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Nanosystems: Phys. Chem. Math., 2023, 14 (3), 363–371

Influence of the composition of the BiPO4–BiVO4 system on the phase formation, morphology, and properties of nanocrystalline composites obtained under hydrothermal conditions

Olga V. Proskurina – Ioffe Institute, 194021 St. Petersburg; St. Petersburg State Institute of Technology, 190013 St. Petersburg, Russia; proskurinaov@mail.ru
Ilke Diana Chetinel – St. Petersburg State Institute of Technology, 190013 St. Petersburg, Russia; diana03ridak@gmail.com
Anna S. Seroglazova – Ioffe Institute, 194021 St. Petersburg; St. Petersburg State Institute of Technology, 190013 St. Petersburg, Russia; annaseroglazova@yandex.ru
Victor V. Gusarov – Ioffe Institute, 194021 St. Petersburg, Russia; victor.v.gusarov@gmail.com

Corresponding author: Olga V. Proskurina, proskurinaov@mail.ru

DOI 10.17586/2220-8054-2023-14-3-363-371

ABSTRACT BiPO4/BiVO4 nanocrystalline composites were synthesized under hydrothermal conditions. The influence of the initial composition of the system on the phase state, the size of crystallites, and the morphology of the formed particles was determined. The photocatalytic activity of the nanocomposite was studied using the decomposition of methyl violet as an example.

KEYWORDS hydrothermal synthesis, phase formation, nanocrystals, bismuth orthophosphate, bismuth orthovanadate

ACKNOWLEDGEMENTS X-ray diffraction studies were performed employing the equipment of the Engineering Center of the St. Petersburg State Institute of Technology. The research was supported by the Russian Science Foundation Grant 21-13-00260.

FOR CITATION Proskurina O.V., Chetinel I.D., Seroglazova A.S., Gusarov V.V. Influence of the composition of the BiPO4/BiVO4 system on the phase formation, morphology, and properties of nanocrystalline composites obtained under hydrothermal conditions. Nanosystems: Phys. Chem. Math., 2023, 14 (3), 363–371.

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О.В. Проскурина, И.Д. Четинел, А.С. Сероглазова, В.В. Гусаров

[In Russian] Влияние состава системы BiPO4/BiVO4 на фазообразование, морфологию и свойства нанокристаллических композитов, полученных в гидротермальных условиях

АННОТАЦИЯ Нанокристаллические композиты BiPO4/BiVO4 синтезированы в гидротермальных условиях. Определено влияние исходного состава системы на фазовое состояние, размер кристаллитов и морфологию образующихся частиц. На примере разложения метилового фиолетового изучена фотокаталитическая активность нанокомпозита.

КЛЮЧЕВЫЕ СЛОВА гидротермальный синтез, фазообразование, нанокристаллы, ортофосфат висмута, ортованадат висмута

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