Pt nanoparticle-functionalized RGO counter electrode for efficient dye-sensitized solar cells
https://doi.org/10.17586/2220-8054-2019-10-6-637-641
Abstract
In this paper, we present a facile method for replacing conventional Pt-based counter electrode (CE) in dye-sensitized solar cells (DSCs) for the alternative low-cost nanostructured material containing reduced graphene oxide (RGO). Pt-NPs/RGO-based nanohybrid layers were synthesized at low temperature on a conductive glass substrate using microwave-assisted heating reduction strategy. The obtained material was characterized using XRD, SEM and TEM measurements and used for fabrication layered CEs on glass substrates. Photovoltaic characteristics of the DSCs based on Pt nanoparticle-functionalized RGO CEs were investigated under simulated AM1.5G solar illumination at an intensity of 1000 W/m2. The obtained results have shown that Pt-NPs decorated RGO surfaces can be successfully used as CEs in high-efficiency DSCs and may be promising as low-cost electrodes in energy storage devices.
Keywords
About the Authors
O. V. AlexeevaRussian Federation
Department of Solar Photovoltaics
Kosygin St. 4, Moscow, 119334
S. S. Kozlov
Russian Federation
Department of Solar Photovoltaics
Kosygin St. 4, Moscow, 119334
L. L. Larina
Russian Federation
Department of Solar Photovoltaics
Kosygin St. 4, Moscow, 119334
O. I. Shevaleevskiy
Russian Federation
Department of Solar Photovoltaics
Kosygin St. 4, Moscow, 119334
References
1. O’Regan B., Gratzel M. A low-cost, high-efficiency solar cell based on dye-sensitized colloidal TiO2 films. Nature, 1991, 353, P. 737–740.
2. Shevaleevskiy O. The future of solar photovoltaics: from physics to chemistry. Pure Appl. Chem., 2008, 80, P. 2079–2089.
3. Nikolay T., Larina, L., Shevaleevskiy O., Ahn B.T. Electronic structure study of lightly Nb-doped TiO2 electrode for dye-sensitized solar cells. Energ. Environ. Sci., 2011, 4, P.1480–1486.
4. Vildanova M.F., Nikolskaia A.B., Kozlov S.S., Shevaleevskiy O.I., Larina L.L. Novel types of dye-sensitized and perovskite-based tandem solar cells with a common counter electrode. Tech. Phys. Lett., 2018, 44(2), P. 126–129.
5. Yum J., Jung I., Baik. C., Ko J., Nazeeruddin M.K., Gratzel M. High efficient donor–acceptor ruthenium complex for dye-sensitized solar cell application. Energ. Environ. Sci. 2009, 2, P. 100–102.
6. Dao V.D., Choi Y., Yong K., Larina L.L., Shevaleevskiy O., Choi H.-S. A facile synthesis of bimetallic AuPt nanoparticles as a new transparent counter electrode for quantum-dot-sensitized solar cells. J. Power Sources, 2015, 274, P. 831–838.
7. Larina L.L., Alexeeva O.V., Almjasheva O.V., Gusarov V.V., Kozlov S.S., Nikolskaia A.B., Vildanova M.F., Shevaleevskiy O.I. Very widebandgap nanostructured metal oxide materials for perovskite solar cells. Nanosystems: Phys. Chem. Math., 2019, 10(1), P. 70–75.
8. Almjasheva O.V., Smirnov A.V., Fedorov B.A., Tomkovich M.V., Gusarov V.V. Structural features of ZrO2–Y2O3 and ZrO2–Gd2O3 nanoparticles formed under hydrothermal conditions. Russ. J. Gen. Chem., 2014, 84(5), P. 804–809.
9. Bugrov A.N., Almjasheva O.V. Effect of hydrothermal synthesis conditions on the morphology of ZrO2 nanoparticles. Nanosystems: Phys. Chem. Math., 2013, 4, P. 810–815.
10. Kannan A.G., Zhao J., Jo S.G., Kang Y.S., Kim D.-W. Nitrogen and sulfur co-doped graphene counter electrodes with synergistically enhanced performance for dye-sensitized solar cells. J. Mater. Chem. A, 2014, 2, P. 12232–12239.
11. Somik M., Balavinayagam R., Griggs L., Hamm S., Baker G.A., Fraundorf P., Sengupta S., Gangopadhyay S. Ultrafine sputter-deposited Pt nanoparticles for triiodide reduction in dye-sensitized solar cells: impact of nanoparticle size, crystallinity and surface coverage on catalytic activity. Nanotechnology, 2012, 23, P. 485405.
12. Dao V.-D., Hoa N.T.Q., Larina L.L., Lee J.-K., Choi H.-S. Graphene-platinum nanohybrid as a robust and low-cost counter electrode for dye-sensitized solar cells. Nanoscale, 2013, 5, P. 12237–12244.
13. Chen J., Yao B., Li C., Shi G. An improved Hummers method for eco-friendly synthesis of graphene oxide. Carbon, 2013, 64, P. 225–229.
14. Gong F., Wang H., Wang Z.-S., Self-assembled monolayer of graphene/Pt as counter electrode for efficient dye-sensitized solar cell. Phys. Chem. Chem. Phys., 2011, 13, P. 17676–17682.
15. Qui L., Zhang H., Wang W., Chen Y., Wang. R. Effects of Pt/RGO as counter electrode in dye-sensitized solar cells. Appl. Surf. Sci., 2014, 319, P. 339–343.
16. Zhang D.W., Li X.D., Li H.B., Chen S., Sun Z., Yin X.J., Huang S.M. Graphene-based counter electrode for dye-sensitized solar cells. Carbon, 2011, 49(15), P. 5382–5388.
17. Ahn H.-J., Lee J.-S., Kim H.-S., Hwang I.-T., Hong J.-H., Shin J., Jung C.-H. Fabrication of large Pt nanoparticles-decorated rGO counter electrode for highly efficient DSSCs. J. Ind, Eng. Chem., 2018, 65, P. 318–324.
18. Yoon S.-W., Dao V.-D., Larina L.L., Lee J.-K., Choi H.-S. Optimum strategy for designing PtCo alloy/reduced graphene oxide nanohybrid counter electrode for dye-sensitized solar cells. Carbon, 2016, 96, P. 229–336.
19. Dao V.-D., Ko S.H., Choi H.-S., Lee J.-K. Pt-NP–MWNT nanohybrid as a robust and low-cost counter electrode material for dye-sensitized solar cells. J. Mater. Chem., 2012, 22, P. 14023–14029.
20. Dao V.-D., Tran C.Q., Ko S.-H., Choi H.-S. Dry plasma reduction to synthesize supported platinum nanoparticles for flexible dye-sensitized solar cells. J. Mater. Chem. A, 2013, 1, P. 4436–4443.
Review
For citations:
Alexeeva O.V., Kozlov S.S., Larina L.L., Shevaleevskiy O.I. Pt nanoparticle-functionalized RGO counter electrode for efficient dye-sensitized solar cells. Nanosystems: Physics, Chemistry, Mathematics. 2019;10(6):637-641. https://doi.org/10.17586/2220-8054-2019-10-6-637-641