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NANOSYSTEMS: PHYSICS, CHEMISTRY, MATHEMATICS, 2018, 9 (3), P. 424–429

Structural and magnetic properties of YFe1-xCoxO3 (0.1 ≤ x ≤ 0.5) perovskite nanomaterials synthesized by co-precipitation method

Nguyen Anh Tien – Ho Chi Minh City University of Education, Ho Chi Minh City, Vietnam; anhtienhcmup@gmail.com
Chau Hong Diem – Ho Chi Minh City University of Education, Ho Chi Minh City, Vietnam; hongdiem.chau@gmail.com
Nguyen Thi Truc Linh – Ho Chi Minh City University of Education, Ho Chi Minh City, Vietnam; linhttn2811@gmail.com
V. O. Mittova – Burdenko Voronezh State Medical University, Voronezh, 394036, Russia; vmittova@mail.ru
Do Tra Huong – Thai Nguyen University of Education, Thai Nguyen University, Vietnam; dotrahuong@gmail.com
I.Ya. Mittova – Voronezh State University, Voronezh, 394018, Russia; imittova@mail.ru

YFe1-xCoxO3 (0.1 ≤ x ≤ 0.5) perovskite-type nanomaterials were successfully synthesized by the chemical co-precipitation method via the hydrolysis of Y(III), Fe(III) and Co(II) cations in boiling water using 5 % aqueous KOH solution as a precipitating agent. Along with the increase of cobalt ion concentration (x values, from 0.1 to 0,5), there was an decrease in the crystallite size nanomaterials (from 25.68 to 22.89 nm), as well as in the lattice constants (a = 5.5781 – 5.5217 Å ; b = 5.2732 – 5.2177 Å , c = 7.5902 – 7.5009 Å ; V = 223.26 – 216.11 Å), but there was an increase in the magnetic parameters including coercive force (Hc = 88.86 Oe), remnant magnetization (Mr = 0.031 – 0.268 emu/g), saturation magnetization (Ms = 0.413 – 1.006 emu/g) and maximum energy product ((BH)max = 0.413 – 1.006 emu/g).

Keywords: nanomaterial, co-doped YFeO3, perovskite, co-precipitation.

PACS 75.50.Cc, 81.07.Wx

DOI 10.17586/2220-8054-2018-9-3-424-429

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