Solubility phase equilibrium in ternary system fullerenol C60(OH)24 and praseodymium salt: PrCl3–C60(OH)24–H2O at 25 ◦C
https://doi.org/10.17586/2220-8054-2020-11-4-462-467
Abstract
Solubility diagram was investigated by the method of saturation in ampules at 25 ± 0.02◦C for 4 hours. The solubility diagram of the PrCl3– C60(OH)24–H2O ternary system at 25 ◦C occurs as simple eutonics, consisting of two branches, corresponding to the crystallization of crystalhydrates: PrCl3 · 7H2O and C60(OH)24 · 18H2O. The diagram contains one non-variant point each – eutonics, which corresponds to saturation with pair of crystal-hydrates simultaneously. The diagram also contains very short branch of PrCl3 · 7H2O crystallization, and long branch of C60(OH)24 · 18H2O, where the effect of fullerenol salt-out is distinctly observed.
Keywords
fullerene C60,
arginine,
octo-adduct,
lutetium chloride,
solubility diagram,
ternary system,
simple eutonic
Supporting agencies: This work was supported by Russian Foundation for Basic Research (RFBR) (Projects Nos. 18-08-00143 A, 19-015-00469 A, and 19-016-00003 A).
About the Authors
G. A. Glushnev
St. Petersburg State Technological Institute (Technical University)
Russian Federation
Russian Federation
Moskovsky prospect, 26, St. Petersburg, 190013
Ayat Kanbar
St. Petersburg State Technological Institute (Technical University)
Russian Federation
Russian Federation
Moskovsky prospect, 26, St. Petersburg, 190013
V. A. Keskinov
St. Petersburg State Technological Institute (Technical University)
Russian Federation
Russian Federation
Moskovsky prospect, 26, St. Petersburg, 190013
N. A. Charykov
St. Petersburg State Technological Institute (Technical University); St. Petersburg Electrotechnical University “LETI”
Russian Federation
Russian Federation
Moskovsky prospect, 26, St. Petersburg, 190013
ul. Professora Popova 5, 197376 St. Petersburg
K. N. Semenov
St. Petersburg State Technological Institute (Technical University); St. Petersburg State University; Pavlov First St. Petersburg StateMedical University
Russian Federation
Russian Federation
Moskovsky prospect, 26, St. Petersburg, 190013
7/9 Universitetskaya emb., St. Petersburg, 199034
L’va Tolstogo str. 6–8 St. Petersburg, 197022
Z. K. Shaimardanov
D. Serikbayev East Kazakhstan state technical university
Kazakhstan
Kazakhstan
A.K. Protozanov Street, 69, Ust-Kamenogorsk, 070004
B. K. Shaimardanova
D. Serikbayev East Kazakhstan state technical university
Kazakhstan
Kazakhstan
A.K. Protozanov Street, 69, Ust-Kamenogorsk, 070004
N. A. Kulenova
D. Serikbayev East Kazakhstan state technical university
Kazakhstan
Kazakhstan
A.K. Protozanov Street, 69, Ust-Kamenogorsk, 070004
D. G. Letenko
St.Petersburg State University of Architecture and Civil Engineering (SPSUACE)
Russian Federation
Russian Federation
2nd Krasnoarmeiskaya St. 4, 190005 St. Petersburg
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Review
For citations:
Glushnev G.A., Kanbar A., Keskinov V.A., Charykov N.A., Semenov K.N., Shaimardanov Z.K., Shaimardanova B.K., Kulenova N.A., Letenko D.G. Solubility phase equilibrium in ternary system fullerenol C60(OH)24 and praseodymium salt: PrCl3–C60(OH)24–H2O at 25 ◦C. Nanosystems: Physics, Chemistry, Mathematics. 2020;11(4):462–467. https://doi.org/10.17586/2220-8054-2020-11-4-462-467
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