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Sulfated alumina in the oligomerization reaction of hexene-1and cyclohexene

Abstract

Reactions of hexene-1 and cyclohexene oligomerization were studied over solid superacid catalysts prepared by impregnation or by washing of alumina by sulfate-containing compounds (sulfuric acid or salts). А 100% conversion of hexene-1 was achieved for all investigated catalysts at room temperature. The maximum conversion of cyclohexene was 25% at 83 ◦C

About the Authors

S. A. Lermontov
Institute of Physiologically Active Compounds RAS
Russian Federation

Chernogolovka



A. N. Malkova
Institute of Physiologically Active Compounds RAS
Russian Federation

Chernogolovka



L. L. Yurkova
Institute of Physiologically Active Compounds RAS
Russian Federation

Chernogolovka



V. P. Kazachenko
Institute of Physiologically Active Compounds RAS
Russian Federation

Chernogolovka



V. K. Ivanov
N. S. Kurnakov Institute of General and Inorganic Chemistry RAN; M. V. Lomonosov Moscow State University
Russian Federation

Department of Materials Science

Moscow



A. E. Baranchikov
N. S. Kurnakov Institute of General and Inorganic Chemistry RAN
Russian Federation

Moscow



Yu. D. Tretyakov
M. V. Lomonosov Moscow State University
Russian Federation

Department of Materials Science

Moscow



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Review

For citations:


Lermontov S.A., Malkova A.N., Yurkova L.L., Kazachenko V.P., Ivanov V.K., Baranchikov A.E., Tretyakov Yu.D. Sulfated alumina in the oligomerization reaction of hexene-1and cyclohexene. Nanosystems: Physics, Chemistry, Mathematics. 2013;4(1):113-119. (In Russ.)

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ISSN 2220-8054 (Print)
ISSN 2305-7971 (Online)