NANOSYSTEMS: PHYSICS, CHEMISTRY, MATHEMATICS, 2014, 5 (4), P. 564-573
EFFECT OF HIGH PRESSURES AND HIGH TEMPERATURES ON STRUCTURAL AND MAGNETIC CHARACTERISTICS OF NANOSTRUCTURED SOLID SOLUTIONS Zn1-xFexO
T. V. Dyachkova – Federal State government- nanced research institution Institute of Solid State Chemistry of the Ural Branch of the Russian Academy of Sciences, Ekaterinburg, Russia; dyachkova@ihim.uran.ru
V. N. Krasil’nikov – Federal State government- nanced research institution Institute of Solid State Chemistry of the Ural Branch of the Russian Academy of Sciences, Ekaterinburg, Russia; kras@ihim.uran.ru
O. I. Gyrdasova – Federal State government- nanced research institution Institute of Solid State Chemistry of the Ural Branch of the Russian Academy of Sciences, Ekaterinburg, Russia; gyrdasova@ihim.uran.ru
E. V. Shalaeva – Federal State government- nanced research institution Institute of Solid State Chemistry of the Ural Branch of the Russian Academy of Sciences, Ekaterinburg, Russia; shalaeva@ihim.uran.ru
A.P. Tyutyunnik – Federal State government- nanced research institution Institute of Solid State Chemistry of the Ural Branch of the Russian Academy of Sciences, Ekaterinburg, Russia; tyutyunnik@ihim.uran.ru
V. V. Marchenkov – Federal State government- nanced research institution Institute of Metal Physics of the Ural Branch of the Russian Academy of Sciences, Ekaterinburg, Russia; march@imp.uran.ru
Yu. G. Zaynulin – Federal State government- nanced research institution Institute of Solid State Chemistry of the Ural Branch of the Russian Academy of Sciences, Ekaterinburg, Russia; zaynulin@ihim.uran.ru
H. W. Weber – Atominstitut, Vienna University of Technology, Vienna, Austria; weber@ati143.ac.at
Nanostructured solid solutions of the composition Zn1-xFexO (0 ≤ x ≤ 0.075) with tubular aggregate morphology, synthesized by the precursor method, were subjected to thermobaric treatment at P = 5 GPa and T = 600-700 °C. Using the samples with x = 0.05 as an example, it was shown that the application of pressure leads to morphology variation, reduction of structural parameters and to an increase in ferromagnetism.
Keywords: High pressure – high temperature, nanomaterials, glycolate, semiconductors.
PACS 71.20.Nr, 73.63.Bd, 75.50.Pp
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