NANOSYSTEMS: PHYSICS, CHEMISTRY, MATHEMATICS, 2013, 4 (1), P. 139-147
INVESTIGATION OF INTERACTIONS OF GASEOUS TITANIUM TETRACHLORIDE WITH WATER AEROSOL BY IN-SITU SMALL-ANGLE X-RAY SCATTERING USING SINCROTRONE IRRADIATION
A. B. Tarasov – Department of Materials Science, M.V. Lomonosov Moscow State University, Moscow, Russia; Laboratory of Solid State Ionics, Institute of Problems of Chemical Physics RAS, Chernogolovka, Russia; alexey.bor.tarasov@gmail.com
G. B. Trusov – Chemistry Department, M.V. Lomonosov Moscow State University, Moscow, Russia
A.Yu. Gruzinov – National Research Center “Kurchatov Institute”, Moscow, Russia
E. A. Goodilin – Department of Materials Science, M.V. Lomonosov Moscow State University, Moscow, Russia; Chemistry Department, M.V. Lomonosov Moscow State University, Moscow, Russia
A.V. Zabelin – National Research Center “Kurchatov Institute”, Moscow, Russia
The process of heterogeneous hydrolysis of titanium tetrachloride vapor onto aerosol water droplets is studied for the first time using in situ small-angle X-ray scattering technique allowed to suggest a new model of the process.
Keywords: gas-phase SAXS, TiO2, titania, TiCl4 hydrolysis.
UDC 546.824: 544.72
PACS 77.84.Cg, 81.07.Bc