Jianc, Yuan Ji, Wei Han, Biao Wang, Xilong Liu, Yunlong Xi. One pot low-temperature growth of hierarchical d-MnO2 nanosheets on nickel foam for supercapacitor applications. Electrochim. Act., 2015, 161, P. 297–304.
15. Lobinsky A.A., Tolstoy V.P., Gulina L.B. Direct synthesis of Co2Al(OH)7−2x(CO3)x·nH2O layered doublehydroxide nanolayers by successive ionic layer deposition and their capacitive performance. Applied Surface Science, 2014, 320, P. 609–613.
16. Tolstoy V.P., Chernyshova I.V., Skryshevsky V.A. Handbook of infrared spectroscopy of ultrathin films. John Wiley & Sons, Inc., Hoboken, New Jersey, 2003, 710 p.
17. Kashani M.M., Youzbashi A.A., Hashemzadeh F., Sabaghzadeh L. Structural properties of nickel hydroxide/oxyhydroxide and oxide nanoparticles obtained by microwave-assisted oxidation technique. Powder Technol., 2013, 237, P. 562–568.
18. Cerc Koroseca R., Bukoveca P., Pihlar B., ˇ Surca Vukb A., Orelb B., Draˇzi ˇ c G. Preparation and structural investigations of electrochromic ˇ nanosized NiOx films made via the sol-gel route. Solid State Ionics, 2003, 165, P. 191–200.
19. Ren Y., Chim W.K., Guo L., Tanoto H., Pan J., Chiam S.Y. The coloration and degradation mechanisms of electrochromic nickel oxide. Solar Energy Mater. Solar Cells, 2013, 116, P. 83–88.
20. Gui Chen, Lingjing Chen, Siu-Mui Ng, Tai-Chu Lau. Efficient chemical and visible-light-driven water oxidation using nickel complexes and salts as precatalysts. Chem. Sus. Chem., 2014, 7, P. 127–134.
21. Biesinger M.C., Payne B.P., Grosvenor A.P., Lau L.W.M., Gerson A.R., Smart R.St.C. Resolving surface chemical states in XPS analysis of first row transition metals, oxides and hydroxides: Cr, Mn, Fe, Co and Ni. Appl. Surf. Sci., 2011, 257, P. 2717–2730.
22. Fomanyuk S.S. Electrochromic and gasochromc properties thin films of nickel hydroxide. Metal physics and advanced technologies, 2011, 33, P. 297–306.
23. Kim B., Oh A., Kabiraz M.K., Hong Y., Joo J., Baik H., Choi S.-I., Lee K. NiOOH exfoliation-free nickel octahedra as highly active and durable electrocatalysts toward the oxygen evolution reaction in an alkaline electrolyte. ACS Appl. Mater. Interfaces, 2018, 10, P. 10115–10122.
24. Qiong Zhang, Cancan Zhang, Jianbo Liang, Penggang Yin, Yang Tian. Orthorhombic α-NiOOH nanosheet arrays: phase conversion and efficient bifunctional electrocatalysts for full water splitting. ACS Sustainable Chem. Eng., 2017, 5(5), P. 3808–3818.
25. Diaz-Morales O., Ferrus-Suspedra D., Koper M.T.M. The importance of nickel oxyhydroxide deprotonation on its activity towards electrochemical water oxidation. Chem Sci., 2016, 7(4), P. 2639–2645.
26. Cian-Tong Lu, Yen-Wen Chiu, Mei-Jing Li, Kan-Lin Hsueh, Ju-Shei Hung. Reduction of the electrode overpotential of the oxygen evolution reaction by electrode surface modification. Int. J. of Electrochem., 2017, 2017, 7494571.
Review
For citations:
Lobinsky A.A., Tolstoy V.P., Tolstoy V.P., Kodinzev I.A. Electrocatalytic properties of γ-NiOOH nanolayers, synthesized by successive ionic layer deposition, during the oxygen evolution reaction upon water splitting in the alkaline medium. Nanosystems: Physics, Chemistry, Mathematics. 2018;9(5):669-675. https://doi.org/10.17586/2220-8054-2018-9-5-669-675
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