Structure of nanoparticles in the ZrO2–Y2O3 system, as obtained under hydrothermal conditions
https://doi.org/10.17586/2220-8054-2020-11-6-729-738
Abstract
It is shown that monocrystalline nanoparticles with fluorite structure are formed in the ZrO2–Y2O3 system, under hydrothermal conditions. The limiting content of Y2O3 in the nanocrystals based on zirconium dioxide is 21.7–22.6 mol.%. Yttrium oxide not included in the structure forms an amorphous phase, which is stable even upon thermal treatment at 1000–1300 ◦C. It has been found that under hydrothermal conditions the structure of the nanocrystals based on ZrO2(Y2O3) solid solution includes water, its content depending on yttrium oxide concentration in the solid solution.
Supporting agencies: The authors express their gratitude to V.V. Gusarov for the attention he paid to the work. X-ray diffraction and SEM/EDS was performed using the equipment of the Engineering Center Saint Petersburg State Institute of Technology. This study was financially supported by the Russian Science Foundation (project no. 20-63-47016).
About the Authors
A. I. Shuklina
Saint Petersburg State Electrotechnical University “LETI”
Russian Federation
Russian Federation
ul. Professora Popova, 5, Saint Petersburg, 197376
A. V. Smirnov
ITMO University
Russian Federation
Russian Federation
Kronverksky Pr. 49, bldg. A, Saint Petersburg, 197101
B. A. Fedorov
ITMO University
Russian Federation
Russian Federation
Kronverksky Pr. 49, bldg. A, Saint Petersburg, 197101
S. A. Kirillova
Saint Petersburg State Electrotechnical University “LETI”
Russian Federation
Russian Federation
ul. Professora Popova, 5, Saint Petersburg, 197376
O. V. Almjasheva
Ioffe Institute
Russian Federation
Russian Federation
Politekhnicheskaya St. 26, Saint Petersburg, 194021
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Shuklina A.I., Smirnov A.V., Fedorov B.A., Kirillova S.A., Almjasheva O.V. Structure of nanoparticles in the ZrO2–Y2O3 system, as obtained under hydrothermal conditions. Nanosystems: Physics, Chemistry, Mathematics. 2020;11(6):729–738. https://doi.org/10.17586/2220-8054-2020-11-6-729-738
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