Preview

Наносистемы: физика, химия, математика

Расширенный поиск

Electrical properties of hot wall deposited PbTe–SnTe thin films

Аннотация

Polycrystalline Pb1−xSnxTe (0.0 ≤ x ≤ 1.0) telluride alloys were synthesized by the direct fusion technique. Thin films of these materials were prepared by a hot wall deposition method on glass substrates at Tsub =230–330 C and in a vacuum of about 10−5 Torr. The microstructure of the films was characterized by XRD, SEM, EDX and AES. The films showed a natural cubic structure. The thin films’ microstructure consisted of densely packed grains with dimensions of 50–300 nm and crystallite growth direction is perpendicular to substrate plane. The as-grown Pb1−xSnxTe films showed p-type conductivity. Thermoelectric measurements of the films showed high values for the room-temperature Seebeck coefficient ranging, from 20 to 400 µV·K−1, for SnTe to PbTe thin films, respectively. The conductivity of the films was in the range of 3·101–1·104 −1·cm−1.

Об авторах

V. Ivanov
State Scientific and Production Association “Scientific-Practical Materials Research Centre of the National Academy of Sciences of Belarus
Беларусь


V. Gremenok
State Scientific and Production Association “Scientific-Practical Materials Research Centre of the National Academy of Sciences of Belarus
Беларусь


H. Seidi
State Scientific and Production Association “Scientific-Practical Materials Research Centre of the National Academy of Sciences of Belarus
Беларусь


S. Zimin
Yaroslavl State University
Россия


E. Gorlachev
Yaroslavl State University
Россия


Список литературы

1. Goldsmith J.H. Thermoelectric refrigeration. Plenum New York, 2000, 281 p.

2. Nishida I.A. Grain size effect on thermoelectric properties of PbTe prepared by spark plasma sintering. Material Japan, JIM, 35, P. 943–947 (1996).

3. Dimmock J.O. Meingailis I. Band structure and laser action in PbxSn1−xTe. Phys. Rev. Lett., 26, P. 1193–1197 (1966).

4. Xing Gao, Murray S.D. Investigation of band inversion in (Pb,Sn)Te alloys using ab initio calculations. Physical Review B, 77, P. 033103 (2008).

5. Lopez O. Hot wall epitaxy. Thin Solid Films, 49, P. 3–7 (1978).

6. Schikora D., Sitter H., J. Humenberger J. High quality CdTe epilayers on GaAs grown by hot wall epitaxy. Appl. Phys. Lett., 48, P. 1276–1279 (1986).

7. Pal A.K., Mondal A., Chaudhuri S. Preparation and characterization of ZnTe/CdSe solar cells. Vacuum, 41, P. 1460–1463 (1990).

8. Seto S., Yamada S., Suzuki K. Growth kinetics and structural characterization of polycrystalline CdTe films grown by hot-wall vacuum evaporation. Solar Energy Materials and Solar Cells, 50, P. 133–137 (1998).

9. Muthukumarasamy N., Balasundaraprabhu R., Jayakumar S., Kannan M.D. Photoconductive properties of hot wall deposited CdSe0.6Te0.4 thin films. Materials Science and Engineering B, 137, P. 1–3 (2007).

10. Bashkirov S.A., Lazenka V.V., Gremenok V.F., Bente K. Microstructure of SnS thin films obtained by hot wall vacuum deposition method. J. Adv. Microsc. Res., 6, P. 153–156 (2011).

11. Bashkirov S.A., Gremenok V.F., et al. Tin sulfide thin films and ZnO/n-CdS/p-SnS/Mo heterojunctions for photovoltaic applications. Thin Solid Films, 520, P. 5807–5810 (2012).

12. Schaffler R., Klose M., Schock H.W. Pulsed laser deposition and characterization of CuInSe thin films for solar cell applications. Materials Science Forum Vois., 173, P. 135–138 (1995).

13. Farinre T.O., Zemel J.N. Preparation and properties of Pb1−xSnxTe epitaxial films. J. Vacuum Sci. Technology, 7, P. 121–123 (1970).


Рецензия

Для цитирования:


 ,  ,  ,  ,   . Наносистемы: физика, химия, математика. 2013;4(6):816-822.

For citation:


Ivanov V.A., Gremenok V.F., Seidi H.G., Zimin S.P., Gorlachev E.S. Electrical properties of hot wall deposited PbTe–SnTe thin films. Nanosystems: Physics, Chemistry, Mathematics. 2013;4(6):816-822.

Просмотров: 4


Creative Commons License
Контент доступен под лицензией Creative Commons Attribution 4.0 License.


ISSN 2220-8054 (Print)
ISSN 2305-7971 (Online)