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ZnO nanoparticles as solar photocatalysts: Synthesis, effect of annealing temperature and applications

https://doi.org/10.17586/2220-8054-2020-11-6-672-679

Abstract

ZnO nanoparticles were prepared by a hydrothermal method from the source materials of Zinc acetylacetonate hydrate and ammonium hydroxide. Further prepared samples were annealed at various temperatures for 3 hours. X-ray diffraction analysiswas employed to study the structure and crystalline nature of synthesized nanoparticles. Scanning electron microscope images showed that the prepared ZnO nanoparticles acquired nano needle, hexagonal disk and porous nanorods structures due to the effect of annealing temperature. The photocatalytic activity of the prepared ZnO nanoparticles was evaluated for Methyl Blue (MB) dye which showed 94% of degradation and good stability for five cycles.

About the Authors

S. Sathya
PG and Research Department of Physics, Poompuhar College (Affiliated to Bharathidasan University)
India

Melaiyur



J. Vijayapriya
PG and Research Department of Physics, Poompuhar College (Affiliated to Bharathidasan University)
India

Melaiyur



K. Parasuraman
PG and Research Department of Physics, Poompuhar College (Affiliated to Bharathidasan University)
Russian Federation

Melaiyur



D. Benny Anburaj
PG and Research Department of Physics, D.G. Govt. Arts College (Affiliated to Bharathidasan University)
Russian Federation

Mayiladuthurai



S. Joshua Gnanamuthu
PG and Research Department of Physics, TBML College (Affiliated to Bharathidasan University)
India

Porayar



References

1. Hartley T.W. Public perception and participation in water reuse. Desalination, 2006, 187, P. 115–26.

2. Plumlee M.H, Larabee J., Reinhard M. Peruorochemicals in water reuse. Chemosphere, 2008, 72, P. 1541–1547.

3. Peiyan Ma, Yan Wu, Zhengyi Fu, Weimin Wang. Shape-controlled synthesis and photocatalytic properties of three-dimensional and porous zinc oxide. J. Alloys Compd., 2011, 509, P. 3576–3581.

4. Qazi Inamur Rahman, Musheer Ahmad, Sunil Kumar Misra, Minaxi Lohani. Effective photocatalytic degradation of rhodamine B dye by ZnO nanoparticles. Mater. Lett., 2013, 91, P. 170–174.

5. Perera S.D., Mariano R.G., et al. Hydrothermal Synthesis of Graphene-TiO2 Nanotube Composites with Enhanced Photocatalytic Activity. ACS Catal., 2012, 2, P. 949–956.

6. Rajesh Kumar, O. Al-Dossary, Girish Kumar, Ahmad Umar. Zinc Oxide Nanostructures for NO2 GasSensor Applications: A Review. NanoMicro Lett., 2015, 7, P. 97–120.

7. Hoffman R.L. ZnO-based transparent thin-film transistors. Appl. Phys. Lett., 2003, 82, P. 733–735.

8. Jia Huang, Zhigang Yin, Qingdong Zheng. Applications of ZnO in organic and hybrid solar cells. Energy Environ. Sci., 2011, 4, P. 3861–3877.

9. Steinfeld A. Solar hydrogen production via a two-step water-splitting thermochemical cycle based on Zn/ZnO redox reactions. Int. J. Hydrogen Energy, 2002, 27, P. 611–619.

10. Eue Soon Jang, Jung-Hee Won, Seong-Ju Hwang, Jin-Ho Choy. Fine Tuning of the Face Orientation of ZnO Crystals to Optimize their Photocatalytic Activity. Adv. Mater., 2006, 18, P. 3309–3312.

11. Zhong Lin Wang. ZnO nanowire and nanobelt platform for nano technology. Mater. Sci. Eng. R, 2009, 64, P. 33–71.

12. Hongqiang Wang, Guanghai Li, et al. Controllable Preferential-Etching Synthesis and Photocatalytic Activity of Porous ZnO Nanotubes. J. Phys. Chem. C, 2008, 112, P. 11738–11743.

13. Qingzhi Wu, Xia Chen, et al. Amino Acid-Assisted Synthesis of ZnO Hierarchical Architectures and Their Novel Photocatalytic Activities. Cryst. Growth Des., 2008, 8, P. 3010–3018.

14. Xingfu Zhou, Dangyu Zhang, et al. Mechanistic Investigations of PEG-Directed Assembly of One-Dimensional ZnO Nanostructures. J. Phys. Chem. B, 2006, 110, P. 25734–25739.

15. Santhosh C., Velmurugan V., et al. Role of nanomaterials in water treatment applications. Chem. Eng. J., 2016, 306, P. 1116–1137.

16. Kong Y.C., Yu D.P., et al. Ultraviolet-emitting ZnO nanowires synthesized by a physical vapor deposition approach. Appl. Phys. Lett., 2001, 78, P. 406–409.

17. Zhang B.P., Binh N.T., et al. Formation of highly aligned ZnO tubes on sapphire (0001) substrates. Appl. Phys. Lett., 2004, 84, P. 4098–4100.

18. Zheng Wei Pan, Zu Rong Dai, Zhong Lin Wan. Nanobelts of Semiconducting Oxides. Science, 2001, 291, P. 1947–1949.

19. Xu C.X., Sun X.W., Dong Z.L., Yu M.B. Zinc oxide nanodisk. Appl. Phys. Lett., 2004, 85, P. 3878–3880.

20. Seung-Ho Jung, Eugene Oh, et al. Sonochemical Preparation of Shape-Selective ZnO Nanostructures. Cryst. Growth Des., 2008, 8, P. 265–269.

21. Yadav R.S., Priya Mishra, Pandey A.C. Growth mechanism and optical property of ZnO nanoparticles synthesized by sonochemical method. Ultrasonics Sonochemistry, 2008, 15, P. 863–868.

22. Khizar Hayat, Gondal M.A., et al. Nano ZnO synthesis by modified sol gel method and its application in heterogeneous photocatalytic removal of phenol from water. Appl. Catal. A: General, 2011, 393, P. 122–129.

23. Seema Rani, Poonam Suri, Shishodia P.K., Mehra R.M. Synthesis of nanocrystalline ZnO powder via solgel route for dye-sensitized solar cells. Sol. Energy Mater. Sol. Cells, 2008, 92, P. 1639–1645.

24. Jaykrushna Das, Deepa Khushalani. Nonhydrolytic Route for Synthesis of ZnO and Its Use as a Recyclable Photocatalyst. J. Phys. Chem. C, 2010, 114, P. 2544–2550.

25. Matt Law, Greene L.E., et al. Nanowire dye-sensitized solar cells. Nat. Mater., 2005, 4, P. 445–459.

26. Wang B.G., Shi E.W., Zhong W.Z. Twinning Morphologies and Mechanisms of ZnO Crystallites under Hydrothermal Conditions. Cryst. Res. Technol., 1998, 33, P. 937–941.


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Sathya S., Vijayapriya J., Parasuraman K., Benny Anburaj D., Joshua Gnanamuthu S. ZnO nanoparticles as solar photocatalysts: Synthesis, effect of annealing temperature and applications. Nanosystems: Physics, Chemistry, Mathematics. 2020;11(6):672–679. https://doi.org/10.17586/2220-8054-2020-11-6-672-679

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ISSN 2220-8054 (Print)
ISSN 2305-7971 (Online)