NANOSYSTEMS: PHYSICS, CHEMISTRY, MATHEMATICS, 2013, 4 (5), P. 690–695
SULFATED NANO-CERIA AS A CATALYST OF HEX-1-ENE OLIGOMERIZATION
S. A. Lermontov – Institute of Physiologically Active Compounds of the Russian Academy of Sciences, Chernogolovka, Moscow region, Russia; lermon@ipac.ac.ru
A.N. Malkova – Institute of Physiologically Active Compounds of the Russian Academy of Sciences, Chernogolovka, Moscow region, Russia; malkova@ipac.ac.ru
L.L. Yurkova – Institute of Physiologically Active Compounds of the Russian Academy of Sciences, Chernogolovka, Moscow region, Russia; yurkova@ipac.ac.ru
A.Ye. Baranchikov – Kurnakov Institute of General and Inorganic Chemistry of Russian Academy of Sciences,
Moscow, Russia; a.baranchikov@yandex.ru
V.K. Ivanov – Kurnakov Institute of General and Inorganic Chemistry of Russian Academy of Sciences,
Moscow, Russia; Materials Science Department, Moscow State University, Moscow, Russia; van@igic.ras.ru
Oligomerization of hex-1-ene over acid catalysts obtained by the impregnation of cerium dioxide by sulfatecontaining compounds (sulfuric acid or its salts) was studied. Maximum conversion of hexene-1 over sulfated ceria catalysts was 7–12% at 60°C.
Keywords: sulfated ceria, olefins oligomerization, hex-1-ene.
PACS 82.65.+r, 81.07.Bc, 81.16.Be
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