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Nanosystems: Phys. Chem. Math., 2022, 13 (1), 115–127

A new approach to function-structure modeling of the surface modified polymers

Fedor A. Doronin – Moscow Polytechnic University, Moscow, Russia; f.a.doronin@mospolytech.ru
Andrey G. Evdokimov – Moscow Polytechnic University, Moscow, Russia; evdokag@gmail.com
Yury V. Rudyak – Moscow Polytechnic University, Moscow, Russia; rudyak@mail.ru
Georgy O. Rytikov – Moscow Polytechnic University, Moscow; State university of management, Moscow, Russia; gr-yandex@yandex.ru
Irina P. Taranets – Moscow Polytechnic University, Moscow, Russia; qwerty818@mail.ru
Viktor G. Nazarov – Moscow Polytechnic University, Moscow, Russia; 110505n@gmail.com

Corresponding author: Fedor A. Doronin, f.a.doronin@mospolytech.ru

DOI 10.17586/2220-8054-2022-13-1-115-127
PACS 87.15.Aa

ABSTRACT We introduce a novel approach to function-structure modeling of the polymer materials. It’s based on mathematical and statistical processing of the images obtained by scanning electron microscopy (SEM) of the corresponding surfaces. We studied the correlation-rotational anisotropy, the degrees of planar and contour heterogeneity and the morphological spectra of the SEM images to characterize the function-structure relationships quantitatively. The introduced quantitative characteristics will allow to rationalize the choice of chemical compositions of the modifying gas mixtures (for example, helium-fluorine-oxygen) that provide the maximum possible wetting edge angles for the materials under consideration with reference polar and non-polar liquids.

KEYWORDS oxyfluorination, scanning electron microscopy, modification, morphology, correlation, polymer substrate

ACKNOWLEDGEMENTS This work was carried out with the financial support of the Ministry of science and higher education of the Russian Federation (State assignment “Structure and properties of polymer materials obtained with the use of systems of methods of chemically, thermally and / or mechanically induced surface and volume modification”, topic number FZRR-2020-0024, code 0699-2020-0024).

FOR CITATION Doronin F.A., Evdokimov A.G., Rudyak Yu.V., Rytikov G.O., Taranets I.P., Nazarov V.G. A new approach to function-structure modeling of the surface modified polymers. Nanosystems: Phys. Chem. Math., 2022, 13 (1), 115–127.

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