NANOSYSTEMS: PHYSICS, CHEMISTRY, MATHEMATICS, 2016, 7 (6), P. 983–1001
Silicene is a phantom material
E. F. Sheka – Department of Theoretical Physics and Mechanics; Peoples’ Friendship University of Russia, Str. Miklukho-Maklay, 6, Moscow 117198, Russia; sheka@icp.ac.ru
The paper presents a comparative consideration of sp2 nanocarbons and their silicon and higher tetrels analogues from the viewpoint of the spin molecular theory taking into account the electron correlation in open-shell molecules. High radicalization of silicene and quantum instability of flat honeycomb 2D structures of germanene and stanene make all the species phantom materials leaving graphene the only one-atom thick 2D solid free of the crucial restrictions.
Keywords: silicene, siligraphene, boronitrosilicene, spin molecular theory, unrestricted Hartree-Fock formalism, open-shell molecules.
DOI 10.17586/2220-8054-2016-7-6-983-1001
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