Solid-phase interaction in ZrO2–Fe2O3 nanocrystalline system
https://doi.org/10.17586/2220-8054-2018-9-6-763-769
Abstract
Based on the results of X-ray phase analysis and Mossbauer spectroscopy, it was demonstrated that in the ZrO¨ 2–Fe2O3 system, represented by the mechanical mixture of m–ZrO2 (14±2 nm) and α-Fe2O3 (43±2 nm) nanoparticles, being heated above the temperature corresponding to the melting temperature of the two-dimensional nonautonomous phase, transformation of α-Fe2O3 occurs resulting in appearing of the X-ray amorphous magnetically disordered state localized on the surface of ZrO2 nanoparticles in the form of a thin layer. Transformation pattern in ZrO2–Fe2O3 nanocrystalline system has been introduced.
Supporting agencies: The authors express their gratitude to V.V. Gusarov for the attention he paid to the work and for his help in the interpretation of the results. This work was supported by Ministry of education and science of the Russian Federation (Project 3.6522.2017).
About the Authors
S. A. Kirillova
St. Petersburg State Electrotechnical University “LETI”
Russian Federation
Russian Federation
ul. Professora Popova, 5, St. Petersburg, 197376
O. V. Almjasheva
St. Petersburg State Electrotechnical University “LETI”
Russian Federation
Russian Federation
ul. Professora Popova, 5, St. Petersburg, 197376
V. V. Panchuk
St. Petersburg State University
Russian Federation
Russian Federation
Universitetskaya nab., 7–9, St. Petersburg, 199034
V. G. Semenov
St. Petersburg State University
Russian Federation
Russian Federation
Universitetskaya nab., 7–9, St. Petersburg, 199034
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Review
For citations:
Kirillova S.A., Almjasheva O.V., Panchuk V.V., Semenov V.G. Solid-phase interaction in ZrO2–Fe2O3 nanocrystalline system. Nanosystems: Physics, Chemistry, Mathematics. 2018;9(6):763–769. https://doi.org/10.17586/2220-8054-2018-9-6-763-769
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