La and Co-based materials for ammonia decomposition: activity, stability and structural changes
V. A. Borisov,
Z. A. Fedorova,
Z. N. Ichetovkin,
E. Y. Gerasimov,
D. A. Shlyapin,
A. Y. Stroeva,
V. L. Temerev,
A. B. Arbuzov,
S. V. Tsybulya,
P. V. Snytnikov,
A. V. Kuzmin https://doi.org/10.17586/2220-8054-2025-16-4-498-509
Abstract
The La0.9Sr0.1Sc0.9Co0.1O3-δ (LS) and La0.9Sr0.1CoO3-δ (LC) phases and composite materials based on them were synthesized. There are data in the literature on the activity of pure or modified forms of LC in ammonia decomposition, but there are no data on the activity of the LS phase and LS–LC composites. Therefore, the stability and activity of LS–LC composites and initial LS and LC in ammonia decomposition were investigated. The best result in the decomposition of ammonia at 700◦C and WHSV of 60000 ml NH3·g-1cat ·h-1 shows LC – 99%, the worst LS – 80%. Under the same conditions, the activity of samples LC, 40LS–60LC and 50LS–50LC remains unchanged for 40 hours. It was found that during ammonia decomposition, the LC phase decomposes to form cobalt and La(OH)3 nanoparticles, but the LS phase does not undergo significant changes, which is confirmed by X-ray diffraction, IR spectroscopy, Raman spectroscopy and TEM.
Supporting agencies: This work was supported by the Ministry of Science and Higher Education of the Russian Federation within the governmental assignment for the Boreskov Institute of Catalysis (project FWUR- 2024-0039 and FWUR-2024-0033). Physico-chemical studies were carried out using facilities of the shared research center “National center of investigation of catalysts” at Boreskov Institute of Catalysis.
About the Authors
V. A. Borisov
Center of New Chemical Technologies BIC, Boreskov Institute of Catalysis
Russian Federation
Russian Federation
Vadim A. Borisov
Neftezavodskaya st., 54, Omsk, 644040, Russia
Z. A. Fedorova
Boreskov Institute of Catalysis
Russian Federation
Russian Federation
Zaliya A. Fedorova
Lavrentiev Ave., 5, Novosibirsk, 630090, Russia
Z. N. Ichetovkin
Vyatka State University;
Institute of Solid State Chemistry and Mechanochemistry of the Siberian Branch of the RAS
Russian Federation
Russian Federation
Zakhar N. Ichetovkin - Department of Technology of Inorganic Materials and Electrochemical Production
Moskovskaya st., 36, Kirov, 610000, Russia
Kutateladze st., 18, Novosibirsk, 630128, Russia
E. Y. Gerasimov
Boreskov Institute of Catalysis
Russian Federation
Russian Federation
Evgeniy Y. Gerasimov
Lavrentiev Ave., 5, Novosibirsk, 630090, Russia
D. A. Shlyapin
Boreskov Institute of Catalysis
Russian Federation
Russian Federation
Dmitry A. Shlyapin
Lavrentiev Ave., 5, Novosibirsk, 630090, Russia
A. Y. Stroeva
Vyatka State University
Russian Federation
Russian Federation
Anna Y. Stroeva - Department of Technology of Inorganic Materials and Electrochemical Production
Moskovskaya st., 36, Kirov, 610000, Russia
V. L. Temerev
Center of New Chemical Technologies BIC, Boreskov Institute of Catalysis
Russian Federation
Russian Federation
Victor L. Temerev
Neftezavodskaya st., 54, Omsk, 644040, Russia
A. B. Arbuzov
Center of New Chemical Technologies BIC, Boreskov Institute of Catalysis
Russian Federation
Russian Federation
Alexey B. Arbuzov
Neftezavodskaya st., 54, Omsk, 644040, Russia
S. V. Tsybulya
Boreskov Institute of Catalysis
Russian Federation
Russian Federation
Sergey V. Tsybulya
Lavrentiev Ave., 5, Novosibirsk, 630090, Russia
P. V. Snytnikov
Boreskov Institute of Catalysis
Russian Federation
Russian Federation
Pavel V. Snytnikov
Lavrentiev Ave., 5, Novosibirsk, 630090, Russia
A. V. Kuzmin
Vyatka State University
Russian Federation
Russian Federation
Anton V. Kuzmin - Department of Technology of Inorganic Materials and Electrochemical Production
Moskovskaya st., 36, Kirov, 610000, Russia
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Borisov V.A., Fedorova Z.A., Ichetovkin Z.N., Gerasimov E.Y., Shlyapin D.A., Stroeva A.Y., Temerev V.L., Arbuzov A.B., Tsybulya S.V., Snytnikov P.V., Kuzmin A.V. La and Co-based materials for ammonia decomposition: activity, stability and structural changes. Nanosystems: Physics, Chemistry, Mathematics. 2025;16(4):498-509. https://doi.org/10.17586/2220-8054-2025-16-4-498-509
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