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NANOSYSTEMS: PHYSICS, CHEMISTRY, MATHEMATICS, 2012, 3 (4), P. 101–113

MORPHOLOGY AND DIMENSIONAL PARAMETERS OF BOEHMITE NANOCRYSTALS OBTAINED UNDER HYDROTHERMAL CONDITIONS

Svetlana Kirillova – Saint Petersburg Electrotechnical University “LETI”, Saint Petersburg, Russia, assistant, refractory-sveta@mail.ru
Alexander Smirnov – Saint Petersburg National Research University of Information Technologies, Mechanics and Optics, Saint Petersburg, Russia, Associate Professor of Physics Department, Ph.D., smirnav@phd.ifmo.ru
Boris Fedorov – Saint Petersburg National Research University of Information Technologies, Mechanics and Optics, Saint Petersburg, Russia, Professor of Physics Department, Ph.D., borfedorov@rambler.ru
Andrey Krasilin – Ioffe Physical-Technical Institute RAS, Saint Petersburg, Russia, postgraduate, ikrasilin@gmail.com
Alexander Bugrov – Institute of Macromolecular Compounds, Saint Petersburg, Russia, postgraduate, bugrov.an@mail.ru
Kamil Gareev – Saint Petersburg Electrotechnical University “LETI”, Saint Petersburg, Russia, postgraduate, kggareev@yandex.ru
Irina Gracheva – Saint Petersburg Electrotechnical University “LETI”, Saint Petersburg, Russia, Associate professor, PhD, iegrachova@mail.ru
Vyacheslav Almjashev – Saint Petersburg Electrotechnical University “LETI”, Saint Petersburg, Russia, assistant, vac@mail.ru

The complex physicochemical investigation of the morphological parameters of boehmite nanoparticles and their agglomerates has been carried out. It is shown that a complex approach to the nanoparticle analysis can resolve the contradictions and to increase the reliability of measurement results. The possibilities of the method of small-angle X-ray scattering for the characterization of nanoparticle with isometric shape have been demonstrated. The features of the dynamic light scattering method in the analysis of lamellar nanoparticles agglomerates are considered.

Keywords: boehmite, nanoparticles, hydrothermal synthesis, particle morphology, particle size, size distribution, agglomerates, atomic force microscopy, scanning electron microscopy, dynamic light scattering, X-ray diffractometry, small-angle X-ray scattering, adsorption-desorption gas analysis (BET method).

UDC 544.08

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