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Nanosystems: Physics, Chemistry, Mathematics

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Vol 4, No 1 (2013)
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5-13 7
Abstract

The paper describes briefly biography and well-known achievements of academician Yuriy Tretyakov, the founder and dean of Materials Science Department, head of inorganic chemistry division of Chemistry Department of Moscow State University, leader of synergy laboratory of General and Inorganic Chemistry Institute of Russian Academy of Sciences.

14-23 9
Abstract

In the paper, a bibliometric analysis of publications of Yu.D.Tretyakov in different areas is performed.

48-53 9
Abstract

The present article is devoted to the β → α phase transformation of Са3(РО4). This phase transformation is low-rate, first-order reconstructive transition, so α−Ca3(PO4)2 can be obtained in the course of low-rate cooling (ca. 5˚С/min). Transformation α → α’ is a high-rate, first-order deformation phase transition; such a fact indicates that α’−Ca3(PO4)2 cannot be obtained even by quenching.

54-65 8
Abstract

In this work, a preparation procedure of reactionary bonded material formed from Ca3(PO4)2 and water under different conditions is discussed with respect to its microstructure and mechanical properties.

66-71 7
Abstract

The paper analyses the effect of silver nanoparticles on structural integrity of erythrocytes in hemolysis depending on nanoparticle size and morphology. It is shown than smaller nanoparticles might cause erythrocyte destruction while chloride ions seem to slow down such a process.

78-82 9
Abstract

The studies concerning photocatalytic properties of nanocrystalline ceria and ceria-based materials appear to be controversial. Moreover, photocatalytic properties of nanocrystalline ceria-based solid solutions still remain unstudied. In this paper, we have performed synthesis and detailed study of nanocrystalline Ce 1−x GdxO2−z(x = 0,1; 0,15; 0,2) samples in a model reaction of crystal violet dye photodecomposition.

83-89 3
Abstract

Cerium dioxide is a unique material which is promising for biomedical applications. The vast majority of currently existing methods of synthesis results in CeO 2 formation in the form of nanopowders. However such powders are useless as biomedical preparations because their exact dosage is nearly impossible. In this paper, we have offered a facile method of ceria stable sols synthesis and investigated the effect of varying concentrations and molar ratio of initial reagents on the CeO 2 particle size. The toxicity of ceria sols has been analyzed using Vibrio fischeri and Escheriсhia Coli bioluminescent microorganisms. Comparative studies of photocatalytic activity of ceria sols has been also performed

90-97 1
Abstract

In present paper zinc oxide nanostructure synthesis and modification for bioanalytical applications are described. Properties of modified zinc oxide array have been studied, and original scheme for conductometric immunosensor has been proposed.

98-104 4
Abstract

A new approach for synthesis of Cu 1−x Ni x GeO 3 (x = 0÷0, 15) in form of nanorods is developed. Analysis of the lattice evolution with Cu(II) percentage showed a change of the cell parameters that corresponds to the theoretical simulation completely. Doping with nickel leads to a rise of dopant concentration in the solid solution.

105-112 4
Abstract

For the first time, ultradispersed cathode materials LiNi 0.4 Mn 0.4 Co 0.2 O 2 were obtained from freeze dried precursors with different anionic composition. The thermal decomposition of freeze drying precursors was carried out at 800–950 ◦C. By using XRD and SEM techniques, it was shown that particle size, crystallinity and cation ordering of Ni 2+ and Li + ions enhance with increasing thermal treatment temperature up to 900 ◦C. It was established that LiNi 0.4 Mn 0.4 Co 0.2 O 2 powders obtained from nitrate precursor at 900 ◦C possess the highest degree of crystallinity and cation ordering

113-119 1
Abstract

Reactions of hexene-1 and cyclohexene oligomerization were studied over solid superacid catalysts prepared by impregnation or by washing of alumina by sulfate-containing compounds (sulfuric acid or salts). А 100% conversion of hexene-1 was achieved for all investigated catalysts at room temperature. The maximum conversion of cyclohexene was 25% at 83 ◦C

120-129 1
Abstract

Here, the detailed study of thermal stability, evolution of morphology and of crystal structure of anodic alumina membranes in temperature range up to 1400˚С is reported. Thermal properties of anodic aluminum oxide, e.g. thermal expansion, heat capacity and thermal conductivity, are determined experimentally. According to obtained results, anodic alumina membranes are promising for creation of hi-tech devices operating at high temperatures

130-138 1
Abstract

The paper describes the influence of optical coherency and vibration dissipation into protein environment on the effectiveness of electron transfer in reaction centers of purple bacteria

139-147 5
Abstract

The process of heterogeneous hydrolysis of titanium tetrachloride vapor onto aerosol water droplets is studied for the first time using in situ small-angle X-ray scattering technique allowed to suggest a new model of the process

148-159 4
Abstract

The correlation between chemical composition and heat conductivity of fluoride materials, including glasses and anti-glasses (heterovalent solid solutions with variable amount of ions in the unit cells), obeys Tretyakov’s principle of equivalency of the disorder sources. Increase of the rare earth element content in M 1−x R x F 2+x (M = Ca, Sr, Ba; R = La–Lu, Y) solid solutions results in a sharp decline of their heat conductivity as well as alters the temperature dependency of the latter parameter. Heat conductivity of M 1−x R x F 2+x , instead of going through its maximum at lower temperature (as it should be for the typical crystalline materials), becomes monotoneous as for glasses. Methods controlling the heat conductivity of the novel materials have been discussed



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ISSN 2220-8054 (Print)
ISSN 2305-7971 (Online)