Express analysis of endohedral fullerenes amount contained at fullerene mixture
https://doi.org/10.17586/2220-8054-2016-7-1-140-145
Abstract
This paper describes the technique for rapid determination of endohedral metallofullerene (EMF) content in a fullerene mixture (FM). The methods of mass spectroscopy and atom emission element analysis underlay at the technique. By the method of mass spectroscopy, the type of EMF with atom-guest is registered and by the method of emission spectroscopy, the quantity of that element which is contained in the FM is determined. The technique may be used for rapid determination of EMF weight percents in the FM in the specific case if only one type of EMF is present, and of EMF average content if there are different types of EMF are present. The technique is demonstrated through the example of analysis of FM with Y, which was extracted from the carbon condensate (CC) by different solvents (C5H5N and CS2).
Supporting agencies: The work was supported by the Ministry of Education and Science of Russia (Russian-Japanese joined project, Agreement N 14.613.21.0010, ID RFMEFI61314X0010).
About the Authors
G. N. Churilov
Kirensky Institute of Physic SB RAS; Siberian Federal University
Russian Federation
Russian Federation
Krasnoyarsk
A. A. Popov
Leibniz Institute for Solid State and Materials Research
Germany
Germany
Dresden
U. E. Guliaeva
Kirensky Institute of Physic SB RAS; Siberian Federal University
Russian Federation
Russian Federation
Krasnoyarsk
N. A. Samoylova
Leibniz Institute for Solid State and Materials Research
Germany
Germany
Dresden
N. G. Vnukova
Kirensky Institute of Physic SB RAS; Siberian Federal University
Russian Federation
Russian Federation
Krasnoyarsk
A. L. Kolonenko
Kirensky Institute of Physic SB RAS
Russian Federation
Russian Federation
Krasnoyarsk
V. G. Isakova
Kirensky Institute of Physic SB RAS
Russian Federation
Russian Federation
Krasnoyarsk
A. I. Dudnik
Kirensky Institute of Physic SB RAS; Siberian Federal University
Russian Federation
Russian Federation
Krasnoyarsk
V. S. Koravanets
Siberian Federal University
Russian Federation
Russian Federation
Krasnoyarsk
References
1. Yang S., Liu F., Chen C., Jiao M., Wei T. Fullerenes encaging metal clusters - clusterfullerenes. Chem. Commun., 2011, 47, P. 11822–11839.
2. Meng J., Wang D.L., Wang P.C., J. Biological characterization of [Gd@C82(OH)22]n nanoparticles as fullerene derivatives for cancer therapy. Nanosci. Nanotechnol, 2010, 10(12), P. 8610–8616.
3. Popov A.A., Yang S., Dunsch L. Endohedral fullerenes. Chem. Rev., 2013, 113, P. 5989–6113.
4. Kareev I.E., Laukhina E., Bubnov V.P., Martynenko V.M., Lloveras V., Vidal-Gancedo J., Mas-Torrent M., Veciana J., Rovira C. Harnessing Electron Transfer from the Perchlorotriphenylmethide Anion to Y@C82(C2v) to Engineer an Endometallofullerene-Based Salt. Chem. Phys. Chem., 2013, 14, P. 1670.
5. Churilov G.N. Plasma Synthesis of Fullerenes. Instruments and Experimental Techniques, 2000, 43(1), P. 1– 10.
6. Churilov G.N., Kratschmer W., Osipova I.V., Glushenko G.A., Vnukova N.G., Kolonenko A.L., Dudnik A.I. Synthesis of fullerenes in a high-frequency arc plasma under elevated helium pressure. Carbon, 2013, 62, P. 389–392.
7. Terek T., Mika J. Gegush E. Emission spectrochemical analysis. MIR, 1982, 464 p.
Review
For citations:
Churilov G.N., Popov A.A., Guliaeva U.E., Samoylova N.A., Vnukova N.G., Kolonenko A.L., Isakova V.G., Dudnik A.I., Koravanets V.S. Express analysis of endohedral fullerenes amount contained at fullerene mixture. Nanosystems: Physics, Chemistry, Mathematics. 2016;7(1):140-145. https://doi.org/10.17586/2220-8054-2016-7-1-140-145
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